• Ocean Science Journal
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• v.42 no.1
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• pp.49-59
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• 2007

Besides empirical algorithms with the blue-green ratio, the algorithms based on fluorescence are also important and valid methods for retrieving chlorophyll-a concentration in the ocean waters, especially for Case II waters and the sea with algal blooming. This study reviews the history of initial cognitions, investigations and detailed approaches towards chlorophyll fluorescence, and then introduces the biological mechanism of fluorescence remote sensing and main spectral characteristics such as the positive correlation between fluorescence and chlorophyll concentration, the red shift phenomena. Meanwhile, there exist many influence factors that increase complexity of fluorescence remote sensing, such as fluorescence quantum yield, physiological status of various algae, substances with related optical property in the ocean, atmospheric absorption etc. Based on these cognitions, scientists have found two ways to calculate the amount of fluorescence detected by ocean color sensors: fluorescence line height and reflectance ratio. These two ways are currently the foundation for retrieval of chlorophyll-a concentration in the ocean. As the in-situ measurements and synchronous satellite data are continuously being accumulated, the fluorescence remote sensing of chlorophyll-a concentration in Case II waters should be recognized more thoroughly and new algorithms could be expected.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.162-165
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• 2007

Chlorophyll concentration is an important factor for physical oceanography as well as biological oceanography. For these necessity many oceanographic researchers have been investigated it for a long time. But investigation using vessel is very inefficient, on the other hands, ocean color remote sensing is a powerful means to get fine-scale (spatial and temporal scale) measurements of chlorophyll concentration. Geostationary Ocean Color Imager (GOCI), for ocean color sensor, loaded on COMS (Communication, Ocean and Meteorological Satellite), will be launched on late 2008 in Korea. According to the necessity of algorithm for GOCI, we developed chlorophyll algorithm for GOCI in this study. There are two types of chlorophyll algorithms. One is an empirical algorithm using band ratio, and the other one is a fluorescence-based algorithms. To develop GOCI chlorophyll algorithm empirically we used bands centered at 412 nm, 443 nm and 555 nm for the DOM absorption, chlorophyll maximum absorption and for absorption of suspended solid material respectively. For the fluorescence-based algorithm we analyzed in-situ remote sensing reflectance $(R_{rs})$ data using baseline method. Fluorescence Line Height $({\Delta}Flu)$ calculated from $R_{rs}$ at bands centered on 681 nm and 688 nm, and ${\Delta}Flu_{(area)}$ are used for development of algorithm. As a result ${\Delta}Flu_{(area)}$ method leads the best fitting for squared correlation coefficient $(R^2)$.