• 제목/요약/키워드: exchange process

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Structure and Properties of Cation Exchange Membrane made of Sulfonated Polyethersulfone

  • Nah, Sung-Soon;Lee, Sung-Min;Ryul, Min-Byung;Lee, Chang-So
    • 한국막학회:학술대회논문집
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    • 한국막학회 1999년도 The 7th Summer Workshop of the Membrane Society of Korea
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    • pp.115-115
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    • 1999
  • In this work a new process was developed for the sulfonation of the chemicallly stable engineering polymer polyethersulfone as membrane materials for electrodialysis or a flow battery applications. Commercially available polyethersulfone polymer was partially sulfonated using a CSA sulfonating agent in a dichloromethane solvent, which sulfonated polyethersulfone with various sulfonation levels have been prepared. Sulfonated polyethersulfone (SPES) membranes with different ion capacities were prepared for the purpose of identifying cation exchange membrane properties, in an attempt to find a low cost replacement for Nafion, which most of the perfluorinated membranes, known to exhibit a prolonged service life, are expensive and difficult to process. The following features were determined: the degree of sulfonation, water uptake, thermal analysis, and electrochemical properties such as ion exchange capacities, resistivity, selectivity of ion permeation. The surface of the cation exchange membranes, decomposed with the H202-treatment, were observed by using scanning electron microscope. The area resistivities of SPES mebranes in 5N-NaOH decreased from $2,150{\;}{\Omega}-cm2$ to less than $15{\Omega}-cm2$ as the ion exchange capacity (IEC) increased from 0.62 to 1.73 millieequivlants per dry gram(meq/dg).eq/dg).

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Development of the Abstract Test Cases of Ship STEP

  • Kim Yong-Dae;Hwang Ho-Jin
    • Journal of Ship and Ocean Technology
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    • 제9권3호
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    • pp.23-32
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    • 2005
  • Ship STEP(Standard for the Exchange of Product Model Data) which is composed of AP 215 (Ship Arrangement), AP 216(Ship Hull Form), AP 218 (Ship Structure), has been developed more than last 10 years and it is now at the stage just before IS(International Standard). It is expected that ship STEP would be used for the seamless data exchange among various CAD/CAM/CAE systems of shipbuilding process. In this paper the huge and complicated data structure of ship STEP is briefly reviewed at the level of ARM(Application Reference Model) and some abstract test cases which will be included as part of the standards are introduced. Basically ship STEP has common data model to be used without losing compatibility among those three different ship AP's, and it is defined as the modeling framework. Typical cases of data exchange during shipbuilding process, such as hull form data exchange between design office and model basin, midship structure data between shipbuilding yard and classification society are reviewed and STEP physical data are generated using commercial geometric modeling kernel. Test cases of ship arrangement at initial design stage and hydrodynamic data of crude oil carrier are also included.

이온교환법에 의한 탈질소 공정개발의 기초연구(V) -질산성 질소 선택적인 이온교환수지의 합성- (Basic Study for Development of Denitrogenation Process by Ion Exchange(V) -Synthesis of Nitrate-Selective Ion Exchange Resines-)

  • 이동환;김승일;전진희;박찬영;이민규
    • 한국환경과학회지
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    • 제9권4호
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    • pp.319-323
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    • 2000
  • Nitrate-selective ion exchange resin which have bulky tertiary amine as functional group have been synthesized by the reaction of chloromethylated polystyrene-divinylbenzene copolymer and the corresponding tertiary amine [$NR_3=NE_{t3} 1, N{(C_2 H_4 H_3)}_32]$in ethanol, while commercial resin has $NMe_3$ as functional group. The fundamental properties such as bulk density, water content, appearance index, exchange capacity, effective size, uniformity coefficient of synthesized anion exchange resin (1) have been measured. The ion exchange resin (1) and (2) exhibited the better selectivity for nitrate than sulfate in both batch and continuous column experiments.

