• Title/Summary/Keyword: fluorostyrene

Search Result 2, Processing Time 0.014 seconds

Synthesis and Physical Properties of Ophthalmic Copolymer Containing 4-fluorostyrene (4-Fluorostyrene을 포함하는 안의료용 고분자 합성 및 물리적 특성)

  • Kim, Tae-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
    • /
    • v.54 no.3
    • /
    • pp.317-322
    • /
    • 2010
  • This study used 4-fluorostyrene with the cross-linker EGDMA (ethylene glycol dimethacrylate), HEMA (2-hydroxyethyl methacrylate) and the initiator AIBN (azobisisobutyronitrile) for copolymerization. Measurement of the physical properties of the copolymerized polymer showed that the water content was 19.98 ~ 31.08%, refractive index 1.443 ~ 1.475, visible transmittance 87 ~ 93% and tensile strength 0.246 ~ 0.311 kgf while the contact angle showed a distribution between $54.14^{\circ}$ and $66.95^{\circ}$. Therefore, the ophthalmic material produced using 4-fluorostyrene satisfied the basic physical properties required for contact lenses and also showed an increase in wettability and refractive index while having no significant change in water content with relation to styrene. Based on the results of this study, the produced copolymer is suitable for use as a material to high refractive index and wettability contact lenses.

Dispersion Properties and Photocatalytic Activities of TiO2 Powders Obtained by Homogeneous Precipitation Process at Low Temperature in a Acrylic Resin (저온균일침전법으로 제조된 TiO2 분말의 아크릴레진에서의 분산특성 및 광분해 효과)

  • Woo S. H.;Kim W. W.;Rhee C. K.
    • Journal of Powder Materials
    • /
    • v.11 no.6 s.47
    • /
    • pp.503-509
    • /
    • 2004
  • Dispersion stabilities and photocatalytic activities of rutile $TiO_{2}$ powders with unique nano-structure synthesized by homogeneous precipitation process at low temperature(HPPLT) have been investigated in the acrylic resin containing fluorostyrene in the range of 0~0.16 mole. Isoelectric point of $TiO_{2}$ in the acrylic resin placed in the neutral region whereas that of $TiO_{2}$ in the water placed in the acidic region, indicating that zeta potential and agglomeration of $TiO_{2}$ powder is strongly dependent on the pH and the type of solvent. To prepare an adhesion, an acrylic resin containing fluorostyrene was synthesized by a radical polymerization. The adhesion of coating layer was increased with increasing fluorostyrene's contents without changing the dispersion stabilities and degrading photocatalytic properties.