• 제목/요약/키워드: extreme-pressure property

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불소계 폴리올에스테르의 합성과 윤활 특성 (Synthesis and Lubrication Properties of Semi-Fluorinated Polyol Esters)

  • 백진욱;정근우;김영운
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2001년도 제33회 춘계학술대회 개최
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    • pp.149-155
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    • 2001
  • New semi-fluorinated polyol esters were synthesized by condensation reaction of polyols (NPG and TMP) and carboxylic acids such as 2-ethylhexanoic acid, stearic acid and perfluorooctanoic acid. The structures of polyol esters were confirmed by FT-IR and H-NMR etc. And, the fluorinated polyol esters were insoluble in several oils, however, the semi-fluorinated polyol esters were soluble in several oils depended on the structure of polyol esters. The physical properties such as 4-ball wear property and extreme-pressure (EP) properties were characterized by measuring wear scar diameter through ASTM D2266 and by determining the load-carrying through ASTM D2783 method, respectively. As the results, wear scar diameters of oils in which the semi-fluorinated polyol esters were added were not changed compared to those of not added oils. While extreme-pressure properties remarkably Increased with fluorine contents of the esters depended on the structure of acid moiety and polyol moiety. Also, the extreme-pressure property of semi-fluorinated NPG polyol ester in gasoline engine oil was better than that of commercial Teflon coating additive.

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기유와 극압제가 압연유의 윤활성 및 내소부성에 미치는 영향 (Influence of Base Oils and Extreme Pressure Additives on Lubricity and Anti-Seizure Property of Lubricant in Cold Rolling)

  • 한석영;송교봉;이준정
    • 대한기계학회논문집
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    • 제16권7호
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    • pp.1363-1372
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    • 1992
  • 본 연구에서는 고속 냉간 압연유를 개발하기 위한 기초 연구로써 압연유의 기본이 되는 기유의 종류와 압연유에 첨가되는 각종 첨가제중 고속, 고압하 압연에서 가장 문제가 되는 히트 스크래치를 방지하는 역할을 하는 극압제의 종류 및 함량이 압연유의 윤활성과 내소부성에 어떠한 영향을 주는가를 소다식 진자형 마찰계수 시험 기, Falex 시험기 그리고 Four Ball 시험기와 같은 실험실적 평가방법과는 달리 실제 롤과 스트립 사이의 접촉조건이 상사한 시험압연기를 사용한 윤활성 및 내소부성 평가 실험을 통하여 검토하였다. 본 평가 실험에 사용된 시험압연기는 압하배분, 압연 채 터링(chattering), 장력 제어, 압연윤활 특성, 압연재 형상 제어, 이주속 압연특성 등 을 시험할 수 있는 다목적 냉간압연기로써 그 구조와 제원을 Fig.1과 Table 1에 나타 내었다. 또한 극압제를 함우하고 있는 압연유와 스트립 표면간의 화학반응에 의한 극압막의 존재여부를 확인하기 위하여 EDS(energy dispersive spectrometer) 분석법과 ESCA (electron spectroscopy for chemical analysis) 분석법을 이용하여 분석하였다.

엔진오일의 혼합첨가제에 따른 윤활특성에 관한 연구 (A Study on the Lubricational Characteristics with Compound Additives of Engine Oil)

  • 이봉구;오성모
    • Tribology and Lubricants
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    • 제11권1호
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    • pp.50-57
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    • 1995
  • When engine oil is used under severe running condition, the Lubricational characteristics is very important. I have studied the Lubricational characteristics with Compound Additives of engine oil for the Falex wear test machine. Adding detergent (Ca-phenate) to engine oil, the seizure is more improved than in case of non-adding, and adding Zn-DTP (Zinc dialkyl dithio phosphate), the extreme pressure property is excellent at the high load. But when the PTFE (Polytetra Fluoro Ethylene) and MoS$_{2}$ (Molybdenum disulfide) are added, the temperature characteristics and the anti-wear property become excellent because the stability can be maintained in a high temperature. The result are as follows, it can be improved that when the compound of the Ca-phenate and Zn-DTP, MoS$_{2}$, PTFE, etc. was added to engine oil, the lubrication characteristics become better. It is argued that it is improved because of excellence of the anti-wear, the extreame pressure properties and the heat stability.

