• Title/Summary/Keyword: exposed specimen

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Service Life Prediction of Concrete Structures Exposed to a Sulfuric Acid Environment

  • Jeon, Joong-Kyu;Moon, Han-Young;Jeon, Chan-Ki;Song, Jong-Hwa
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.385-389
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    • 2007
  • In this study, it was investigated the resistance of OPC, 60% GGBS, 20% PFA and 10% SF mortar specimens against sulfuric acid corrosion. As an index for degree of acid corrosion, the corrosion depth was evaluated. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders; 60% GGBS mortar specimen was the most resistant to sulfuric acid corrosion. From the laboratory testing of sulfuric acid corrosion, an empirical prediction model was suggested as a power function of time and the pH of sulfuric acid, and was applied to an assessment of concrete structures exposed to an acidic environment. It was found that the empirical model gave a more precise prediction of sulfuric acid deterioration of concrete rather than a conventional model, mostly used for predicting carbonation of concrete.

Deterioration Properties of Shotcrete as Tunnel Supporter was Exposed to Harmful Ions (터널 지보용 숏크리트의 유해이온에 대한 열화특성)

  • Jung, Ho-Seop;Kim, Dong-Gyou
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.5
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    • pp.55-64
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    • 2008
  • Shotcrete have become a deterioration which was exposed to harmful environments. In this study, in order to evaluate the deterioration properties of shotcrete, visual examination, compressive strength, adhesive strength, microstructural analysis were investigated up to the 60th weeks of exposure. The attack solutions for test are sodium sulfate and hydrochloric acid solution with different concentrations, respectively. From the results, although the compressive strength of shotcrete specimens and the adhesive strength between specimens and rocks were high at the early immersion age, they rapidly dropped in the subsequent phases, especially in 5% sodium sulfate and pH1 hydrochloric acid solution. With continued exposure, various harmful ions penetrated into the shotcrete specimen, reacted with the cement hydrate, and generated expansion substances. It was verified that the shotcrete specimens suffered a serious deterioration by chemical attack.

Effects of Plasticizer to Polyvinylchloride on Radio-resistance of Organic Stabilizer,Dielectric and Mechanical Characteristics under the Influence of Radiation (Polyvinylchloride에 있어 가소제의 첨가가 유기안정제의 내 방사성 및 유전, 기계적 특성에 미치는 영향)

  • 김봉흡;강도열;이재인
    • 전기의세계
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    • v.26 no.2
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    • pp.89-94
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    • 1977
  • In order to investigate the properties of radiation resistance together with dielectric, and mechanical relaxation behaviors of polyvinylcholoride exposed to several different doses under the .gamma.-ray of Co$^{60}$ source, several observations were carried out on the exposed specimens propared by mixing dibutyl-tin-dilaulate and dibutyl-tin-dimaleate as stabilizer with or without adding dioctyl-phthalate as plasticizer. Conclusions obtained from the study are as follows: The origin of the absorption band at 1,540-1,640$cm^{-1}$ / on I.R. spectrum seems to be RCOO- ion originated from ionization of the stabilizer, and this peak can be useful as a measure of radiation resistance on polyvinylchloride. Addition of increasing plasticizer to polyvinylchloride exhibits increasing radiation resistance and the reason for this result may be attributed to aromatic resonance absorption of radiation energy by diotylphthalate. On dose dependent dielectric characteristics, nonplastized specimen shows a peak at about 10 Mrad and that this peak disappears on the plastification of specimens. Those phenomena may be explainable in considering the statistical distribution of scissored chain molecular segments as well as the plastification process of plasticizer to polyvinylchloride chain molecules.

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The Effect of Heat Curing Methods on the Temperature History of the Fly Ash Concrete Subjected to Extremely Low Temperature (복합보온양생 방법이 극저온 조건하 플라이애시 치환 콘크리트의 온도이력에 미치는 영향)

  • Han, Min-Cheol;Son, Ho-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.85-90
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    • 2012
  • In this study, temperature profile of the fly ash concrete were studied in accordance with the change of heating curing method combination for the slab concrete in order to develop efficient protection method of the concrete subjected to $-20^{\circ}C$. The slab concretes with the size of $1200mm{\times}600mm{\times}200mm$ were fabricated with W/B of 50% and exposed to $-20^{\circ}C$ for 7 days. Five different combinations of heat curing methods were applied to the slab concrete specimen; two combinations of heat supplying by electrical heater and surface heat insulation material such as polyethylene film and quadrupled layer bubble sheet based on heat enclosure installment; three combinations of heating coil embedment and surface heat insulation materials such as polyethylene film, sawdust and quadrupled layer bubble sheet based on heat enclosure installment. Test results showed that by applying both heating coil and bubble sheet and heat enclosure, the concrete exposed to $-20^{\circ}C$ can be effectively protected from early-age frost damage.

