• Title/Summary/Keyword: fine particles

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Reinforcement of Porous Mullite Ceramics Using Ultra Fine Mullite Precursor Powders

  • Cho, Yong-Ick;Hisao Suzuki;Hidehiro Kamiya
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.137-141
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    • 1999
  • To increase the strength of high-purity porous mullite ceramics, ultra fine mullite precursor powders of about 10nm in diameter were deposited at point of contact between primary coarse mullite particles of about 60$\mu\textrm{m}$. The deposited and hetero coagulated structures of ultra fine mullite precursor powders were controlled by pH. The optimum pH condition to form a uniform deposition of mullite powders between coarse mullite particles was in the range from 7 to 8. Deposition of the ultra fine powders did not form at pH < 7 and pH > 10 irregular deposition was observed from pH 8 to 9.

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Computer Simulation of Sintering and Grain Growth

  • Matsubara, Hideaki
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.324-328
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    • 1998
  • This paper is aimed to study the computer simulation of sintering process for ceramics by Monte Carlo and molecular dynamics methods. Plural mechanisms of mass transfer were designed in the MC simulation of sintering process for micron size particles; the transfer of pore lattices for shrinkage and the transfer of solid lattices for grain growth ran in the calculation arrays. The MD simulation was performed in the case of nano size particles of ionic ceramics and showed the characteristic features in sintering process at atomic levels. The MC and MD simulations for sintering process are useful for microstructural design for ceramics.

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Self-assembly of Fine Particles Applied to the Production of Antireflective Surfaces

  • Kobayashi, Hayato;Moronuki, Nobuyuki;Kaneko, Arata
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.1
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    • pp.25-29
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    • 2008
  • We introduce a new fabrication process for antireflective structured surfaces. A 4-inch silicon wafer was dipped in a suspension of 300-nm-diameter silica particles dispersed in a toluene solution. When the wafer was drawn out of the suspension, a hexagonally packed monolayer structure of particles self-assembled on almost the complete wafer surface. Due to the simple process, this could be applied to micro- and nano-patterning. The self-assembled silica particles worked as a mask for the subsequent reactive ion etching. An array of nanometer-sized pits could be fabricated since the regions that correspond to the small gaps between particles were selectively etched off. As etching progressed, the pits became deeper and combined with neighboring pits due to side-etching to produce an array of cone-like structures. We investigated the effect of etching conditions on antireflection properties, and the optimum shape was a nano-cone with height and spacing of 500 nm and 300 nm, respectively. This nano-structured surface was prepared on a $30\;{\times}\;10-mm$ area. The reflectivity of the surface was reduced 97% for wavelengths in the range 400-700 nm.

Biocompatible Dispersion Methods for Carbon Black

  • Kim, Hwa;Park, Kwangsik;Lee, Moo-Yeol
    • Toxicological Research
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    • v.28 no.4
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    • pp.209-216
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    • 2012
  • The biological activity of particles is largely dependent on their size in biological systems. Dispersion in the aqueous phase has been both a critical impediment to and a prerequisite for particle studies. Carbon black has been used as a surrogate to investigate the biological effects of carbonaceous particles. Here, biocompatible methods were established to disperse carbon black into ultrafine and fine particles which are generally distinguished by the small size of 100 nm. Carbon black with a distinct particle size, N330 and N990 were suspended in blood plasma, cell culture media, Krebs-Ringer's solution (KR), or physiological salt solution (PSS). Large clumps were observed in all dispersion preparations; however, sonication improved dispersion - averaged particle sizes for N330 and N990 were $85.0{\pm}42.9$ and $112.4{\pm}67.9$ nm, respectively, in plasma; the corresponding sizes in culture media were $84.8{\pm}38.4$ and $164.1{\pm}77.8$ nm. However, sonication was not enough to disperse N330 less than 100 nm in either KR or PSS. Application of Tween 80 along with sonication reduced the size of N330 to less than 100 nm, and dispersed N990 larger than 100 nm ($73.6{\pm}28.8$ and $80.1{\pm}30.0$ nm for N330 and $349.5{\pm}161.8$ and $399.8{\pm}181.1$ nm for N990 in KR and PSS, respectively). In contrast, 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) exhibited little effect. Electron microscopy confirmed the typical aciniform structure of the carbon arrays; however, zeta potential measurement failed to explain the dispersibility of carbon black. The methods established in this study could disperse carbon black into ultrafine and fine particles, and may serve as a useful model for the study of particle toxicity, particularly size-related effects.

