• 제목/요약/키워드: film property

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코팅 두께에 따른 친수성 무기 필름의 특성 분석 (Properties Characterization of the Hydrophilic Inorganic Film as Function of Coating Thickness)

  • 정연호;최원석;신용탁;이민지;김희곤
    • 한국전기전자재료학회논문지
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    • 제26권6호
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    • pp.425-428
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    • 2013
  • In this paper, we present a novel hydrophilic coating material (Wellture Finetech, Korea) which can be utilized as a coating layer for anti-contamination for electrical and electronic system. The coating material was deposited on 4 inch silicon wafer with several different film thickness. The film thickness was controlled by spin coating speed. After curing of the film, we have scratched by permanent marker to check self-cleaning property of the film. Also we have executed several mechanical tests of the films. As the spin coating speed is increased, the film thickness was thinned from 230 nm to 125 nm. Contact angle of the film was lowered from $30^{\circ}$ to $12^{\circ}$ as the spin coating speed is increased from 700 to 2,500 rpm. On permanent marker scratched film surface coated at 1,000 rpm, we have poured regular city water to investigate self cleaning property of the film. The scratches were gradually separated from the film surface due to super-hydrophilicity of the film. Hardness of spin coated film was 9H measured by ASTM D3363 method. and adhesion of all film was 5B tested by ASTM D3359 method. Also, to get exact hardness value of the film, we have utilized a nano-indenter. As spin speed is increased, the hardness of film was increased from 3 GPa to 5 GPa.

플라즈마 공중합 고분자 절연막과 펜타센 반도체막의 계면특성 (Interface Charateristics of Plasma co-Polymerized Insulating Film/Pentacene Semiconductor Film)

  • 신백균;임헌찬;육재호;박종관;조기선;남광우;박종국;김용운;정무영
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1349_1350
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    • 2009
  • Thin films of pp(ST-Co-VA) were fabricated by plasma deposition polymerization (PVDPM) technique. Properties of the plasma polymerized pp(ST-Co-VA) thin films were investigated for application to semiconductor device as insulator. Thickness, dielectric property, composition of the pp(ST-Co-VA) thin films were investigated considering the relationship with preparation condition such as gas pressure and deposition time. In order to verify the possibility of application to organic thin film transistor, a pentacene thin film was deposited on the pp(ST-Co-VA) insulator by vacuum thermal evaporation technique. Crystalline property of the pentacene thin film was investigated by XRD and SEM, FT-IR. Surface properties at the pp(ST-Co-VA)/pentacene interface was investigated by contact angle measurement. The pp(ST-Co-VA) thin film showed a high-k (k=4.6) and good interface characteristic with pentacene semiconducting layer, which indicates that it would be a promising material for organic thin film transistor (OTFT) application.

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Zirconium Titanate Thin FIlm Prepared by Surface Sol-Gel Process and Effects of Thickness on Dielectric Property

  • Kim, Chy-Hyung;Lee, Moon-Hee
    • Bulletin of the Korean Chemical Society
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    • 제23권5호
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    • pp.741-744
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    • 2002
  • Single phase of multicomponent oxide ZrTiO4 film could be prepared through surface sol-gel route simply by coating the mixture of 100 mM zirconium butoxide and titanium butoxide on $Pt/Ti/SiO_2Si(100)$ substrate, following pyro lysis at $450^{\circ}C$, and annealing it at 770 $^{\circ}C.$ The dielectric constant of the film was reduced as the film thickness decreased due to of the interfacial effects caused by layer/electrode and a few voids inside the multilayer. However, the dielectric property was independent of applied dc bias sweeps voltage (-2 to +2 V).The dielectric constant of bulk film, 31.9, estimated using series-connected capacitor model was independent of film thickness and frequency in the measurement range, but theoretical interfacial thickness, ti, was dependent on the frequency. It reached a saturated ti value, $6.9{\AA}$, at high frequency by extraction of some capacitance component formed at low frequency range. The dielectric constant of bulk ZrTiO4 pellet-shaped material was 33.7 and very stable with frequency promising as good applicable devices.

EFFECT OF ANNEALING ON THE OPTICAL PROPERTY OF RF-SPUTTERED CdTe THIN FILM

  • Lee, Dong-Young;Lee, Soon-Il;Oh, Soo-Ghee
    • 한국표면공학회지
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    • 제29권6호
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    • pp.666-672
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    • 1996
  • The optical property of CdTe thin film is important for applications such as the compound semiconductor type solar cells. CdTe films are prepared by RF sputtering at various substrate temperature between $25^{\circ}C$ and $300^{\circ}C$, then, annealed in argon gas environment at $400^{\circ}C$. The annealing process of the thin film caused variation in the film structure and the composition of films. The deformation of CdTe thin film was observed by X-ray diffractometry. After annealing, the grain size increased and the portion of the non-crystalline CdTe reduced. Futhermore, the structure of sputtered CdTe film grown at the substrate temperature more than $250^{\circ}C$ was enhanced in the (111) direction of zincblend structure. There was a discrepancy, in the spectroscopic ellipsometer spectrum, between the single crystal CdTe and the sputtered CdTe thin films, especially in the region over 3.2eV. An oxidation layer was found on the CdTe thin film by spectroscopic ellipsometry analysis.

