• Title/Summary/Keyword: fiber morphology

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Parametric Study on the Morphology of Electrospun Cellulose Web (전기방사 조건이 셀룰로오스 웹 형상에 미치는 영향)

  • Jung, Yeon-Su;Jeong, Young-Jin
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.62-68
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    • 2012
  • Cellulose was electrospun over water collector and the cellulose solution was prepared using N-methyl-morpholine N-oxide/water(nNMMO/$H_2O$). The morphology of electrospun cellulose was investigated by scanning electron microscopy (SEM). SEM images showed that the fiber formation depended on processing parameters such as solution concentration, applied electric field strength, solution feeding rate and temperature of water in coagulation bath. High concentration, low temperature of water bath, and low feeding rate were more favorable to obtain fiber morphology. All the variables affected on the fluidity of the cellulose solution and diffusion of NMMO. Low fluidity and fast diffuision of NMMO was critical for obtaining fiber morphology.

Characteristic Change of Fiber Depending on the Refining Conditions of Reconstituted Tobacco Process (판상엽 고해조건에 따른 섬유특성 변화 평가)

  • Han young-Rim;Sung Yong-Joo;Kim Sam-Kon;Kim Kun-Soo;Han In-Ho
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.2
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    • pp.195-200
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    • 2005
  • The goal of refining is to treat fibers so they meet the requirements of the papermaking process. The refining process in papermaking has great influence on the quality of the final product by changing the fiber properties, such as fiber length, shape, fine contents and so on. In this study, the effect on the morphological change of fibers by the refining conditions were investigated using the fiber morphology analyzer. Fiber morphology analyzer used to determine which pulps are suitable for producing particular products. Furthermore it is widely used in paper mills to monitor paper quality. The morphological change of fibers according to refining conditions were evaluated out by measuring fiber, shive and fine. In the fiber morphology, the domestic reconstituted tobacco fiber has the bigger average fiber length value than that of the foreign reconstituted tobacco.

EFFECT OF DIFFERENT SOURCES OF FIBER ON THE INTESTINAL MORPHOLOGY OF DOMESTIC GEESE

  • Chiou, Peter W.S.;Lu, T.W.;Hsu, J.C.;Yu, B.
    • Asian-Australasian Journal of Animal Sciences
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    • v.9 no.5
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    • pp.539-550
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    • 1996
  • Experiment was conducted to study the effect of sources of dietary fiber on the intestinal morphology of geese. Sixty white Roman geese of two-week-old were divided randomly into six groups and were fed with isoenergetic and isonitrogenous diets which contain alfalfa meal, barley hull, rice hull, purified cellulose, lignin, or pectin as the major dietary source of fiber. Different sources of dietary fiber significantly influenced the villi height and the crypt depth in the duodenum, and the villi height and the muscle layer thickness in the ileum (p < 0.05). The duodenal villus in the geese that fed diets with alfalfa meal, rice hull or pectin supplemented were significantly longest ($968.5{\mu}m$), whereas the lignin group was significantly shortest villus and deepest crypt depth (p < 0.05). The thicknesses of the ileal and caecal muscle layer were significantly thicker in the geese fed with cellulose supplemented diets than in those fed with the other treatment diets. The caecum of the barley bran fed geese possessed significantly longest villi and the most thick muscle layers (p < 0.05). From scanning electronic microscopic observation, the leafy and plate-like in the duodenal villi morphology of geese represented a more effective nutrient absorption in the small intestine. The morphology of ileal villi in geese was similar from herbivorous rabbit and from the African Green monkey.

Dyeing Study on DMF-Modified Polyesters for Morphology Characterization

  • Park, Myung-Ja
    • The International Journal of Costume Culture
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    • v.5 no.2
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    • pp.53-65
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    • 2002
  • Morphology of polyester fiber was physically modified by solvent treatment. PET fiber was treated with N,N-dimethylformamide (DMF) at 100, 120, $140^{circ}C$ for 10 minutes without tension. The structural changes in the morphology of DMF-induced modified PET fiber were FTIR and SEM analysis. Also dyeing behavior of DMF-treated polyester fibers with various disperse dyes was studied to detect changes of amorphous area in fine structure. DMF treatment resulted in increases in total void content, degree of crystallinity, trans isomer content, chain folding, segmental mobility and molecular packing, but it resulted in decreases in amorphous orientation, intermolecular forces and individual void size through longitudinal shrinkage, lateral welling and removal of oligomers. Void-size distribution could be estimated from the dye uptake with various sizes of disperse dyes. In contrast to the large increases in dye uptake with small dye molecules, there is no and little dye uptake with the bulkiest dye, which means that void size is bigger or smaller than the volume of each dye. Diffusion rates of dye molecules showed increases. This dyeing study revealed that the disperse dyeing is very effective method for characterizing the internal morphology of polyester fiber.

