• Composites Research
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• v.35 no.6
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• pp.456-462
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• 2022

Since natural fibers are highly flammable, it is not easy to make them flame retardant. In this study, a liquid flame retardant based on phytic acid, APTES, and Thiourea, which are flame retardant candidates derived from nature, was prepared and its performance was verified through flame retardant treatment and flame retardancy evaluation of bamboo fibers. When a liquid flame retardant is used, it is possible to treat a large amount of natural fibers with flame retardant treatment. Nine types of flame-retardant treated bamboo fibers were prepared according to the Taguchi design of experiment method. Thereafter, vertical burning test and microcalorimeter test were performed for flame retardancy evaluation, and the surface of natural fibers before and after flame-retardant treatment was compared using scanning electron microscope. The results show that phytic acid has a significant effect on improving the flame retardancy of natural fibers. Through microstructure analysis, it was assumed that the phytic acid helps flame retardant to uniformly adhere to the surface of natural fibers. If such research results are utilized, it is possible to make a large amount of natural fibers high flammability in an eco-friendly way, which is expected to be advantageous for the application of prototypes.

• Journal of the Korean Wood Science and Technology
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• v.30 no.2
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• pp.172-179
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• 2002

In this study, two materials treated with a flame retardant were examined for their fire resistance. The first, MDF (medium density fiberboard) was overlaid by an oak sliced veneer, which was either treated by soaking in a 6wt.% solution of flame retardant chemicals (pentabromine-chlorinated paraffin) or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. The second material, Pinus koraiensis penal was either treated by a spray treatment using a flame retardant solution or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. Pentabromine-chorinated paraffin chemicals were added (6 part of urethane resin) as the flame retardant chemicals in the polyurethane coatings. In the fire resistance test, the th𝜃(℃·min) decreased with the flame retardant treatment or/and the flame retardant coatings, compared to the untreated sample Weight loss (%) decreased with the flame retardant treatment or/and the flame retardant coatings. The ignition time (sec.) increased and the residual flame time (sec.) decreased with the flame retardant treatment or/and flame retardant coatings. Therefore, the flame retardant treatment or/and flame retardant polyurethane coatings have excellent incombustibility.

• Journal of the Korean Wood Science and Technology
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• v.51 no.5
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• pp.410-418
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• 2023

In this study, the combustion characteristics of the Tulip tree, which is the representative broad-leaved afforestation tree in Korea, were analyzed. The flame retardant performance of the Tulip tree was analyzed by analyzing combustion characteristics on a total of three test samples; flame retardant treated, both flame retardant and oil stain-treated, and untreated. Then the flame retardance grade was classified for each of them. According to the result, test samples showed the strongest flame retardance were in order of flame retardant treated (C), both flame retardant and oil stain-treated (B), and untreated (A). As a result of analyzing the total heat emission and maximum heat emission rates, which is the evaluation standard for interior materials of Korean domestic buildings, test samples with flame retardant treat or flame retardant and oil stain treat were qualified for the flame-retardant standard. Both flame retardant and oil stain-treated samples showed higher total heat release (THR) and heat release rate compared to flame retardant-treated samples as the oil causes combustion with oxygen. On the other hand, they didn't qualify the THR in Quasi-non-combustible standards. To determine the correlation between the physical and combustion characteristics of wood, the combustion characteristics of other diffuse porous wood species, with which the Tulip tree is affiliated were analyzed, and noticed that the characteristic correlates with the density and quantity of wood. The results of this study are expected to be used as basic information on the combustion characteristics of the Tulip tree.

• Journal of the Korea Safety Management & Science
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• v.25 no.1
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• pp.61-66
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• 2023

The purpose of this study is to compare and analyze the flame retardant performance of Japanese cypress(Chamaecyparis obtusa) plywood, commonly used in indoor decoration, furniture, and tableware, by treating it with three different fire retardants with different primary ingredients. The experiment was conducted in compliance with Article 31, Paragraph 2 of the Enforcement Decree of the Fire Facilities Installation and Management Act and Articles 4 and 7-2 of the Flame Retardant Performance Standards. After flame time, after glow time, char length, and char area were measured. As a result, first, after flame time was measured at 0 seconds regardless of whether the flame retardant treatment was applied. Second, after glow time was relatively long, measuring 22.7 seconds without treatment, which is likely due to the weak fire resistance and high concentration of carbon monoxide generated by the chemical characteristics of the Japanese cypress itself. Third, it was confirmed that the effects of the primary ingredient, phosphorus, in the flame retardant treatment varied depending on the technological development of the manufacturers of the same species of Japanese cypress plywood. In the future, it is expected that the results of this study will provide fundamental data to select flame retardant treatments that show high flame retardant performance according to the botanical characteristics of the wood.

• Journal of the Korean Wood Science and Technology
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• v.33 no.4 s.132
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• pp.38-44
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• 2005

This study was carried out to investigate the combustion characteristics of flame retardant treated wood by water-soluble flame retardants which are made from mixture of aqueous solution of monoammonium phosphate, sodium borate and zinc borate. The combustion characteristics for flame retardant treated wood were carried out using thermal analysis (TGA, combustion heat) and flame retardant test (LOI, flame propagation). The results of thermal analysis and flame retardant test are as follows; 1) The sample treated by F4 showed excellent flame retardant effects in almost all of combustion characteristics. 2) From TGA curves, all the samples undergo pyrolysis and oxidation in two main discrete steps. 3) The effect of flame retardant for softwood is higher than those for hardwood, and the combustion heat has decreased with increase of the content of flame retardant. 4) LOI values are almost similar in flame retardant treated wood samples. The range of LOI is from 24 to 30. However, these values are much higher than LOI value of non-treated wood sample. 5) The blended aqueous solution had a final in the range of about pH 8.4, and a slight odor of ammonia.