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디젤 엔진오일의 사용에 따른 물성 변화에 관한 연구 (A study of the Property Changes of Oil Used in Diesel Engine)

  • 강석춘;호광일
    • 한국자동차공학회논문집
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    • 제4권1호
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    • pp.1-15
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    • 1996
  • This study is concerned with the property changes(chemical and mechanical) of the used oil in diesel engine, which were sampled from a test engine with dynamometer and various cars. The properties of oil are TAN, viscosity, oxidation, ZDTP depletion factor and etc. Also the relation between the change of chemical and antiwear property of used oil was strongly related to ZDTP depletion factor as wall as the change of TAN(total acid number), sulfation and pentan unsoluble contents which were reated to the formation of protect film in sliding area. The oil used in pick-up(small) truck engine was deteriorated within the shortest distance than that of other cars. The antiwear property of used oil was decreased sharply as the running distance were over 5,000km. The oil used to mini bus was the least to deteriorate of properities for the funning distance.

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전자선조사에 의한 선형저밀도폴리에틸렌의 개질 (Modification of Linear Low Density Polyethylene by Irradiation of Electron Beam)

  • 오장훈;천성득;황규면
    • 유변학
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    • 제10권4호
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    • pp.256-258
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    • 1998
  • 선형저밀도폴리에틸렌(LLDPE)의 필름 제조시 가공성 및 필름의 투명성을 개선하기 위한 실험을 하였다. LLDPE에 전자선을 조사하여 분자구조를 변형시켜줌으로써 가공 특성 및 광학적 특성이 향상된 필름을 얻을 수 있었다. 전자선 조사량의 세기를 조절하여 일정량만 조사하고 자외선 안정제를 소량 처방하면 필름 가공시 젤이 생기지 않았고 투명성 및 가공성이 개선되었다.

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Dyeing Properties of Polyurethane-impregnated PET Knit

  • Park, Jong-Ho;Kim, Sung-Dong
    • 한국염색가공학회지
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    • 제20권5호
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    • pp.35-40
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    • 2008
  • Dyeing and washing fastness properties of polyurethane-impregnated polyester (PU-impregnated PET), and the distribution of two disperse dyes between PET and PU film were studied to investigate the effect of PU portion to exhaustion and washing fastness. Dyeing properties of PU-impregnated PET were quite different with those of PET: PU-impregnated PET absorbed disperse dye linearly from the early stage of dyeing to equilibrium, and it exhibited excellent build-up property up to 4 %owf dyeing. The absorbed dye on PU film at early dyeing stage migrated to more substantive PET at the temperature higher than $115^{\circ}C$. The amount of exhausted dye on PET portion was larger than on PU film and the distribution ratio was $2.08{\sim}2.34$. The grade of washing fastness of PU-impregnated PET was the same as or lower by $0.5{\sim}1$ grade than PU film whose washing fastness was lower by $0.5{\sim}1$ than PET.

Ag 편광 광도핑에 의한 칼코게나이드 박막의 광유기 이방성(PA) (The photoinduced anisotropy(PA) by Ag polarized-photodoping in amorphous chalcogenide thin films)

  • 장선주;여철호;박정일;정홍배
    • 한국전기전자재료학회논문지
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    • 제13권6호
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    • pp.533-537
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    • 2000
  • It was known that chalcogenide glasses have the superior property of the photoinduced anisotropy(PA). In this study we observed the phenomenon of Ag polarized-photodoping in chalcogenide As$_{40}$ /Ge$_{10}$/Se$_{15}$ /S$_{35}$ and the double-layer of Ag doped As$_{40}$ /Ge$_{10}$/Se$_{15}$ /S$_{35}$ thin film using the irradiation with the polarized He-Ne laser light. The Ag polarized-photodoping results in reducing the time of saturation anisotorpy and increasing the sensitivity of linearly anisotropy intensity up to maximum 220% The Ag polrized-photodoping shows improvement of the photoinduced anisotropy property in polarized photodoping of the chalcogenide thin film. It will offer lots of information for the photodoping mechanism and analysis of chalcogenide thin film.in film.ilm.

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Effect of Deposition Rate on the Property of ZnO Thin Films Deposited by Pulsed Laser Deposition

  • Kim Jae-Won;Kang Hong-Seong;Lee Sang-Yeol
    • Journal of Electrical Engineering and Technology
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    • 제1권1호
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    • pp.98-100
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    • 2006
  • ZnO thin films were deposited at different repetition rates of 5 Hz and 10 Hz by pulsed laser deposition. X-ray diffraction (XRD) full widths at half maximum (FWHMs) of (002) ZnO peak in ZnO thin film deposited at 5 Hz and 10 Hz was 0.22 and $0.26^{\circ}$, respectively. The grain size of ZnO thin film deposited at 5 Hz was larger than that of 10 Hz. The variation of repetition rates did not have an effect on the optical property of ZnO thin films. The degradation of the crystalline quality and surface morphology in ZnO thin film deposited at 10 Hz resulted from supersaturation effect by decrease of time interval between a ZnO particle arriving on a substrate by laser shot and a ZnO particle arriving on a substrate by next laser shot.

박막 물성평가 압입시험의 수치접근법 (A Numerical Approach to Indentation Techniques for Thin-film Property Evaluation)

  • 이진행;유한석;이형일
    • 대한기계학회논문집A
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    • 제31권3호
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    • pp.313-321
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    • 2007
  • In this work, the prior indentation theory for a bulk material is extended to an indentation theory for evaluation of thin-film material properties. We first select the optimal data acquisition location, where the strain gradient is the least and the effect of friction is negligible. A new numerical approach to the thin-film indentation technique is then proposed by examining the finite element solutions at the optimal point. With this new approach, from the load-depth curve, we obtain the values of Young's modulus, yield strength, strain-hardening exponent. The average errors of those values are less than 3, 5, 8% respectively.