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Surface Modification of Polyacrylonitrile by Low-temperature Plasma (저온플라즈마처리에 의한 폴리아크릴로니트릴의 표면개질)

  • Seo, Eun-Deock
    • Textile Coloration and Finishing
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    • v.19 no.1 s.92
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    • pp.45-52
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    • 2007
  • Polyacrylonitrile(PAN) fiber was treated with low-temperature plasmas of argon and oxygen for surface modification, and its surface chemical structure and morphology were examined by a field emission scanning electron microscope(FESEM) and a Fourier-transform infrared microspectroscopy(IMS). The argon-plasma treatment caused the only mechanical effect by sputtering of ion bombardment, whereas the oxygen plasma brought about a chemical effect on the PAN fiber surface. The experimental evidences strongly suggested that cyclization of nitrile group and crosslinking were likely to occur in the oxygen-plasma treatment. On the other hand, with the argon-plasma treatment, numerous my pits resulted in ranging from several tens to hundreds nanometers in radius. The plasma sensitivity of functional groups such as C-H, $C{\equiv}N$, and O-C=O groups in the PAN fiber was dependent on their chemical nature of bonding in the oxygen-plasma, in which the ester group was the most sensitive to the plasma. Vacuum-ultraviolet(VUV) radiation emitted during plasma treatment played no substantial role to alter the surface morphology.

Morphology of Metal Salt of Carboxylic Acid: Metal and Acid Dependency on Branched Round Cluster Images

  • Min Su Kang;Kwang-Jin Hwang
    • Journal of the Korean Chemical Society
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    • v.67 no.4
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    • pp.222-225
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    • 2023
  • Metallic salts of C10-18 aliphatic carboxylic acids were prepared and their scanning electron microscopic images were analyzed for the morphology dependency with the metal and the carboxylic acid. Regardless of metal ion, metal salts of dicarboxylic acids showed a high crystallinity with a fiber image (SuA-Na). The aromatic dicarboxylates also represented a morphology of a rectangular-rod or board shapes (IA-Li, IA-Ba). With Na ion, most aliphatic carboxylate (MA, PA, SA) showed a fiber-like crystallinity. However, other monovalent Li, K and multivalent Mg, especially Al ion resulted a glassy-amorphous in the metallic salts of acids (MA, PA, SA). With divalent Ba and Ca ions, the metal salt of aliphatic acids expressed a branched round cluster shape as in SA-Ca, SA-Ba. Both Li and Mg ions with a similar size showed a strong morphological similarity in the metallic salts of aliphatic acids MA, PA, SA. In the case of Na and Ca ions with a similar size (98, 106 pm), both ionic salts of stearic acid gave a branching effect for a fiber or round granular image. In the case of hydroxyl-aliphatic acids (HLA, HPA, HSA), the fiber images in HLA-Na and HSA-Na was appeared about 100 nm thicker than those of nonhydroxycarboxylates (LA-Na, SA-Na). The metallic salts of unsaturated C-18 carboxylic acids (OlA, LeA and LnA) showed an amorphous glassy image due to a kinked carbon chain.

A Theoretical Study on the Initial Collection Efficiency and Particle Deposition Morphology in Model Fiber Filter (모델 섬유 필터(Model Fiber Filter)에서의 입자의 퇴적 양상 및 초기 집진 효율에 대한 관한 이론적 연구)

  • 유도영;전기준;정용원
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.427-428
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    • 2000
  • 공기 여과 장비에 주로 쓰이는 섬유층 여과기(fibrous filter)는 다양한 장비에 널리 쓰이고 있다. 섬유층 여과기는 이를 구성하는 섬유(fiber)의 직경, 표면 조도, 그리고 이들로 해서 나타나는 공극률, 하전여부, 등 여러 가지 필터의 특성에 따라 다양한 포집양상(Deposition Morphology)을 보인다. 제조 공정에 따라 달라지는 특성을 가진 필터는 여과 과정을 거치면서 입자가 퇴적되고 압력강하가 증가하여 필터의 수명이 다하게 된다. (중략)

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High Tenacity Cellulosic Fiber from Liquid Crystal Solution of Cellulose Triacetate (셀룰로오스 트리아세테이트 액정용액으로 부터 고강도 셀룰로오스 섬유 제조에 관한 연구)

  • 홍영근
    • Textile Coloration and Finishing
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    • v.6 no.1
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    • pp.44-48
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    • 1994
  • Cellulose triacetate(CTA) liquid crystal solutions obtained via dissolution of CTA in solvent mixture of triflucroacetic acid and methylene chloride were spun and saponified in various chemicals. Among chemicals, methanol/sodium hydroxide mixture endowed highest tenacity as well as modulus to regenerated cellulosic fiber and the fiber thereof showed Cell I or Cell IV morphology, or mixed morphology of Cell I and IV.

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