• 제목/요약/키워드: first principle calculation

검색결과 74건 처리시간 0.03초

Ni이 첨가된 $MnO_2$ 산화물전극의 전자상태 계산 (Calculation of Electronic State of MnO2 Oxide Electode Having Ni Additive)

  • 이동윤;김봉서;송재성
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2002년도 하계학술대회 논문집 C
    • /
    • pp.1515-1517
    • /
    • 2002
  • $MnO_2$ is used for the oxide electrode of electrochemical equipments because of its good electric conductivity and low oxygen overpotential. The effect of additives on the properties of $MnO_2$ has been investigated to enhance the electric conductivity and the stability in an acid solution. In this research, the effect of Ni addition on ${\beta}-MnO_2$ was studied by the theoretical quantum chemical method. The calculation was carried out by the discrete variation $X{\alpha}$ method, which is a sort of the first principle method and use Hatre-Fock-Slater approximation. The electron energy level, the density of state, the bond overlap population, the charge density distribution and the net ionic transfer between cations and anions were calculated and discussed. The used cluster model was $(Mn_{10}NiO_{44})^{-44}$.

  • PDF

분자궤도계산법에 의한 $\beta$-$MnO_2$의 전자상태 및 화학결합 계산 (Calculation on Electronic State and Chemical Bonding of $\beta$-$MnO_2$ by DV-X$\alpha$ Method)

  • 이동윤;김봉서;송재성;김현식
    • 한국결정학회지
    • /
    • 제14권1호
    • /
    • pp.16-23
    • /
    • 2003
  • β-MnO₂ 전자상태와 화학결합을 하트리-폭-슬레이터 근사를 사용하는 제 1원리 분자 궤도법의 일종인 DV-X/sub α/ 법에 의해 이론적으로 조사하였다. 벌크상의 β-MnO₂에 대한 상태를 해석하기에 적합한 클러스터 모델을 결정하기 위하여, 여러 가지 다른 크기를 지닌 수종의 클러스터 모델들에 대한 계산을 행하였다. 실험적으로 측정된 XPS와 이론적으로 계산된 XPS를 비교함으로써, Mn/sub 15/O/sub 56/ 모델이 β-MnO₂의 전자 상태와 화학 결합을 계산하기에 가장 적합한 모델임을 결정하였다. 이 모델을 사용하여 에너지 준위, 상태 밀도, 유효 공유 결합 전하, 유효 전하, 전자 밀도 분포를 구하고, 이에 대한 고찰을 행하였다.

멀티콥터 영상 전송을 위한 압축 센싱 기법 (Compressed Sensing Techniques for Video Transmission of Multi-Copter)

  • 정국현;이선의;이상화;김진영
    • 한국위성정보통신학회논문지
    • /
    • 제9권2호
    • /
    • pp.63-68
    • /
    • 2014
  • 본 논문에서는 멀티콥터의 효율적 영상 전송을 위해 필요한 압축센싱 기법을 제안한다. 제안된 구조는 압축센싱에 기반한 데이터 용량을 줄이는 것에 중점을 둔다. 우선 Spectrum sensing의 기본원리를 설명하고 AMP(Approximate Message Passing)와 CoSaMP(Compressive Sampling Matched Pursuit)을 수학적 분석과 모의실험 결과를 통해서 비교한다. 또한 두 알고리즘을 계산시간과 복잡도 관점에서 평가하고 멀티콥터 동작에 적합한 알고리즘을 제안한다. 본 논문의 실험결과는 AMP 알고리즘이 CoSaMP 알고리즘보다 계산시간이 적고 이미지 에러 확률도 낮다는 것을 보여준다.

(두 자리 수)×(한 자리 수)의 계산 원리 탐구 - 퀴즈네어 막대와 배열 모델을 활용한 수업 사례 연구 - (Exploring the Principle of Computation between Two-Digit Number and One-Digit Number: A Case Study of Using Cuisenaire Rods and Array Models)

  • 김정원;방정숙
    • 대한수학교육학회지:수학교육학연구
    • /
    • 제27권2호
    • /
    • pp.249-267
    • /
    • 2017
  • 3학년 1학기의 곱셈 단원에서는 2학년에서 다룬 (한 자리 수)${\times}$(한 자리 수)인 곱셈 구구를 바탕으로 (두 자리 수)${\times}$(한 자리 수)의 계산을 다룬다. 학생들은 종종 계산은 잘 하면서도 정작 계산 원리를 이해하지 못하는 경향이 있다. 이에 본 연구는 퀴즈네어 막대와 배열 모델을 활용하여 곱셈의 계산 원리를 학생들이 탐구할 수 있도록 수업을 설계하고 실행하였다. 연구결과, 대부분의 학생들은 퀴즈네어 막대와 배열 모델을 통하여 곱셈의 원리를 이해하고 이를 곱셈식으로 나타낼 수 있었으며, 특히 곱셈식을 다양하게 해결하는 과정에서 결합법칙이나 분배법칙을 자연스럽게 발견할 수 있었다. 몇몇 학생들은 처음에 모델이나 곱셈식을 표현하는 과정에서 어려움을 드러내기도 하였으나 수업이 진행됨에 따라 보다 성공적으로 수행할 수 있었다. 본 연구 결과를 토대로 수와 연산의 성질을 적용하여 곱셈의 계산 원리를 의미있게 지도할 수 있는 방안에 대한 시사점을 제공한다.

