• 제목/요약/키워드: flow of charge

검색결과 437건 처리시간 0.025초

활성탄의 후 처리에 의한 EDLC 전극재의 전기화학 성능 개선 (Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC)

  • 이은지;권순형;최푸름;정지철;김명수
    • 한국재료학회지
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    • 제24권6호
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    • pp.285-292
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    • 2014
  • Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

응급환자 간호사정 도구개발 (Development of an Nursing Assessment Tool for Emergency Patients)

  • 안미현
    • 간호행정학회지
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    • 제4권2호
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    • pp.419-437
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    • 1998
  • Nurses use a nursing process. that is a scientific approach method. in order to understand the clients' condition and to solve their problems. Professional nurses have accepted the nursing process as a standard framework for nursing activities, and the first step of the nursing process is nursing assessment. The purpose of this study was to develop a nursing assessment tool for emergency patients. Assessment is a first step in the nursing process, and scientific assessment helps to better understand the patients. Thus the development of an assessment tool for emergency patients will improve of nursing quality and advance to efficacy of emergency room(ER) management. The study involved the development of a conceptual framework, preliminary tool, content validity verification process. and reliability verification process. The conceptual framework was developed through a review of the literature. and preliminary tool was developed from the conceptual framework that based on care flow sheet' developed James A. Haley. The preliminary tool was evaluated for validity and reliability by seven experts, one ER nurse manager, two ER head nurses, two emergency medicine doctors. and two ER charge nurses and by ten nurses with one to five year careers in ER nursing. The results of this study was as follows 1. The conceptual framework which was developed was composed of three parts. They were triage criteria, first assessment and secondary assessment. 2. The preliminary tool which was developed had 31 items based on the conceptual framework. 3. To test expert validity a 4-point scale was used. items which had gained 3-4 points from six persons of the seven experts were selected. All 31 items from the preliminary tool were selected. 4. The reliability test was done by ten nurses educated in the use of the assessment tool. Two pairs of nurses simultaneously assessed the same patients. A total agreement percentile was calculated and result was 87.3% agreement. 5. After the validity and reliability testing. the final emergency patient nursing assessment tool was finalized with 31 items. and a check-list for the responses. This study concludes that the tool which was developed is both valid and reliable will advance quality care for emergency patients. This emergency nursing assessment tool was also found to be an adequate tool for assessment of emergency patients.

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Bile Acid Inhibition of N-type Calcium Channel Currents from Sympathetic Ganglion Neurons

  • Lee, Hye-Kyung;Lee, Kyoung-Hwa;Cho, Eui-Sic
    • The Korean Journal of Physiology and Pharmacology
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    • 제16권1호
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    • pp.25-30
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    • 2012
  • Under some pathological conditions as bile flow obstruction or liver diseases with the enterohepatic circulation being disrupted, regurgitation of bile acids into the systemic circulation occurs and the plasma level of bile acids increases. Bile acids in circulation may affect the nervous system. We examined this possibility by studying the effects of bile acids on gating of neuronal (N)-type $Ca^{2+}$ channel that is essential for neurotransmitter release at synapses of the peripheral and central nervous system. N-type $Ca^{2+}$ channel currents were recorded from bullfrog sympathetic neuron under a cell-attached mode using 100 mM $Ba^{2+}$ as a charge carrier. Cholic acid (CA, $10^{-6}M$) that is relatively hydrophilic thus less cytotoxic was included in the pipette solution. CA suppressed the open probability of N-type $Ca^{2+}$ channel, which appeared to be due to an increase in (no activity) sweeps. For example, the proportion of sweep in the presence of CA was ~40% at +40 mV as compared with ~8% in the control recorded without CA. Other single channel properties including slope conductance, single channel current amplitude, open and shut times were not significantly affected by CA being present. The results suggest that CA could modulate N-type $Ca^{2+}$ channel gating at a concentration as low as $10^{-6}M$. Bile acids have been shown to activate nonselective cation conductance and depolarize the cell membrane. Under pathological conditions with increased circulating bile acids, CA suppression of N-type $Ca^{2+}$ channel function may be beneficial against overexcitation of the synapses.

양극산화에 의한 다공성 알루미나 막의 제조 및 기체투과 특성 (Gas Permeation Characteristics of Microporous Alumina Membrane Prepared by Anodic oxidation)