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AN ELECTROCHEMICAL STUDY ON SURFACE FINISH OF DENTAL AMALGAM (아말감의 표면연마에 관한 전기화학적 연구)

  • Suk, Chang-In;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.16 no.2
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    • pp.18-32
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    • 1991
  • The purpose of this study was to observe characteristic properties of amalgam through the polarization curves and SEM images from 4 type amalgams (Amalcap, Shofu spherical. Dispersalloy and Tytin) with 3 different surface finish procedures (polishing, burnishing and carving) by using the potentiostats (EG & GPARC) and SEM (Jeol JSM-35). After each amalgam alloy and Hg was triturated as the direction of the manufacturer by means of mechanical amalgamator (Samki), the triturated mass was inserted into the cylndrical metal mold which was 12 mm in diameter and 10 mm in height and was pressed with $100kg/cm^2$. 4 specimens of each type amalgam were burnished with egg burnisher and another 4 specimens of each type amalgam were carved with Hollenback carver. Above 8 specimens and remaining untreated 4 specimens were stored at room temperature for about 7 days. Untreated 4 specimens of each type amalgam were polished with abrasive papers (Deer) from #400 to #1200 and finally on the polishing cloth with $0.5{\mu}m$ and $0.06{\mu}m$ $Al_2O_3 $ powder suspended water. Anodic polarization measurements was employed to compare the corrosion behaviours of the amalgams in 0.9% saline solution at $37^{\circ}C$. The open circuit potential was determined after 30 minutes immersion of specimen in electrolyte. The scan rate was 1 mV/sec and the surface area of amalgam exposed to the solution was $0.64cm^2$ for each specimen. All the potentials reported are with respect to a saturated calomel electrode (SCE). SEM images of each specimen were taken after + 800 mV (SCE) polarization. The results were as follows: 1. The corrosion potential of high copper amalgam was more anodic than that of low copper amalgam. 2. The polished amalgam were more resistant to corrosion than any other burnished and carved amalgam. 3. In the case of polishing, current density of high copper amalgam was lower than that of low copper amalgam.

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The effect of continuous application of MDP-containing primer and luting resin cement on bond strength to tribochemical silica-coated Y-TZP

  • Lim, Myung-Jin;Yu, Mi-Kyung;Lee, Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.43 no.2
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    • pp.19.1-19.10
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    • 2018
  • Objectives: This study investigated the effect of continuous application of 10-methacryloyloxydecyldihydrogen phosphate (MDP)-containing primer and luting resin cement on bond strength to tribochemical silica-coated yttria-stabilized tetragonal zirconia polycrystal (Y-TZP). Materials and Methods: Forty bovine teeth and Y-TZP specimens were prepared. The dentin specimens were embedded in molds, with one side of the dentin exposed for cementation with the zirconia specimen. The Y-TZP specimen was prepared in the form of a cylinder with a diameter of 3 mm and a height of 10 mm. The bonding surface of the Y-TZP specimen was sandblasted with silica-coated aluminium oxide particles. The forty tribochemical silica-coated Y-TZP specimens were cemented to the bovine dentin (4 groups; n = 10) with either an MDP-free primer or an MDP-containing primer and either an MDP-free resin cement or an MDP-containing resin cement. After a shear bond strength (SBS) test, the data were analyzed using 1-way analysis of variance and the Tukey test (${\alpha}=0.05$). Results: The group with MDP-free primer and resin cement showed significantly lower SBS values than the MDP-containing groups (p < 0.05). Among the MDP-containing groups, the group with MDP-containing primer and resin cement showed significantly higher SBS values than the other groups (p < 0.05). Conclusions: The combination of MDP-containing primer and luting cement following tribochemical silica coating to Y-TZP was the best choice among the alternatives tested in this study.

