• Title/Summary/Keyword: exothermic performance

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Evaluation of the Exothermic Properties and Reproducibility of Concrete Containing Electro-conductive Materials (전기전도성 재료를 혼입한 콘크리트의 발열특성 및 재현성 평가)

  • Song, Dong-Geun;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.25-34
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    • 2016
  • From 1990's, a study on the development of exothermic concrete, a concrete which electro-conductive material is mixed, has been proceeded. However, due to the difficulty of exothermic reproducibility of concrete specimen, the study has been unable to continuously carried out. Accordingly, this study was focused on developing an exothermic concrete for the purpose of snow-melting material. Cement paste and mortar specimens mixed with graphite, conductive metal powder and chemical admixture were made. The evaluation of exothermic performance and reproducibility was conducted under $-2^{\circ}C$ of low temperature. In addition, micro-chemical analysis was carried out to investigate a cause of exothermic reproducibility. As a test result, the specimen mixed with graphite and superplasticizer with air entrained showed the best exothermic performance and reproducibility. Through micro-chemical analysis, it is judged that polymer or methacrylic acid (MAA), the contents inside the superplasticizer with air entrained, gave exothermic reproducibility by generating the electrochemical reaction with graphite.

An improvement on the concrete exothermic models considering self-temperature duration

  • Zhu, Zhenyang;Chen, Weimin;Qiang, Sheng;Zhang, Guoxin;Liu, Youzhi
    • Computers and Concrete
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    • v.19 no.6
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    • pp.659-666
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    • 2017
  • Based on the Arrhenius equations, several hydration exothermic models that precisely calculate the influence of concrete's self-temperature duration on its hydration exothermic rate have been presented. However, the models' convergence is difficult to achieve when applied to engineering projects, especially when the activation energy of the Arrhenius equation is precisely considered. Thus, the models' convergence performance should be improved. To solve this problem and apply the model to engineering projects, the relationship between fast iteration and proper expression forms of the adiabatic temperature rise, the coupling relationship between the pipe-cooling and hydration exothermic models, and the influence of concrete's self-temperature duration on its mechanical properties were studied. Based on these results, the rapid convergence of the hydration exothermic model and its coupling with pipe-cooling models were achieved. The calculation results for a particular engineering project show that the improved concrete hydration exothermic model and the corresponding mechanical model can be suitably applied to engineering projects.

An experimental analysis of work factors in Pre-combustion Chamber Diesel Engine (예연소실식 디이젤기관 일량구성인자에 관한 실험적 연구)

  • 최갑석;류정인
    • Journal of Advanced Marine Engineering and Technology
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    • v.11 no.1
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    • pp.53-62
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    • 1987
  • The Performance of Pre-combustion Chamber Diesel Engine mainly depends upon the compression, combustion and Expansion Processes. The analysis of varying tendency of the work factors for crank angles during these processes, which are consisted of 5 items such as exothermic energy, flow work, work in nozzle part, kinetic energy and cooling energy, are considered important as basic elements for effective combustion and performance improvement. In this paper, varying tendencies of the theoretical factors are investigated with pressure data through experiments. By the results, the trends of work factors are presented as basic data for comparing the influencing effects on work.

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A Study on Toluene Oxidation Reaction Characteristics of Ni-Based Catalyst in Induction Heating System (유도가열 시스템을 이용한 Ni계 촉매의 톨루엔 산화 반응 특성 연구)

  • Lee, Ye Hwan;Kim, Sung Chul;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.627-631
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    • 2021
  • Research on induction heating catalyst system was conducted to solve problems of the existing catalyst system for removing volatile organic compounds. In the present study, three types of Ni-based commercial catalysts were employed, and induction heating reaction characteristics including the catalyst volume, composition, heat treatment atmosphere, and position in the coil were investigated. The composition and volume of the catalyst affected the exothermic and toluene oxidation performance in the induction heating system. In particular, the Fe-added catalyst showed high exothermic performance compared to that of other catalysts consisting of more than 99% Ni, but had low toluene oxidation performance. In addition, the heat treatment in an air atmosphere of the Ni-based catalyst drastically reduced the performance. In the induction heating system, the optimal condition for the catalyst was to be located in the center of the coil. The catalyst showed similar activities among seven repeated experiments under the optimal condition derived from this work.

Development of exothermic system based on internet of things for preventing damages in winter season and evaluation of applicability to railway vehicles

  • Kim, Heonyoung;Kang, Donghoon;Joo, Chulmin
    • Smart Structures and Systems
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    • v.29 no.5
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    • pp.653-660
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    • 2022
  • Gravel scattering that is generated during operation of high-speed railway vehicle is cause to damage of vehicle such as windows, axle protector and so on. Especially, those are frequently occurred in winter season when snow ice is generated easily. Above all, damage of vehicle windows has not only caused maintenance cost but also increased psychological anxiety of passengers. Various methods such as heating system using copper wire, heating jacket and heating air are applied to remove snow ice generated on the under-body of vehicle. However, the methods require much run-time and man power which can be low effectiveness of work. Therefore, this paper shows that large-area heating system was developed based on heating coat in order to fundamentally prevent snow ice damage on high-speed railway vehicle in the winter season. This system gives users high convenience because that can remotely control the heating system using IoT-based wireless communication. For evaluating the applicability to railroad sites, a field test on an actual high-speed railroad operation was conducted by applying these techniques to the brake cylinder of a high-speed railroad vehicle. From the results, it evaluated how input voltage and electric power per unit area of the heating specimen influences exothermic performance to draw the permit power condition for icing. In the future, if the system developed in the study is applied at the railroad site, it may be used as a technique for preventing all types of damages occurring due to snow ice in winter.