  • 심원;이창우;함영민
    • 공업화학
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    • 제10권2호
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    • pp.212-217
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    • 1999
  • 기체투과 특성을 관찰하기 위해 양극산화에 의해 세공직경의 크기가 서로 다른 상부층과 하부층으로 이루어진 이중기하구조의 다공성 알루미나막을 제조하였다. 양극산화는 황산 전해질 하에서 직류에 의한 정전류법으로 행하였으며, 양질의 막을 얻기 위해 열산화, 화학연마, 전해연마 등의 전처리를 한 후 양극산화를 행하였다. 양극산화에 의한 알루미나 막의 제조에서 세공직경은 전해질의 종류 및 농도, 전해 온도, 전류밀도 등에 의존하는데, 전류밀도를 극도로 낮추어 세공직경이 20 nm 이하인 상부층을 제조하고 전류밀도를 높여서 세공직경이 36 nm인 하부층을 제조하였다. 막의 두께는 전기량에 의해 조절되어 상부층의 두께는 약 $6{\mu}m$이었으며 하부층을 포함하는 막의 총 두께는 약 $80{\sim}90{\mu}m$로 제조되었다. 제조된 막은 가압법에 의한 기체투과 실험을 행하였다. 제조된 막의 기체투과 기구는 Knudsen 흐름을 따르는 것을 확인하였다.

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충격 전달에 의한 Gap Test의 폭굉 반응 해석 (A Study on Shock-induced Detonation in Gap Test)

  • 김보훈;강원규;장승교;박정수;여재익
    • 한국추진공학회지
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    • 제20권2호
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    • pp.75-85
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    • 2016
  • 감쇠기를 사이에 두고 여폭약과 수폭약으로 충전된 파이로 착화기는 격벽의 압력 감쇠 현상과 고에너지 물질의 충격 점화 특성을 갖는다. 고폭약의 폭굉 반응 및 비반응 물질 통과에의 폭압 감쇠와 더불어 격벽의 형상 변화를 모사하기 위해서는 충격 전달에 의한 gap test의 폭굉 모델링이 필요하다. 본 연구에서는 오일러리안 레벨셋 기법이 적용된 다중물질 하이드로 코드를 사용하여 pentolite 작약과 열폭압 RDX의 폭발 반응 및 PMMA gap을 통과하는 충격파 전달을 해석함으로써 화약-격벽간 상호작용 및 임계 두께, 음향 임피던스, go/no-go 기폭 점화에 대한 특성을 정량화하였다.

혼합 기능을 갖는 마이크로 펌프의 연구 (A Study on the MHD Micropump with Mixing Function)

  • 최범규;강호진;김민석
    • 대한기계학회논문집B
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    • 제34권6호
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    • pp.579-586
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    • 2010
  • MEMS 기술의 향상과 함께 $\mu$-TAS(Micro Total Analysis System)가 개발 되어 의료 및 생물학 분야가 급속하게 성장했다. $\mu$-TAS의 한 분야로 Chip 위에서 소량의 sample과 반응물을 가지고 혼합공정과 분석공정이 이루어지는 LOC(Lab on a chip)에 관한 연구는 활발하게 연구되어진다. LOC는 마이크로 펌프 와 마이크로 믹서와 같은 microfluidic 장치들로 구성된다. Microfluidic 시스템의 유동이 층류 유동이므로 유체상태의 반응물들을 효율적으로 혼합하고 공급하는 것이 어렵다. 본 논문은 이송 및 혼합이 동시에 이루어지는 MHD micropump의 설계와 제작에 관해 제시하였다. 최종 개선사양은 상용 CFD 프로그램의 해석결과를 통하여 결정하였다.

Hierarchical Control Scheme for Three-Port Multidirectional DC-DC Converters in Bipolar DC Microgrids

  • Ahmadi, Taha;Hamzeh, Mohsen;Rokrok, Esmaeel
    • Journal of Power Electronics
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    • 제18권5호
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    • pp.1595-1607
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    • 2018
  • In this paper, a hierarchical control strategy is introduced to control a new three-port multidirectional DC-DC converter for integrating an energy storage system (ESS) to a bipolar DC microgrid (BPDCMG). The proposed converter provides a voltage-balancing function for the BPDCMG and adjusts the states of charge (SoC) of the ESS. Previous studies tend to balance the voltage of the BPDCMG buses with active sources or by transferring power from one bus to another. Furthermore, the batteries available in BPDCMGs were charged equally by both buses. However, this power sharing method does not guarantee efficient operation of the whole system. In order to achieve a higher efficiency and lower energy losses, a triple-layer hierarchical control strategy, including a primary droop controller, a secondary voltage restoration controller and a tertiary optimization controller are proposed. Thanks to the multi-functional operation of the proposed converter, its conversion stages are reduced. Furthermore, the efficiency and weight of the system are both improved. Therefore, this converter has a significant capability to be used in portable BPDCMGs such as electric DC ships. The converter modes are analyzed and small-signal models of the converter are extracted. Comprehensive simulation studies are carried out and a BPDCMG laboratory setup is implemented in order to validate the effectiveness of the proposed converter and its hierarchical control strategy. Simulation and experimental results show that using the proposed converter mitigates voltage imbalances. As a result, the system efficiency is improved by using the hierarchical optimal power flow control.