조명디자인 교육연구 (A Study on Lighting Design Education)

  • 안희영
    • 한국실내디자인학회논문집
    • /
    • 제17호
    • /
    • pp.128-135
    • /
    • 1998
  • The first issue was concerning the subject to provide students with an understanding of the principle of light its concept mental factors etc and with the observation and analysis of the light of an object and its form which is the process for designers to be able to deal with the deeper design concept by complementing the setting of necessary concept. The second issue was concerning the process of basic learning about basic electricity and lighting that lighting designers or interior decoration and architecture designer should have such as the introduction of light in kind of light source lighting system and so forth. The third issue was focused on practical affairs such as design and expression techniques the calculation of illumination using the computer simulation and so on. In addition such issues as the history of lighting photograph and its linkage with the field of engineering about new material ware addressed.

  • PDF

다변수 변분해법에 의한 비적합 8절점 육면체 요소 (Incompatible Three-Dimensional Hexagonal Finite Elements by Multivariable Method)

  • 주상백;신효철
    • 대한기계학회논문집A
    • /
    • 제20권7호
    • /
    • pp.2078-2086
    • /
    • 1996
  • This paper introduces two three-dimensional eight-node hexagonal elements obtained by using multivariable variational mehtod. Both of them are based on the modified hellinger-reissner principle to employ incompatible displacements and assumed stresses of assumed strains. The internal functions of element are introduced to as element formulation through two different methods : the first one uses the functions determined directly from the element boundary condition of the incompatible displacements ; while the second, being a kind of B-bar mehtod, employs the modification technique of strain-displacement matrix to pass the patch test. The elements are evaluated on the selective problems of bending and material incompressibility with regular and distorted meshes. The results show that the new elements perform with good accuracy in both of deformation and stress calculation and they are insensitive to distorted geometry of element.

Efficient Generation of Computer-generated Hologram Patterns Using Spatially Redundant Data on a 3D Object and the Novel Look-up Table Method

  • Kim, Seung-Cheol;Kim, Eun-Soo
    • Journal of Information Display
    • /
    • 제10권1호
    • /
    • pp.6-15
    • /
    • 2009
  • In this paper, a new approach is proposed for the efficient generation of computer-generated holograms (CGHs) using the spatially redundant data on a 3D object and the novel look-up table (N-LUT) method. First, the pre-calculated N-point principle fringe patterns (PFPs) were calculated using the 1-point PFP of the N-LUT. Second, spatially redundant data on a 3D object were extracted and re-grouped into the N-point redundancy map using the run-length encoding (RLE) method. Then CGH patterns were generated using the spatial redundancy map and the N-LUT method. Finally, the generated hologram patterns were reconstructed. In this approach, the object points that were involved in the calculation of the CGH patterns were dramatically reduced, due to which the computational speed was increased. Some experiments with a test 3D object were carried out and the results were compared with those of conventional methods.

The Concept of a Gravity Engine and Energy Performance for Tidal and Hydro-Power

  • Lee, Jae-Young
    • 에너지공학
    • /
    • 제9권1호
    • /
    • pp.47-53
    • /
    • 2000
  • This paper is to propose the concept and performance of a gravity engine which could extract energy from sea or river as a clean. renewable and sustainable power. the vertical motion of the buoyancy cylinder of the present gravity engine is converted to the mechanical work directly without any hydraulic loss. The positive net energy between the imposed and harnessed one is achieved by the specific operating procedure. The detailed derivation of the energy balance is made based on the first principle of thermodynamics. The calculation demonstrates that the present gravity engine could harness more energy than the conventional turbine system in the same basin area because of the relatively high efficiency in the energy conversion system and added mass from the buoyancy cylinder.

  • PDF

열팽창 분사식 가스차단부의 소호실내 압력상승 계산 (Calculation of Pressure Rise in a Thermal-expansion Type Arc Chamber)

  • 최영길;오연호;신영준;박경엽;김희진
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1998년도 하계학술대회 논문집 A
    • /
    • pp.167-169
    • /
    • 1998
  • Recently $SF_6$ gas circuit breakers utilizing the thermal-expansion principle are increasingly used in distribution power system. Active researches and developments have been conducted to reduce the size and weight, and to improve the interrupting performance of the circuit breakers. It was first developed a programme which could show the hot gas flowing into the thermal-expansion arc chamber. This programme, using so-called FLIC method basically, adopted 'Simplified Enthalpy Arc Model' which was somewhat modified to estimate the arc quenching process. The computation by it was compared with the measured results of the pressure rise in the chamber, and both showed fairly good agreement.

  • PDF

다층 케이블 돔형 구조물의 자기평형을 위한 부재력 비율 결정 (Determination of Member Force Ratios for Self-equilibrium State of Multi-Layered Cable Dome Type Structures)

  • 김재열
    • 한국공간구조학회논문집
    • /
    • 제13권2호
    • /
    • pp.75-82
    • /
    • 2013
  • For each cable component in a cable dome structure, pre-tension is needed for stability of whole the structure. The summation of these pre-tension at each joint should be zero to achieve the self equilibrium structure. The first step in cable dome structure analysis is to find the ratio of pre-tension in each member which can produce a stable and structure on self-equilibrium. In this paper, a new method based on the basic principle of closed force polygon for equilibrium system is proposed for the determination of self-equilibrium mode of cable dome structure. A single layer cable dome and two multi layer type domes have been analyzed. The ratios of cable members are determined by the presented method, and check the validation of the results by numerical calculation.