Hydration Heat Properties of High Flowing Self-Compacting Concrete with Normal Strength (보통강도 고유동 자기충전 콘크리트의 수화발열 특성)

  • Choi, Yun-Wang;Kim, Byoung-Kwon;Lee, Jae-Nam;Ryu, Deug-Hyun;Song, Yong-Kyu;Jung, Woo-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.497-500
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    • 2008
  • This research carries out experiments for hydration exothermic rate and adiabatic temperature rise of concrete to examine the characteristics of the hydration heat of high flowing self-compacting concrete with a normal strength. As a result of the hydration exothermic rate experiment, the high flowing self-compacting concrete that used Lime stone powder and fly ash as polymers shows that its hydration heat amount reduces due to the reduction of unit cement. The result measured the adiabatic temperature rise of concrete presents that high flowing self-compacting concrete having lots of binder contents has a good performance in temperature reduction due to the effect of polymer and that triple adding high flowing self-compacting concrete has a similar temperature rise speed with conventional concrete. As a result of the research, high flowing self-compacting concrete shows a better temperature reduction performance for the binder content per unit than conventional concrete. In addition, it is judged that triple adding high flowing self-compacting concrete with a specified concrete strength 30 MPa is more beneficial in temperature reduction and early hydration heat than double adding high flowing self-compacting concrete.

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A Performance Study of Portable Hydrogen Storage Tank (휴대용 수소 저장체 성능 특성 연구)

  • Park, Joon-Ho;Hwang, Yong-Sheen;Jee, Sang-Hoon;Kim, Sung-Han;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.315-318
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    • 2009
  • Hydrogen is the ideal candidate as an alternative energy carrier, so many hydrogen storage methods are investigated. The hydrogen storage method using metal hydride is good candidate as energy sources for portable devices because hydrogen-storage as metal hydride shows large volumetric storage density. In this study, we investigated the variations of hydrogen charging/discharging performance of metal hydride tanks at different temperature conditions. We charged metal hydride tanks with hydrogen in low temperature because of the exothermic reactions of hydrogen absorption while we discharged in high temperature to provide sufficient heat because of the endothermic reactions of desorption. In addition, we investigated the difference of hydrogen charging/discharging performance between two tanks having different sizes.

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Ignition Studies Of Igniter using Hydrogen Peroxide And Kerosene (Catalyst Ignition) (과산화수소/케로신(촉매점화) 점화기의 점화특성에 관한 연구)

  • Kim, Ki-Woo;Kim, Tae-Wan;Lee, Yang-Suk;Kim, Yoo;Ko, Young-Sung;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.57-60
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    • 2009
  • Exothermic and ignition characteristic of igniter is very important factor in engine performance. Since the igniter performance is effected by Hydrogen Peroxide decomposition rate, we have to test the preliminary catalyst performance test. In this report, after making igniter using hydrogen peroxide/kerosene, a thermal characteristic were examined by comparing hydrogen peroxide mass and catalyst mass. And then we study ignition characteristic of the affects of O/F ratio using the previous data.

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Process Optimization for Preparing High Performance PAN-based Carbon Fibers

  • Yun, Jeong-Hyeon;Kim, Bo-Hye;Yang, Kap-Seung;Bang, Yun-Hyuk;Kim, Sung-Ryong;Woo, Hee-Gweon
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2253-2258
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    • 2009
  • wet spun polyacrylonitrile (PAN) fiber precursors. The process variables chosen were treatment temperature, applied tension in stabilization process. The temperature profile of the stabilization was set on the basis of exothermic peaks of the differential scanning calorimetry (DSC) result. Both tensile strength and modulus increased with holding at onset temperatures of the exothermic peaks for extended duration, and with a higher heating rate up to the onset temperatures at a given applied tension among the experimental conditions. The increase in load monotonously increased the tensile modulus, on the other hand, the tensile strength was maximum at the load of 15 mg/filament (T15). The load 20 mg/ filament (T20) was considered to be exceeded to form oriented crystalline structure, possibly introducing more defects in the fiber than under load of T15. The sample CP3-T15 O5 H30 showed the best tensile properties among the samples experimented whose tensile properties are compatible with the commercialized grade of general purpose carbon fibers even at low carbonization temperature such as $800\;{^{\circ}C}$ (the carbonization temperature in the commercial process. 1300∼$1500\;{^{\circ}C}$).

Numerical Analysis of dynamic behavior and steady state characteristics of methane autothernal reformer (메탄 자열 개질기의 동적 거동 및 정상 특성에 관한 수치적 연구)

  • Lee, Shin-Ku;Park, Joon-Guen;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.5-8
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    • 2007
  • In this paper, numerical investigation has been carried out to study performance of methane autothermal reformer and dynamic behavior for light-off under various operating conditions. In order to simulate the given problems, numerical methods are incorporated using finite-volume method. In addition, porous medium approach is accepted because the catalytic phenomena occur in porous media. Also, start-up issue is significant in autothermal reformer although the reaction is marginally exothermic. Thus, in this study transient behavior has been also investigated to find out optimal operating conditions for start-up.

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