Particle Transport of Residual Soils (풍화잔적토의 유동특성에 대한 연구)

  • 이인모;박광준
    • Geotechnical Engineering
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    • v.13 no.5
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    • pp.155-168
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    • 1997
  • The phenomena of detachment and movement of One particles are one of the important mechanisms both in geotechnical and geoenvironmental engineering. In geoenvironmental engineering, in particular, movement of fine particles may facilitate the transport of contaminants since the particle surfaces absorb contaminants before movement. Weathered granitic residual soils, which are the most abundant in Korea. contain large quantities of fine particles up to 50%. The characteristics of fine particle movement of weathered granitic residual soils are investigated in this paper. Samples are obtained from Poiiong, Shinnaedong in Seoul and Andong in Kyungpook : each of the samples represents typical residual soil types in Korea. Laboratory experiments for the three adopted soil types are performed. It is found that effluent concentration of the samples is influenced by porosity, fine particle percentage and particle size distribution. The critical velocity decreases as the fine particle percentage increases and the rate of change of erosion rate increases as the porosity increases. And well-graded samples showed less effluent concentrations compared to poorly-graded samples. The governing equation on the physical mechanism of fine particle movement and its nomerical solution scheme are suggested on the basis of the test results.

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Properties of Roadway Particles from the Interaction between Tire and Road Pavement (차량 주행 과정에서 타이어와 도로의 마찰에 의해서 발생하는 도로입자의 특성연구)

  • Lee, Seok-Hwan;Kim, Hong-Seok;Park, Jun-Hyuk;Woo, Se-Jong;Kwak, Ji-Hyun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.6
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    • pp.24-32
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    • 2012
  • A large fraction of urban $PM_{10}$ concentrations is due to non-exhaust traffic emissions including road dust, tire wear particles, and brake lining particles. Although potential health and environmental impacts associated with tire wear debris have been increased, few environmentally and biologically relevant studies of actual tire wear debris have been conducted. Tire wear particles (TWP) are released from the tire tread as a result of the interaction between the tire and the pavement. Roadway particles (RP), meanwhile, are particles on roads composed of a mixture of elements from tires, pavements, fuels, brakes, and environmental dust. The main objective of present study is to identify the contribution of tires to the generation of RP and to assess the potential environmental and health impacts of this contribution. First, a mobile measurement system was constructed and used to measure the roadway particles on asphalt road according to vehicle speed. The equipment of the mobile system provides $PM_{10}$ concentrations by Dusttrak DRX and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and an aerosol particle sizer (APS). When traveling on an asphalt road at constant speed, there is a clear tendency for PM10 concentration to increase slightly in accordance with an increase in the vehicle speed. It was also found that considerable brake wear particles and particles from tire/road interface were generated by rapid deceleration of the vehicle. The morphology and elements of the roadway particles were also analyzed using SEM-EDX technique.

Change in the Concentration of Fine Particles, Temperature, and Relative Humidity as Affected by Different Volume Ratios of Interior Greening in Real Indoor Space (실내녹화 부피비율이 실공간의 미세분진농도, 온도 및 상대습도에 미치는 영향)