Lithium Dual Complex 그리이스의 합성 및 특성연구 (Synthesis and Characterization of Lithium Dual Complex Grease)

  • 최웅수;권오관;문탁진;유영홍
    • Tribology and Lubricants
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    • 제1권1호
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    • pp.80-87
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    • 1985
  • 고온에서 화학적역안정성 및 기계적안정성의 섬유구조를 갖기 위해 lithim complex gellant로 정한 지방산과 $LiOH\cdot H_2O$ 및 boric acid의 이차연속검화반응으로 lithium dual complex 그리이스를 합성하였다. complex gellant의 양은 14%(NLGI 2호)가 적정량이었으며, 특히 castor wax를 1.5% 첨가했을때 이상적인 성능을 나타냈다. 이렇게 합성한 그리이스의 유분리성, 산화안정성, 내수성, 혼화안정성, 극압 및 내마모성은 ASTM 및 KS 방법에 준해 시험하였으며, 매우 우수한 특성을 지녔음을 알았다.

MRI 소음의 특성을 이용한 공동 내부 목표점의 능동소음 제어 (Active Noise Control for Target Point Inside Bore Using Property of MRI Noise)

  • 이록행;박영진;박윤식
    • 한국소음진동공학회논문집
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    • 제24권1호
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    • pp.62-68
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    • 2014
  • Recently, MRI(magnetic resonance imager) scanner is continually used for medical diagnosis and many biomedical researches. When it operates, however, intense noise is generated. The SPL(sound pressure level) of the noise approaches 130 dB especially in 3 T(Tesla) MRI. Meanwhile, more than 3 T MRI scanners have been developed to get higher-resolution images, so louder noise is expected in the future. The intense noise makes patients feel nervous and uncomfortable. Moreover, it could possibly cause hearing loss to patient in extreme cases. For this reason, some active noise control systems have been researched. One of them used feedback Filtered-X LMS(FXLMS) algorithm which is able to control only narrowband noises and possible to diverge in severe case. In this paper, we determine the property of MRI noise. Using the property, we applied a method of open-loop and adaptive control for reducing MRI noise at target point inside bore. We verified performance of the method with computer simulation and preliminary experiment. The results demonstrate that the method can effectively reduce MRI noise at target point.

열동력 시스템 내부 열교환 표면의 클리닝에 관한 연구 (A study of cleaning of heat transfer surface in thermal power system)

  • 한규일
    • 수산해양기술연구
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    • 제51권4호
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    • pp.576-582
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    • 2015
  • The efficiencies of thermal power system using fossil fuel depend on heat exchangers which extract energy from the exhaust gas before it is expelled to the atmosphere. To increase heat transfer efficiency it is very important to maintain the surface of heat exchanger as clean condition. The accepted skill of cleaning of fouled surface of heat exchanger is soot blowing. A high pressure jet of air is forced through the flat surface of plate to remove the deposit of fouling. There is, however, little knowledge of the fundamental principles of how the jet behave on the surface and how the jet actually removes the deposit. Therefore, the study focuses on the measuring of cleaning area and cleaning dwell time after accumulating the simulated deposit on the flat surface. The deposit test rig was built for the study and simulated deposit material is used after measuring the physical property of the each material by shearing stress test. Much data was obtained for the analysis by the parameters change such as the different jet speed, different inner pressure and variable distance of the jet from the test rig surface. The experimental data was compared with the theoretical equation and most of the data matches well except some extreme cases.

프리스트레스트 콘크리트 관형 구조물의 폭발량에 따른 내부폭발저항성능에 관한 실험적 평가 (Experimental Evaluation of Internal Blast Resistance of Prestressed Concrete Tubular Structure according to Explosive Charge Weight)

