• 한국세라믹학회지
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• 제46권5호
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• pp.493-496
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• 2009

Phase stabilized leucite, which has high coefficient of thermal expansion, was synthesized, and its thermal expansion behavior was investigated. The homogeneous leucite phase was synthesized by solid state reaction from the mixture of $K_2CO_3-Al_2O_3-SiO_2$. and its stabilization from tetragonal to cubic phase was attempted by adding $Cs_2CO_3$ into starting materials. And fine powder with an average particle size of a few hundreds ${\mu}m$ were fabricated by planetary milling. During milling, amorphization of leucite was observed and recrystallized after heat treatment. The thermal expansion behavior of tetragonal and cubic leucite has measured and discussed. The average coefficient of thermal expansion of tetragonal and cubic phase leucite from room temperature to $750^{\circ}C$ was $21.4{\times}10^{-6}/^{\circ}C$ and $14.5{\times}10^{-6}/^{\circ}C$, respectively.

• 동력기계공학회지
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• 제2권3호
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• pp.34-40
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• 1998

Performance characteristics of a refrigeration systems with various expansion valves and superheat changes were investigated experimentally. Experimental data have been taken utilizing three different devices; a thermostatic expansion valve, a linear type electronic expansion valve and a solenoid type electronic expansion valve. The data taken from tile three types of expansion valves were discussed with the temperature distribution of each zone in the evaporator and the superheat changes of the evaporator outlet In each zone temperature distribution fluctuated larger with the thermostatic expansion valve than with the electronic expansion valves. The optimum superheat ranged from $5^{\circ}C\;to\;15^{\circ}C$, and the superheat with the thermostatic expansion valve showed hunting phenomenon, which affected the evaporating and condensing temperature.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.785-790
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• 2002

Distributions of residual stress in diffusion bonding of dissimilar materials intermetallics TiAl to steel 40Cr were simulated by FEM calculation. Results showed that destructive residual stresses presented in the minute area adjacent to bond-line of the base material with smaller coefficient of thermal expansion. Reducing bonding temperature and diminishing bonding time are in favor of the mollification of interface tresses.

• 한국세라믹학회지
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• 제30권2호
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• pp.93-100
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• 1993

The effects of MgO addition on thermal expansiion coefficient and dielectric constant of mullite were studied. Thermal coefficient and dielectric constant decrease with increasing MgO content and exhibit a minimum value at 1wt% MgO. However, above 3wt% MgO content both values increase. Result of X-ray diffraction analysis how that mullite compositions which include more than 0.1wt% MgO form cordierite. Spinel is also formed as well as cordierite in the composition containing more than 3wt% MgO. The results indicate that addition of MgO affect the thermal expansion coefficient and dielectric constant of mullite substrate because of the formation of new phases; cordierite and spinel. The thermal expansion coefficient and dielectric constant are affected mainly by cordierite and spinel in the regions containing less than more than 3wt% MgO, respectively.

• 폴리머
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• 제31권3호
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• pp.206-214
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• 2007

3차원적 타원체 형태 ($a_1>a_2>a_3$)를 사용하여, 2가지의 종횡비 (1차 종횡비 $\rho_{\alpha}$와 2차 종횡비 $\rho_{\beta}$)를 갖는 배열된 3차원 형태의 충전제를 포함하는 복합체의 열팽창 변화를 이론적으로 예측하는 모델을 연구하였다. Eshelby의 등가 텐서를 이용하여 배열된 타원형 충전제를 기지재의 이론에 의해 열팽창 계수를 예측할 수 있었다. 종단방향 열팽창 계수 ${\alpha}_{11}$는 두 가지 종횡비 모두 증가하면, 감소하여 충전제의 열팽창에 접근한다. 수직방향 열팽창 계수 ${\alpha}_{33}$는 충전제 함유량에 따라 초기에는 증가하여 최대값을 갖는 경향을 보인다. 1차 종횡비 $\rho_{\alpha}$가 증가하면, 횡단방향 열팽창 계수는 감소하나, 2차 종횡비 $\rho_{\beta}$가 증가하면, 같이 증가한다. 또한, 수직방향 열팽창 계수 ${\alpha}_{33}$는 $\rho_{\alpha}$가 증가하면 증가하나, $\rho_{\beta}$가 증가하면, ${\alpha}_{33}$는 반대로 감소한다.