  • Ju, Jin-Hee
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.13 no.2
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    • pp.1-7
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    • 2010
  • The study objective was to compare the interior greening volume ratios for the change in concentration of fine particle, temperature and relative humidity, and to identify the level of interior landscape volume ratio as a suitable condition to achieve the desired indoor properties. Plants were moved into a room (88m3) randomly. After moving, the volume ratio of the interior greening level was set at 0%, 1%, 2% and 3%. The concentration of fine particles was measured with a mini-volume portable air sampler (Air Metrics, USA). The temperature and relative humidity were recorded with a digital sensor (Kiwi-LTH, USA) during the experiment under different volume ratios with three replications. 1. The results of the change in concentration of the fine particles revealed a trend towards an increased volume ratio of interior greening with decreasing concentration of fine particles, compared to non-plants (0%). The concentration of fine particles at volume ratios of 0%, 1%, 2% and 3% was 55ug/$m^3$, 233ug/$m^3$, 40ug/$m^3$ and 30ug/$m^3$, respectively. 2. The change in temperature, at volume ratios of 0%, 1%, 2% and 3% was $21.2^{\circ}C$, $17.4^{\circ}C$, $16.7^{\circ}C$ and $18.9^{\circ}C$, respectively, in near interior greening, and $22.1^{\circ}C$, $18.7^{\circ}C$, $18.4^{\circ}C$ and $20.5^{\circ}C$ respectively, at a distance of 3m from the interior greening. These study results suggested that temperature was affected by volume ratio and distance from the interior greening. 3. The relative humidity, at volume ratios of 0%, 1%, 2% and 3% was 34.2%, 32.5%, 36.7%, and 46.9%, respectively, in near interior greening, and 31.2%, 26.9%, 31.4% and 38.3%, respectively, at a distance of 3m from the interior greening. With increasing volume ratio of interior landscape, there were positive and significant results between the distance difference and the relative humidity more than temperature.

Remediation of Soils Contaminated with Arsenic and heavy Metals by Soil Washing (토양세척에 의한 비소 및 중금속 오염토양의 복원)

  • Ko Ilwon;Lee Cheol-Hyo;Lee Kwang-Pyo;Kim Kyoung-Woong
    • Journal of Soil and Groundwater Environment
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    • v.9 no.4
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    • pp.52-61
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    • 2004
  • In order to remediate soils contaminated with oxyanionic As and cationic Zn and Ni through the pilot-scale acid washing, the effectiveness of acid washing and the properties of contaminated soils, fine soil particle and dissolved contaminants were evaluated. $H_{2}SO_4\;and\;H_{3}PO_4$ washing at pH $2{\sim}3$ enhanced the removal of As by the presence of competitive oxyanions and HCl washing effectively removed simultaneously As, Zn and Ni. The effectiveness of soil washing was little enhanced above the critical reaction time, and the carbonate, Fe/Mn oxide and organic/sulfides associated fraction were dominantly removed. The washing of coarse soil particles was highly efficient, but that of fine soil particles($<74{\mu}m$) was recalcitrant due to the enrichment with contaminants. Moreover, the physical separation of fine particles($<149{\mu}m$) enhanced the overall efficiency of soil washing. Therefore, both chemical extraction and separation of fine soil particles showed the high effectiveness of soil washing in the intersection point to minimize the amount of fine soil particles and to maximize the chemical extraction of contaminants.

Japanese Measurement on Fine Particles(PM2.5) Emission Pollution and Cooperation of Korea -China-Japan to Reduce Fine Particles Pollution- (일본의 미세먼지 대책과 미세먼지 저감을 위한 한중일 협력)

  • Lee, Soocheol
    • Environmental and Resource Economics Review
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    • v.26 no.1
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    • pp.57-83
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    • 2017
  • The Japanese government's attempts to reduce fine particles (PM2.5) emission pollution in Japan have been largely ineffective. This is because PM2.5 in Japan originated from various sources including around half from oversea countries such as China. This prompts the Japanese government to start a new initiative to reduce PM2.5 at its origin by transferring local knowledge on air pollution reduction measures and technologies to China and working closely with the Chinese government. To promote further reduction in PM2.5, bilateral corporation between Japan and China should be extended to include Korea. It is recommended that an international convention should be in place to deal with transboundary air pollutants in East Asia. A successful East Asia corporation to reduce PM2.5 will not only contribute to clean air but also to future sustainable low carbon society in this region.