• 제목/요약/키워드: flow cell

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Issues Related to the Modeling of Solid Oxide Fuel Cell Stacks

  • Yang Shi;Ramakrishna P.A.;Sohn Chang-Hyun
    • Journal of Mechanical Science and Technology
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    • 제20권3호
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    • pp.391-398
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    • 2006
  • This work involves a method for modeling the flow distribution in the stack of a solid oxide fuel cell. Towards this end, a three dimensional modeling of the flow through a Solid Oxide Fuel Cell (SOFC) stack was carried out using the CFD analysis. This paper examines the efficacy of using cold flow analysis to describe the flow through a SOFC stack. It brings out the relative importance of temperature effect and the mass transfer effect on the SOFC manifold design. Another feature of this study is to utilize statistical tools to ascertain the extent of uniform flow through a stack. The results showed that the cold flow analysis of flow through SOFC might not lead to correct manifold designs. The results of the numerical calculations also indicated that the mass transfer across membrane was essential to correctly describe the cathode flow, while only temperature effects were sufficient to describe the anode flow in a SOFC.

평행류와 Interdigitated 유로를 가진 교분자 전해질 연료전지(PEMFC)의 성능특성에 대한 수치해석 (Numerical Analysis on Performance Characteristics of PEMFC with Parallel and Interdigitated Flow Channel)

  • 이필형;조선아;최성훈;황상순
    • 전기화학회지
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    • 제9권4호
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    • pp.170-177
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    • 2006
  • 고분자 전해질 연료전지의 분리판의 유동채널 설계는 고전류밀도에서 발생하는 농도분극에 직접적인 영향을 줄 뿐 아니라 생성되는 물의 효과적인 전달을 위하여 매우 중요하다. 평행류 유로와 interdigitated 유로의 성능비교를 위하여 연료극과 공기극이 포함된 완전한 형태의 고분자 전해질 연료전지의 3차원 수치해석모델을 개발하였다. 수치해석모델을 사용하여 평행류 유동장과 interdigitated 유동장의 압력강하, 채널간의 물질전달, $H_2O$$O_2$의 농도 분포 그리고 i-V 성능을 비교하였다. 그 결과 물질전달에서 채널간의 대류에 의한 물질전할이 더욱 우수한 interdigitated 유동채널에서 성능이 더 높게 나타났으며 압력강하는 보다 크게 나타나 설계시 두가지 성능에 대한 상호보완이 필요함을 알 수 있었다.

교류 흐름 방식을 적용한 암모니아 공급 고체산화물 연료전지의 성능 분석 (Performance Analysis of Ammonia-Fed Solid Oxide Fuel Cell Using Alternating Flow)

  • 쿠엔;잡반티엔;이동근;이선엽;배용균;안국영;김영상
    • 한국수소및신에너지학회논문집
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    • 제33권5호
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    • pp.557-565
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    • 2022
  • The effect of flow configuration in ammonia-fed solid oxide fuel cell are investigated by using a three-dimensional numerical model. Typical flow configurations including co-flow and counter-flow are considered. The ammonia is directly fed into the stack without any external reforming process, resulting in an internal decomposition of NH3 in the anode electrode of the stack. The result showed that temperature profile in the case of counter-flow is more uniform than the co-flow configuration. The counter-flow cell, the temperature is highest at the middle of the channel while in the case of co-flow, the temperature is continuously increased and reached maximum value at the outlet area. This leads to a higher averaged current density in counter-flow compared to that of co-flow, about 5%.

단위-셀 실험과 전산유체해석을 통한 블록형 초고온가스로의 노심우회유량 평가 (ASSESSMENT OF CORE BYPASS FLOW IN A PRISMATIC VERY HIGH TEMPERATURE REACTOR BY USING UNIT-CELL EXPERIMENT AND CFD ANALYSIS)

  • 윤수종;진창용;김민환;박군철
    • 한국전산유체공학회지
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    • 제14권2호
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    • pp.59-67
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    • 2009
  • An accurate prediction of the bypass flow is of great importance in the VHTR core design concerning the fuel thermal margin. Nevertheless, there has not been much effort in evaluating the amount and the distribution of the core bypass flow. In order to evaluate the behavior and the distribution of the coolant flow, a unit-cell experiment was carried out. Unit-cell is the regular triangular section which is formed by connecting the centers of three hexagonal blocks. Various conditions such as the inlet mass flow rate, block combinations and the size of bypass gap were examined in the experiment. CFD analysis was carried out to analyze detailed characteristics of the flow distribution. Commercial CFD code FLUENT 6.3 was validated by comparing with the experimental results. In addition, SST model and standard k-$\varepsilon$ model were validated. The results of CFD simulation show good agreements with the experimental results. SST model shows better agreement than standard k-$\varepsilon$ model. Results showed that block combinations and the size of the bypass gap have an influence on the bypass flow ratio but the inlet mass flow rate does not.