• 한국세라믹학회지
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• 제24권5호
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• pp.411-416
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• 1987

Thermal expansions and thermal expansion coefficients of cordierite ceramics reinforced by SiC whiskers up to 40 vol. % were investigated. The composite specimens were hot pressed at 1523K for 30 min under 28.5 MPa pressing pressure in Ar atmosphere. Thermal expansions of the hot pressed composites were measured using a differential dilatometer up to 1262 K in air. Thermal expansions and thermal expansion coefficient of the composites increased with SiC whisker content. Thermal expansion behaviors of the composites were well explained by modelling parallel slabs randomly distributed on the whisker plane as the microstructural element of the composites.

• Computers and Concrete
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• 제18권5호
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• pp.937-950
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• 2016

This study applied autoclave expansion and heat curing to accelerate the hydration of concrete and investigated how these methods affect the expansion rate, crack pattern, aggregate size effect, and expansion of electric arc furnace oxidizing slag (EOS)-containing concrete. An expansion prediction model was simulated to estimate the expansion behavior over a long period and to establish usage guidelines for EOS aggregates. The results showed that the EOS content in concrete should range between 20% and 30% depending on the construction conditions, and that coarse aggregates with a diameter of ${\geq}4.75-mm$ are not applicable to construction engineering. By comparison, aggregates with a size of 1.18-0.03 mm resulted in higher expansion rates; these aggregates can be used depending on the construction conditions. On Day 21, the prediction model attained a coefficient of determination ($R^2$) of at least 0.9.

• 한국세라믹학회지
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• 제42권5호
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• pp.346-351
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• 2005

The linear thermal expansions of $UO_2$ and $(U_{1-y}Ce_y)O_2$ pellet were measured from room temperature to $1400^{\circ}C$ as a function of Ce contents (0, 7.63, 14.84, and $21.68 mol\%$) by using the TMA(Thermo-Mechanical Analysis) method. From the measured data, the linear thermal expansion rate, the coefficient of linear thermal expansion and density variation with temperature were calculated, and the best-fitted temperature-dependent equations were recommended. It was shown that the rate and coefficient of $(U_{1-y}Ce_y)O_2$ thermal expansion increased and the density decreased with increasing Ce contents.

• 한국재료학회지
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• 제20권2호
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• pp.72-77
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• 2010

Glass-ceramics were fabricated by heat-treatment of glass obtained by melting a coal bottom ash with $Li_2O$ addition. The main crystal grown in the glass-ceramics, containing 10 wt% $Li_2O$, was $\beta$-spodumene solid solution, while in $Li_2O$ 20 wt% specimen was mullite, identified using XRD. The activation energy and Avrami constant for crystallization were calculated and showed that bulk crystallization behavior will be predominant, and this expectation agreed with the microstructural observations. The crystal phase grown in $Li_2O$ 10 wt% glass-ceramics had a dendrite-like shaped whereas the shape was flake-like in the 20 wt% case. The thermal expansion coefficient of the $Li_2O$ 10 wt% glass-ceramics was lower than that of the glass having the same composition, owing to the formation of a $\beta$-spodumene phase. For example, the thermal expansion coefficient of $Li_2O$ 10 wt% glass-ceramics was $20\times10^{-7}$, which is enough for application in various heat-resistance fields. But above 20 wt% $Li_2O$, the thermal coefficient expansion of glass-ceramics, on the contrary, was higher than that of the same composition glass, due to formation of mullite.

• 한국세라믹학회지
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• 제50권6호
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• pp.470-475
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• 2013

In this study, we report that effects of a filler with a high coefficient of thermal expansion on a sealant for high-temperature ($750{\sim}850^{\circ}C$) SOFC. We designed a $SiO_2-BaO-ZnO-B_2O_3-Al_2O_3$ glass system with a softening temperature higher than $750^{\circ}C$. The properties of the glass system show not only low volumetric shrinking but also low swelling. The glass system did not create a crystal phase during along-term heat treatment. We fabricated a seal gasket with 0, 10, 15, and 20 wt% cristobalite added as filler materials with glass powder. The coefficient of thermal expansion of the seal gasket increased according to cristobalite content. During along-term heat treatment, the leak rate decreased by about 5% after a heat treatment in an oxidizing atmosphere at $750^{\circ}C$ for 2000 h, also decreasing by about 6% after a heat treatment in a reducing atmosphere at $750^{\circ}C$ for 1000 h.