• Journal of Adhesion and Interface
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• v.20 no.4
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• pp.135-139
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• 2019

In this work, flame retardant acrylic emulsion pressure sensitive adhesives were newly polymerized combining phosphorous flame retardant monomer and acrylic monomer like butyl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, acrylic acid, and 2-hydroxyethyl methacrylate. The process of polymerization showed 100% of conversion at solid content of 65%, and viscosity of acrylic emulsion was increased up to 5500 cps when phosphorous flame retardant monomer was added into acrylic emulsion. The structure of flame retardant acrylic emulsion was identified using FT-IR and thermal properties like glass transition temperature (Tg) were checked by differential scanning calorimeter (DSC). Acrylic emulsion without phosphorous flame retardant monomer had Tg of -44.1℃ and peel strength of 2,100gf/inch, however, flame retardant acrylic emulsion showed maximum Tg (-31.4℃) and peel strength of 200gf/inch when 15 part of phosphorous flame retardant monomer was added. Flammability test was also conducted to confirm the application of flame retardant acrylic emulsion as the flame retardant addtive.

• Journal of the Korean Wood Science and Technology
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• v.48 no.4
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• pp.417-430
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• 2020

The flame retardancy, such as carbonized length and area, of four plank type wood products by the spreading concentration and impregnation time of flame retardant were measured according to standard of the Nation Fire Agency in Republic of Korea. To measure the flame retardancy, Korean pine plywood, Japanese larch plywood, Japanese cypress planks, and perforated birch plywood boards were treated with self-development flame retardant by 300 and 500 g/㎡ spreading concentration and those were compared with control specimen. In general, the flame retardant performance of wood products improved as the spreading concentration of flame retardant increased. Except for Japanese larch plywood, there was no significant difference in the flame retardant performance by the spreading concentration. The flame retardant performance of perforated birch plywood board was positively correlated up to 60 minutes of impregnation time, but then gradually decreased. These results about the flame retardancy of wood products by spreading concentration and impregnation time were expected to be basic data for improving flame-retardant treated wood.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2010.03a
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• pp.167-168
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• 2010

Non coating type Low melting yarn(L/M PET) not to use the polyurethane resin causing some problems was knitting and evaluated its dyeing characteristics, heat setting properties and flame-retardant properties without flame retardant agent or flame retardant fabric. In order to investigate the dyeing property of fabric of L/M PET, the dyeing of L/M PET was experimented at each different dyeing temperature. Higher exhaustion yield was achieved at lower temperature of L/M PET compared to regular PET. According to result of the study for the heat setting properties of L/M fiber, the K/S value of dyed L/M fiber increased as much as the heat setting temperature did. The experiment for the light fastness reached similar result to dyed PET. However washing fastness in L/M fiber showed lower grade compared with regular PET. flame-retardant efficiency of L/M PET without flame retardant agent or flame retardant fabric measured by $45^{\circ}$ burn test and Contact burn test. The flame?retardant performance of the sample was carried out according to the Korea Fire-fighting Standard.[KOFEIS 1001].

• Journal of the Korean Wood Science and Technology
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• v.49 no.6
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• pp.667-678
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• 2021

The flame retardancy of plywood should be improved as much as possible while minimizing the impact on the bonding strength of plywood. Six commercial flame retardants and three laboratory synthesized phosphorous nitrogen flame retardants were selected. E₀, E₁ and E₂ grade commercial formaldehyde resins (UF) were applied in this study to evaluate the effect of different flame retardants on the curing time of resin, bonding strength, flame retardant performance, and formaldehyde emission of plywood. The results show that the effect of the addition of different flame retardants on the bonding strength of plywood gradually decreased with the increase of the formaldehyde molar ratio of the resin. The effect of flame retardants on the curing time of UF gradually decreased as the mole ratio of formaldehyde increasing, while the amount of formaldehyde emission varied according to the content of formaldehyde in the flame retardant. Compared with plywood without flame retardant, flame retardant of plywood added with phosphorous nitrogen flame retardant was improved.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.2
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• pp.178-183
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• 2022

For enhancing the flame-retardant properties of wallpapers, we developed an organic-inorganic hybrid solution with ZrSiO₄ as a functional ceramic powder, coated on non-woven fabric using dip coating, spray coating, and slot-die coating methods. Their flame retardant properties were characterized by a 45° combustion tester, which is manufactured according to the flame-retardant performance standard (KOFEIS 1001 and KS F 2819). In organic-inorganic hybrid solution, with increasing the concentration of acid-catalyst (acetic acid), the precipitation of ZrSiO₄ powders increased, and the flame retardant properties decreased. The highest flame retardant result was obtained for the solution adding 5 wt% acetic acid. The optimization of the coating method and coating number resulted in the most excellent flame-retardant properties being obtained for the non-woven fabric coated for 5 or 7 times by dip coating method, and their flame-retardant properties corresponded to class 2 flame-retardant performance of wallpapers.