• Title/Summary/Keyword: fly ash/slag

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The Synthesis and Mechanical Property of Calcium Silicate Hydrates Using the Amorphous Silicates (비정질 규산원료를 이용한 칼슘실리케이트 수화물 합성과 역학적 특성)

  • 엄태선;최연묵;최상흘
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.45-55
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    • 1997
  • Various kinds of amorphous silicates were used as raw materials to synthesize building materials based on calcium silicate hydrates. Relationships between the reactivities of silicates and castabilities of the building materials were investigated. In addition, effects of the reactivities of silicates on the mechanical properties of casted specimens were studied by analyzing microstructures and hydrates produced. As the reactivity of silicate increase, the press castability increases and the crystal size of hydrate and pore size also increase. For the mechanical properties, the flexural strength increases with decreasing crystal size and densifing microstructure. The compressive strength is greatly dependent on the den-sification of microstructure rather than crystal size of hydrate. Based on the results, diatomous ma-terials are desirable due to high reactivity and formation of densified microstructure. Slag and fly ash may be partially used as raw materials with amorphous silicates to manufacture building materials based on calcium silicate hydrates.

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A Study on the Effect of the Kinds and Replacement Ratios of Mineral Admixtures on the Development of Chloride Invasion Resistance Property of Concrete Immersed in Salt Water (혼화재 종류 및 치환율이 염수에 침지한 콘크리트의 내염성능 향상에 미치는 영향에 관한 연구)

  • Yoo Jae-Kang;Kim Dong-Seuk;Park Sang-Joon;Won Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.71-76
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    • 2004
  • This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for $3\sim4$ replacement ratios under W/B ratios ranged from 0.40 to 0.55. Specimens were immersed in $3.6\%$ NaCl solution for 330 days, and penetration depth, water soluble chloride contents and acid soluble chloride contents were measured in 28, 91, 182 and 330 days. Then, diffusion coefficient were calculated using total chloride contents. As a results. the kinds of mineral admixture and replacement ratios had a great effect on the resistance property of the concrete to chloride ion invasion compared with the plain concrete. And the optimal replacement ratios of mineral admixture had a limitation for each admixtures. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures and the penetration depth from the concrete skin. Chloride diffusion coefficient of each concretes decreased with the time elapsed. and the diffusion coefficients of the concrete immersed salt water for 330 days had a establishment with the compressive strength measured before immersing.

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Mechanical Properties of Ultra High Strength Concrete Using Ternary Blended Cement (3성분계 혼합시멘트를 사용한 초고강도 콘크리트의 역학적 특성)

  • Kim, Jin Bong;Shin, Ki Su;Park, Ki Bong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.56-62
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    • 2012
  • The results presented in this paper form part of an investigation into the optimization of a ternary blended cementitious system based on ordinary Portland cement (OPC)/blast furnace slag(BFS)/fly ash(FA) for the development of ultra high strength concrete. Concrete covering a wide range of BFS/FA blending proportions were investigated. Compressive strength at the ages of 3, 7 and 28 days for concrete specimens containing 0%, 10%, 20% and 30%FA along with 0%, 30%, 40% and 50%BFS as partial cement replacement at a water-binder ratio of 0.18 were investigated. Tests on porosity and pore size distribution were conducted using mercury intrusion porosimetry. The results show that the combination of FA10 and BFS30 can improve both short- and long-term properties of concrete as results of reducing of pores larger than 50nm.

A Study on the Quality Properties of Alkali-activated cement free Mortar using Industrial by-products (산업부산물을 사용한 알칼리 활성 무시멘트 모르타르의 품질특성에 관한 연구)

  • Kwon, Yong-Hun;Kwon, Yeong-Ho;Lee, Dong-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.58-66
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    • 2013
  • This study investigated quality properties of alkali activated cement free mortar using industrial by-product such as cement kiln dust(CKD), silica fume(SF) and quartz sand powder(SP) to compare with previous research about blast furnace slag(BS) and fly ash(FA). The results were as following. All materials were effective to increase compressive strength, however they showed different tendency on flowability. CKD and SP increased flowability, but on the other hand SF did not because it's blain was great difference with other materials. Flowability and compressive strength were related with grading distributions of binders because CKD, SP and SF which had small particle size filled up BS and FA. Application of industrial by-products with various grading distributions could be effective for the high early strength and flowability of alkali activated cement free mortar using BS.

Effect of Initial Flexural Crack on Resistance to Chloride Penetration into Reinforced Concrete Members (초기 휨균열이 철근콘크리트 부재의 염화물침투저항성에 미치는 영향)

  • Yang, Eun Ik;Jin, Sang Ho;Kim, Myung Yu;Choi, Yoon Suk;Han, Sang Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.2
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    • pp.79-87
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    • 2011
  • In this study, the chloride penetration tests were performed for the initially cracked reinforced concrete members. The chloride diffusion characteristics and the critical crack width are compared, and the properties of self-healing are investigated. According to the test results, the chloride penetration resistance was greatly reduced as the surface crack width increased. When the mineral admixtures are added, the chloride penetration resistance of uncracked specimens were effectively increased, however, in case of the blast furnace slag and fly ash, the cracked specimens showed the more reduced resistance than OPC case, inversely. Also, the critical width was $29{\mu}m$, on average, for immersion test. The crack width with $4{\sim}15{\mu}m$ was restored by self-healing, The parts restored by self-healing were seemed to be visually restored, however, the chloride penetration resistance was not restored, perfectly.