Effect of Oxidation on Hot Ductility Behavior of Plain Carbon Steel (탄소강의 열간연성 거동에 미치는 산화의 영향)

  • Park, Tae Eun;Lee, Un Hae;Sohn, Kwang Suk;Lee, Sung Keun;Kim, In Soo;Yim, Chang Hee;Kim, Donggyu
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.394-400
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    • 2010
  • The effects of oxidation behavior on the hot ductility of plain carbon steels were investigated at various temperatures in order to simulate the continuous casting process more precisely, in which the process undergoes in air atmosphere rather than Ar atmosphere. The high temperature oxidation behavior and scale morphology of the carbon steels exposed to the air and Ar atmosphere at various temperatures were also investigated in order to assess the mechanism of the RA value decreasing in an air atmosphere. The RA values obtained from the air atmosphere were marked below 45% by the test temperature, except for over 1000${^{\circ}C}$, with the RA values remaining in low values in both the low and high temperature region, at which the RA values generally recovered in the Ar atmosphere. The surface roughness of the specimen was developed by external and internal oxidation when the specimen was deformed in an air atmosphere at high temperature, with the result being the stress concentrated at the roughness of the specimen surface, resulting in low RA values. The hot ductility in the air atmosphere was found to be likely controlled by the oxidation rate instead of the microstructures corresponding to test temperatures.

Jet A-1 Coking Tests under Conditions Simulating Gas Turbine Combustor (가스터빈 연소기 모사 조건에서의 Jet A-1 코킹시험)

  • Lee, Dain;Lee, Kangyeong;Han, Sunwoo;Ahn, Kyubok;Ryu, Gyong Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.1
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    • pp.1-11
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    • 2022
  • In a gas turbine, fuel is exposed to a high temperature environment until it is fed to the combustor through the injector. Hydrocarbon fuels can coke under high temperature conditions, which can cause coking material to deposit on fuel lines or block the injector passages. In this study, a specimen simulating a fuel line located inside a gas turbine and Jet A-1 were heated using electric devices. Jet A-1 coking tests were performed by changing the wall temperature of the stainless steel specimen and the temperature of Jet A-1 supplied to the specimen. After the coked specimens were cut, the coking material and the inner surface were analyzed using an energy dispersive X-ray spectrometer and a field emission scanning electron microscope.

Study on Cement-based Grout for Closed-loop Vertical Grout Heat Exchanger (수직 밀폐형 지중열교환기 뒤채움재로서 시멘트 그라우트의 적용성 검토)

  • Park, Moon-Seo;Wi, Ji-Hae;Lee, Chul-Ho;Choi, Hang-Seok;Kang, Shin-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.26 no.7
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    • pp.107-115
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    • 2010
  • In this paper, the applicability of cement grout bas been studied as an alternative to bentontite grout to backfill ground heat exchangers. To provide an optimal mixture design, the groutabilty and thermal conductivity of cement grouts with various mixture ratios were experimentally evaluated and compared. The unconfined compression strength of cement grout specimen was measured, which was exposed to cyclic temperature variation ranging from $50^{\circ}C$ to $-5^{\circ}C$. In addition, the integrity of the interface between circulating HDPE pipes and cement grout was evaluated by performing equivalent hydraulic conductivity tests, on the specimen. in which a pipe locates at the center of the specimen.

IN VIVO EFFECTS OF DENTIN BONDING AGENTS ON DENTINAL FLUID MOVEMENT AND INTRADENTAL NERVE ACTIVITY (In vivo에서 상아질 접착제 도포가 상아세관액 이동과 치수신경활동에 미치는 영향)

  • Son, Ho-Hyun;Lee, Kwang-Won;Park, Soo-Jung
    • Restorative Dentistry and Endodontics
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    • v.21 no.1
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    • pp.425-435
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    • 1996
  • The effect of application of dentin bonding agent to the exposed dentin on the intradental nerve activity (INA), dentinal fluid movement and sealing of the dentinal tubules, was investigated in this study. The INA was recorded from the single pulp nerve unit dissected from the inferior alveolar nerve. And specimen of dentin was observed by SEM. Dentinal fluid 'movement through exposed dentin surface was measured before and after the application of dentin bonding agent. 1. Eight Ao-fiber units (conduction velocity: $8.0{\pm}4.0m$/sec) were identified. 4M NaCl evoked an irregular burst of action potentials which ceased immediately after washing. 2. In 4 $A{\delta}$-fiber units, appliction of All Bond 2 completely abolished the INA induced by 4M NaCl. Also, application of Scotchbond Multipurpose(SBMP) totally abolished the INA induced by 4M NaCl in 4 $A{\delta}$-fiber units. 3. Before the application of dentin bonding agent, outward dentinal fluid movement of $10.2{\pm}5.7\;pl{\cdot}s^{-1}{\cdot}mm^{-2}$ was obsered. But after the application of dentin bonding agent the movement of dentinal fluid was stopped. 4. The gap width of 2-$3{\mu}m$ was formed between exposed dentin and adhesive resin in the specimens applied with dentin bonding agents of All Bone 2 and SBMP. But the formation of hybrid layer and the penetration of resin into were dentinal tubules were not clearly observed in interface between dentin and adhesive resin.

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