교류 임피던스 측정법을 이용한 고분자 전해질 연료전지의 성능특성 분석 (Performance Analysis of Polymer Electrolyte Membrane Fuel Cell by AC Impedance Measurement)

  • 서상헌;이창식
    • 한국수소및신에너지학회논문집
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    • 제20권4호
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    • pp.283-290
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    • 2009
  • This study focuses on the performance characteristics of polymer electrolyte membrane fuel cell (PEMFC) using the AC impedance technique. The experiment was carried out to investigate the optimal operating conditions of PEMFC such as cell temperature, flow rate, humidified temperature and back-pressure. The fuel cell performance was analyzed by DC electronic-loader with constant voltage mode and expressed by voltage-current density. Additionally, AC impedance was measured to analysis of ohmic and activation loss and expressed by Nyquist plot. The results showed that the cell performance increased with increase of cell temperature, air flow rate, humidified temperature and backpressure. Also, the activation loss decreased as the increase of cell temperature, air flow rate, humidified temperature and backpressure.

신규항암제인 Heptaplatin의 인체 흑색종세포(SK-MEL-28)에 대한 세포생존률 및 유세포 분석 (Cell Viability and Flow Cytometry Analysis of a Novel Antitumor Agent, Heptaplatin in Human Melanoma Cell Line, SK-MEL-28)

  • 최수라;명평근
    • 약학회지
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    • 제47권6호
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    • pp.345-351
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    • 2003
  • Heptaplatin, cis-Malonato[(4R,5R)-4,5-bis(aminomethyl)-2-isopropyl-1,3-dioxolane]platinum(II), is a novel platinum-based antitumor agent with clinical potential against human stomach cancer and the 3rd generation of the cisplatin. This study was performed to study how cisplain, heptaplatin and sunpla which is a mixture of heptaplatin and mannitol (w: w=l : 2) affect cell viability of SK-MEL-28 human melanoma cell line. Heptaplatin ($IC_{50}$/; 95.35 $\mu$M) and sunpla ($IC_{50}$/; 10.95 11M) were less effect than cisplatin (IC $_{50}$; 10.92 $\mu$M) on the SK-MEL-28 cells. By cell cycle analysis using flow cytometry, it was identified that the cells were arrested at G2/M phase by cisplatin, heptaplatin and sunpla, and percentage of cell death group was increased according to increasing of time and concentration. These results suggest that cisplatin, heptaplatin and sunpla are a novel anticancer agent against human melanoma cell.l.

2-Bromopropane에 의한 유발된 Sprague-Dawley 랫트의 고환위축의 병리학적 관찰 및 Flow Cytometry를 이용한 검사 (Histopathological Observation and Flow Cytometry Analysis of Testicular Atrophy Induced by 2-Bromopropane On the Sprague-Dawley Rat)

  • 손화영;강부현;조성환;차신우;노정구
    • Toxicological Research
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    • 제14권2호
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    • pp.143-149
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    • 1998
  • This study was carried out to evaluate the testicular toxicity of 2-bromopropane (2-BP), which recently caused occupational intoxication on the reproductive and hematopoietic system in Koreans, using light microscopy, immunohistochemistry and flow cytometry. 10 weeks old male Sprague-Dawley (SD) rats were treated with 0.5 g/㎏/day of 2-BP orally for 8 consecutive weeks. The testes of the rats were vascularly perfused with Karnovsky's solution or immersed in Bouin's solution, embedded in plastic and evaluated with light microscopy. And relative proportions of haploid, diploid, and tetra-ploid states of DNA ploidy in the testicular cell suspensions of the SD rats were examined by flow cytometry. 2-BP induced severe testicular atrophy, depletion and degeneration of spermatogonia, spermatocytes, and spermatids and mild hyperplasia of Leydig cells without significant morphological changes. The Leydig cell hyperplasia was confirmed by immunohistochemistry using proliferating cell nuclear antigen (PCNA). The immunopositive cells against PCNA were observed in the nuclei oj some interstitial cells. Relative proportions of haploid states of DNA ploidy decreased in the atrophic testicular cell suspensions comparing with those of the control. In conclusion, 2-BP induced testicular atrophy with Leydig cell hyperplasia as examined by histopathology, immunohistochemistry and DNA flow cytometry.