  • 최지훈;최승재;양달훈;김장호
    • 대한토목학회논문집
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    • 제39권3호
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    • pp.369-380
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    • 2019
  • PSC 구조물에 폭발과 같은 극한하중이 짧은 시간 동안 발생하게 되면 급작스러운 파괴와 그로 인한 수많은 인명 및 재산피해를 발생시킨다. 하지만 원전격납구조물, 가스탱크와 같은 PSC 구조물의 경우 방호 및 방재개념이 포함된 구조설계가 적용되지 않은 실정이며, 특히, 구조물 내부에서 발생하는 폭발압력하중은 피해규모가 외부폭발에 비해 훨씬 크기 때문에 내부폭발하중에 대한 검증은 반드시 필요하다. 따라서, 본 연구에서는 원전격납구조물의 내부폭발에 대한 저항성능을 검토하기 위해 이방향 프리스트레스트 콘크리트 축소모형을 제작하였다. 내부폭발 실험은 22.68, 27.22, 31.75 kg (50, 60, 70 lbs)의 ANFO 폭약을 이용하여 시편으로부터 1,000 mm의 거리에서 폭발시켰으며, 압력하중, 처짐, 변형률, 균열형상, 긴장력 변화 등의 데이터를 분석하였다. 본 연구결과를 이용하여 원전격납구조물의 내부폭발하중 발생 시 손상도 범위 예측이 가능할 것으로 판단된다.

PECVD 공정에 의한 TiC, TiN 및 Ti(CN)의 마찰 마모 특성 연구 (A Study on the Friction and Wear Characteristics of TiC, TiN and Ti(CN) with PECVD Process)

  • 이봉구;전찬열;김정기;김동현;오성모
    • 한국공작기계학회논문집
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    • 제14권2호
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    • pp.1-7
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    • 2005
  • In order to determine the wear Properties of PECVD ceramic coatings, wear process was evaluated using the coated pin of Falex Tribosystem. Coating materials deposited wear the TiC, TiN and Ti(CN). An experimental process was established to determine the tribological characteristics of friction and wear behavior under the variation of applied load, temperature and sliding distance by the Falex test machine. The experimental results indicate that TiN coating compared with TiC coating on e materials have e excellent friction and wear characteristics. However TiC coating compared i친 TiN coatings have a low friction coefficient with steel and good thermal stability, and Ti(CN) has the excellent anti-wear properly as well as the superiority of extreme pressure property. Compound coating compared wi simple coatings show improved tribological characteristics.

Study on Cold/Oil Atmosphere Resistance Property of Face Seal Rubber for Track Layer

  • Shin, Jae Won
    • Elastomers and Composites
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    • 제53권1호
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    • pp.13-18
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    • 2018
  • A face seal comprising a metal ring and acrylonitrile butadiene rubber (NBR) was installed in the driving part and suspension unit. The seal serves as a bearing and simultaneously prevents entry of foreign matter from external environment as well as internal oil leakage. Subsequently, the rubber-rod ring generates axial pressure owing to rubber elasticity (hardness), performs static sealing function between housing details and outer diameter of seal, and transmits rotational torque to the rotating support ring. In order to improve the durability of NBR, which performs the above tasks, and to effectively use it in tracked-vehicle applications at extreme temperatures, this study reports a mixing design approach to enhance cold and oil resistances of NBR.

Characteristics of Molecular Band Energy Structure of Lipid Oxidized Mammalian Red Blood Cell Membrane by Air-based Atmospheric Pressure Dielectric Barrier Discharge Plasma Treatment

  • Lee, Jin Young;Baik, Ku Youn;Kim, Tae Soo;Jin, Gi-Hyeon;Kim, Hyeong Sun;Bae, Jae Hyeok;Lee, Jin Won;Hwang, Seung Hyun;Uhm, Han Sup;Choi, Eun Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.262.1-262.1
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    • 2014
  • Lipid peroxidation induces functional deterioration of cell membrane and induces cell death in extreme cases. These phenomena are known to be related generally to the change of physical properties of lipid membrane such as decreased lipid order or increased water penetration. Even though the electric property of lipid membrane is important, there has been no report about the change of electric properties after lipid peroxidation. Herein, we demonstrate the molecular energy band change in red blood cell membrane through peroxidation by air-based atmospheric pressure DBD plasma treatment. Ion-induced secondary electron emission coefficient (${\gamma}$ value) was measured by using home-made gamma-focused ion beam (${\gamma}$-FIB) system and electron energy band was calculated based on the quantum mechanical Auger neutralization theory. The oxidized lipids showed higher gamma values and lower electron work functions, which implies the change of surface charging or electrical conductance. This result suggests that modified electrical properties should play a role in cell signaling under oxidative stress.

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