Design and Evaluation of a High Concentration, High Penetration Unipolar Corona Ionizer for Electrostatic Discharge and Aerosol Charging

  • Intra, Panich;Tippayawong, Nakorn
    • Journal of Electrical Engineering and Technology
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    • 제8권5호
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    • pp.1175-1181
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    • 2013
  • The aim of this paper is to design and evaluate a high concentration, high penetration unipolar corona ionizer. The electrostatic characteristics in terms of voltage-current relationships of the present ionizer in the discharge zones for positive and negative coronas were discussed. Using ion current measurement, the concentration and penetration of ions were evaluated at corona voltages across the needle electrodes between 1 and 4 kV, flow rates between 1 and 5 L/min, and an operating pressure of 1 atm. In the discharge zone of the ionizer, the highest ion concentrations were found to be about $1.71{\times}10^{14}$ and $5.09{\times}10^{14}\;ions/m^3$ for positive and negative coronas, respectively. At the outlet of the ionizer, it was found that the highest ion concentration was about $1.95{\times}10^{13}$ and $1.91{\times}10^{13}\;ions/m^3$ for positive and negative coronas, respectively. The highest ion penetration for positive and negative coronas through the ionizer was found to be about 98 % and 33 %, respectively. The $N_it$ product for positive and negative coronas was also found to $1.28{\times}10^{13}$ and $7.43{\times}10^{13}\;ions/m^3s$, respectively. From the findings, this ionizer proved to be particularly useful as an aerosol charger for positive and negative charge before the detector in an electrical aerosol detector.

Synthesis of $LiCoO_{2}$ Nanoparticles From Leach Liquor of Lithium Ion Battery Wastes by Flame Spray Pyrolysis

  • Lee Churl Kyoung;Chang Hankwon;Jang Hee Dong;Sohn Jeong-Soo
    • 자원리싸이클링
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    • 제14권6호
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    • pp.37-43
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    • 2005
  • 페리튬이온전지로부터 회수된 코발트와 리튬 침출액으로부터 화염분부열분해법에 의하여 $LiCoO_{2}$ 나노분말을 제조하였다. 리튬 및 코발트 성분을 함유하는 전극물질은 열처리 및 기계적 처리에 의해 그 농도를 증가 시켰다. 리튬이온전지 양극물질을 질산으로 용해한 다음 침출액중 Li과 Co의 당량비가 1.0 되도록 $LiNO_{3}$로 조절하여 화염분무열분해용 전구체를 제조하었다. 화염분무열분해법에 의해 제조된 $LiCoO_{2}$ 분말의 평균입자크기는 전구체의 몰 농도가 증가하면서 증가되었으며, 화염온도 역시 입자의 크기를 증가시켰다. 변수실험 결과 $11{\~}35nm$ 크기의 결정형 $LiCoO_{2}$ 나노분말을 제조할 수 있었다 또한 나노 $LiCoO_{2}$의 전극재료로서의 가능성을 확인하기 위하여 충방전 특성 평가와 같은 전기화학적 분석을 수행하였다.

A Preliminary Research on Optical In-Situ Monitoring of RF Plasma Induced Ion Current Using Optical Plasma Monitoring System (OPMS)

  • Kim, Hye-Jeong;Lee, Jun-Yong;Chun, Sang-Hyun;Hong, Sang-Jeen
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.523-523
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    • 2012
  • As the wafer geometric requirements continuously complicated and minutes in tens of nanometers, the expectation of real-time add-on sensors for in-situ plasma process monitoring is rapidly increasing. Various industry applications, utilizing plasma impedance monitor (PIM) and optical emission spectroscopy (OES), on etch end point detection, etch chemistry investigation, health monitoring, fault detection and classification, and advanced process control are good examples. However, process monitoring in semiconductor manufacturing industry requires non-invasiveness. The hypothesis behind the optical monitoring of plasma induced ion current is for the monitoring of plasma induced charging damage in non-invasive optical way. In plasma dielectric via etching, the bombardment of reactive ions on exposed conductor patterns may induce electrical current. Induced electrical charge can further flow down to device level, and accumulated charges in the consecutive plasma processes during back-end metallization can create plasma induced charging damage to shift the threshold voltage of device. As a preliminary research for the hypothesis, we performed two phases experiment to measure the plasma induced current in etch environmental condition. We fabricated electrical test circuits to convert induced current to flickering frequency of LED output, and the flickering frequency was measured by high speed optical plasma monitoring system (OPMS) in 10 kHz. Current-frequency calibration was done in offline by applying stepwise current increase while LED flickering was measured. Once the performance of the test circuits was evaluated, a metal pad for collecting ion bombardment during plasma etch condition was placed inside etch chamber, and the LED output frequency was measured in real-time. It was successful to acquire high speed optical emission data acquisition in 10 kHz. Offline measurement with the test circuitry was satisfactory, and we are continuously investigating the potential of real-time in-situ plasma induce current measurement via OPMS.

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