Fire Resistance Properties of High Strength Concrete Made with Various Admixture Types and Fiber Content (혼화재 종류 및 섬유 혼입률 변화에 따른 고강도 콘크리트의 내화특성)

  • Jang, Ki-Hyun;Pei, Chang-Chun;Jin, Hu-Lin;Jee, Suk-Won;Yang, Seong-Hwan;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.63-66
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    • 2007
  • This study investigates the fire resistance properties of high strength concrete, around 60MPa class, designed with various admixture types and fiber content. Test showed that the increase of fiber content decreased the fluidity and slightly inclined the air content of fresh concrete. However, the fiber content in concrete did not affect the compressive strength. For the addition of admixture, specimens adding the shrinkage-reducing-agent (SR) indicated the strength value at 70MPa, which is followed by incorporating silica fume (SF) at 66MPa, the combination of expansive admixture (EA) and SR at 63MPa, only EA at 59MPa, blast furnace slag (BS) at 58MPa and fly ash (FA) at 50MPa in an order. After completing the fire test, all specimens adding 0.05vol.% of polypropylene fiber exhibited protection of spatting, except for the specimens incorporating loft of SF and incorporating 20% of SF with only SR and the combination of EP and SRA, respectively. Therefore the most effective result of this study was shown in the specimens incorporating love of FA and 30% of BS and incorporating 20% of SF with 5 % of EA. It is expected that this test results will be crucial references in near future to develope the spatting resistance method of high strength concrete.

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The Fundamental Study on Quality Properties of Binary Blended Concrete according to Water Reducing Performance of Chemical Admixture and Estimation Equation of Compressive Strength (화학 혼화제의 감수 성능에 따른 2성분계 콘크리트의 품질특성 및 압축강도 추정식에 관한 기초적 연구)

  • Kim, Kyung-Hwan;Oh, Sung-Rok;Choi, Byung-Keol;Choi, Yun-Wang
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.1
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    • pp.9-17
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    • 2016
  • In this study, binary blended concrete mix with fly ash and ground granulated blast furnace slag was prepared according to 3 level of water reduction performance of chemical admixture (0%, 8% and 16%) and 3 level of water-cement ratio (40%, 45% and 50%) for evaluation of quality properties of binary blended concrete according to performance of chemical admixture. concrete mix was carried out repetition test of three times in order to secure the reliability. As a result, compressive strength according to performance of chemical admixture was found that difference of strength was about 20% occurred, chemical admixture was showed that a great influence on qualities of concrete. In addition, reflected the effect of performance of chemiacal admixture, prediction model equations for concrete compressive strength was proposed, it was found that more than 85% of the high correlation.

Evaluation of Rainwater Storage Block Using Recycled Aggregate By-product (순환골재 공정부산물을 활용한 빗물저류블록의 성능평가)

  • Kim, Ho-Kyu;Kim, Young-Ahn;Choi, Seung-Yong;Cho, Young-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.167-173
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    • 2018
  • In general, calcium is required for the reaction of blast furnace slag fine powder and fly ash. The by-products generated during the process of producing recycled aggregates have different calcium contents depending on the crushing stage and the possibility of using the process by-product as a concrete mixture is also different. In this study, the effect of the calcium content of the by-products on the compressive strength was investigated and the block was fabricated by using this. To utilize the by-products as an admixture, the calcium content was analyzed and the bending strength and surface temperature were measured according to the shape of the water storage block. As a result of this study, the possibility of making a block using recycled aggregate by-products was verified and arch type block was constructed to secure storage capacity and bending strength. Also, the surface temperature of the water storage block was reduced by $9^{\circ}C$ or more than that of the general permeable block.

Synthesis of Cement Raw Materials by Melting of Industiral Wastes(II) (폐기물의 용융처리에 의한 시멘트 원료의 합성(II))

  • Hwang, Y.;Sohn, Y. U.;Chung, H. S.;Lee, H. K.;Park, H. S.
    • Resources Recycling
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    • v.6 no.1
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    • pp.29-34
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    • 1997
  • The feasibility of using the industrial inorganic waste materials such as l~mestone sludge. Soundly sand. coal fly 'ash, and chemical glasses as a raw material for cement clinker by melting treatmeut was iovestigated. The slag wh~ch is obtained from thc melts of the mixtnres of waste materials is composed of P-C,S(ZCaO - SIOJ and C,AS(ZCaO . AI,O, . SiO,) phases. The effect of melting tempcrabre, coaling condition and CIS ratio on the fo~mation of P-C,S phasc was examed. In order to obtain thc P-CiS phase which is useful in thc utilhtion as a clinkcr malcrid, it B found that sudl considerations as low melting temperature as possible of the wastc mixhire, quenching the melts and law CIS ratio of the mlxhlre are necessary.

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Strength Correction Factors due to Temperature Drop of Structural Concrete under Low Temperature by the Equivalent Age Method (저온환경에서 타설되는 구조체 콘크리트의 등가재령 방법을 활용한 기온보정강도 설정)

  • Choi, Youn-Hoo;Han, Min-Cheol;Lee, Young-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.5
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    • pp.409-416
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    • 2020
  • In this paper, strength correction factors of the concretes incorporating ordinary Portland cement(OPC), fly ash(FA) and blast furnace slag(BS) with 50% of water to binder ratio due to temperature drop for standard room temperature(20±3℃) are provided. For this, strength development was done based on equivalent age method. For calculating the equivalent age, apparent activation energy was obtained with 24.69 kJ/mol in OPC, 46.59 kJ/mol in FA, 54.59 kJ/ol in BS systems. According to the estimation of strength development of the concretes, the use of FA and BS resulted in larger strength drop than that of OPC under low temperature compared to standard room temperature. Hence, strength correction factors(Tn) for OPC, FA and BS are suggested within 4~17℃ with every 3MPa levels.