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수동급기 직접 메탄올 연료전지의 유로에 따른 성능 평가 (Performance evaluation by flow channel effect for a passive air-breathing Direct Methanol Fuel Cell)

  • 장익황;하승범;차석원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.45-48
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    • 2008
  • This paper presents a passive air-breathing direct methanol fuel cell (DMFC) which has been designed and tested. The single cell is fuelled by methanol vapor that is supplied through flow channel from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The methods for supplying the methanol vapor to the single cell were parallel channel and chamber. This research investigates various methods to identify the effects of using flow channels for providing the methanol vapor at the anode, and the opening ratio between the inlet and outlet ports for the methanol flow at the anode. The best flow channel condition for passive DMFC was a chamber, and the opening ratio was 0.8. Under these conditions, the peak power was 10.2mW/$cm^2$ at room temperature and ambient pressure. The key issues for the Passive DMFCs for using methanol vapor are that sufficient methanol needs to be supplied using a large as possible opening ratio. However, it is shown that the performance of the passive DMFC, which has a channel at the anode,is low due to the low differential pressure and insufficient methanol supply rate.

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PECVD SiNx 박막의 다결정 실리콘 태양전지에 미치는 영향 (Influence of PECVD SiNx Layer on Multicrystalline Silicon Solar Cell)

  • 김정
    • 한국전기전자재료학회논문지
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    • 제18권7호
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    • pp.662-666
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    • 2005
  • Silicon nitride $(SiN_x)$ film is a promising material for anti-reflection coating and passivation of multicrystalline silicon (me-Si) solar cells. In this work, a plasma-enhanced chemical vapor deposition (PECVD) system with batch-type reactor tube was used to prepare highly robust $SiN_x$ films for screen-printed mc-Si solar cells. The Gas flow ratio, $R=[SiH_4]/[NH_3]$, in a mixture of silane and ammonia was varied in the range of 0.0910.235 while maintaining the total flow rate of the process gases to 4,200 sccm. The refractive index of the $SiN_x$ film deposited with a gas flow ratio of 0.091 was measured to be 2.03 and increased to 2.37 as the gas flow ratio increased to 0.235. The highest efficiency of the cell was $14.99\%$ when the flow rate of $SiH_4$ was 350 sccm (R=0.091). Generally, we observed that the efficiency of the mc-Si solar cell decreased with increasing R. From the analysis of the reflectance and the quantum efficiency of the cell, the decrease in the efficiency was shown to originate mainly from an increase in the surface reflectance for a high flow rate of $SiH_4$ during the deposition of $SiN_x$ films.

후방 발열이 있는 경사 충격파의 불안정성 (INSTABILITY OF OBLIQUE SHOCK WAVES WITH HEAT ADDITION)

  • 최정열;신재렬;조덕래
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2007년도 추계 학술대회논문집
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    • pp.232-235
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    • 2007
  • A comprehensive numerical study was carried out to identify the on-set condition of the cell structures of oblique detonation waves (ODWs). Mach 7 incoming flow was considered with all other flow variables were fixed except the flow turning angles varying from 35 to 38. For a given flow conditions theoretical maximum turning angle is $38.2^{\circ}$ where the oblique detonation wave may be stabilized. The effects of grid resolution were tested using grids from $255{\times}100$ to $4,005{\times}1,600$. The numerical smoked foil records exhibits the detonation cell structures with dual triple points running opposite directions for the 36 to 38 turning angles. As the turning angle get closer to the maximum angle the cell structures gets finer and the oscillatory behavior of the primary triple point was observed. The thermal occlusion behind the oblique detonation wave was observed for the $38^{\circ}$ turning angle.

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