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Iron hydrolysis and lithium uptake on mixed-bed ion exchange resin at alkaline pH

  • Olga Y. Palazhchenko;Jane P. Ferguson;William G. Cook
    • Nuclear Engineering and Technology
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    • 제55권10호
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    • pp.3665-3676
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    • 2023
  • The use of ion exchange resins to remove ionic impurities from solution is prevalent in industrial process systems, including in the primary heat transport system (PHTS) purification circuit of nuclear power plants. Despite its extensive use in the nuclear industry, our general understanding of ion exchange cannot fully explain the complex chemistry in ion exchange beds, particularly when operated at or near their saturation limit. This work investigates the behaviour of mixed-bed ion exchange resin, saturated with species representative of corrosion products in a CANDU (Canadian Deuterium Uranium) reactor PHTS, particularly with respect to iron chemistry in the resin bed and the removal of lithium ions from solution. Experiments were performed under deaerated conditions, analogous to normal PHTS operation. The results show interesting iron chemistry, suggesting the hydrolysis of cation resin bound ferrous species and the subsequent formation of either a solid hydrolysis product or the soluble, anionic Fe(OH)3-.

이온교환법에 의한 탈질소 공정개발의 기초연구(II) (Basic Study for Development of Denitrogenation Process by ion Exchange(II))

  • 이민규;주창식
    • 한국환경과학회지
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    • 제7권1호
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    • pp.89-95
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    • 1998
  • Ion exchange performance to remove nitrate in water was studied using commercially available strong base anion exchange resin of Cl- type in the batch and continuous column reactors. The performance was tested using the effluent concentration histories for continuous column or equilibrium conquilibrium between resin and solution. Anion exchange resin used in this study was more effective than activated carbon or zeolite for nitrate removal. With large resin amount or low initial concentration, nitrate removal characteristics for a typical gel-type resin was Increased. On considering the relation between the breakthrough capacity and nitrate concentration of the influent, the use of anion exchange resin were suitable for the hi선or order water treatment. The nitrate removal of above 90% could be possible until the effluent of above 650 BV was passed to the column. Thus, the commercially available strong base anion exchange resin of $Cl^-$ type used in thins study could be effectively used as economic material for treatment of the groundwater. The breakthrough curves showed the sequence of resin selectivity as $SO_4^{2-}$ > $NO_3$ > $NO^{2-}$ > $HCO_3^-$. The results of this study could be scaled up and used as a design tool for the water purification system of the real groundwater and surface water treatment processes.

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사이버 해운거래소 구축 방안 (Design of The Cyber Shipping Exchange)

  • 최형림;박남규;김현수;박영재;황성원;박용성
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2002년도 춘계학술대회논문집
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    • pp.39-51
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    • 2002
  • Online exchange is a cost-effective approach to trade goods and information among multiple sellers and buyers. Shipping industry includes lots of global entities such as shippers, liners, ship owners and shipping agents. Marine insurance companies and ship repairers and many other groups are also supporting the industry. However, international shipping exchanges are located on few cities in the world. Its our motivation that a shipping market can be online so that market participants do the dealing while sitting where they are with more efficient manner, preferable price and larger pool of candidates of trading partners. This paper presents Korean governmental project of building a cyber shipping exchange. The exchange covers ship sale and purchase, charter, insurance, freight futures, repairs, supplying of ships oil and database service. The workflows of each business were analyzed and designed to fit for online environment. The project includes design of trading mechanism, online documents, data flow, data storage and security. Online match making and trading mechanisms such as auction, reverse auction, bid are used. The whole trading process involves multiple organizations and business processes. So, this Paper focuses on how each organization would play their roles so that users can complete transactions with integrated and transparent view. The online exchange selves also as maritime portal site that links to other sites for cooperation vertically or horizontally, and serves database and information in global perspective. This paper also issues and discusses the justification of an online shipping exchange

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Ag(II)매개산화에 의한 폐 유기이온교환수지의 분해 (Destruction of Spent Organic ion Exchange Resins by Ag(II)-Mediated Electrochemical Oxidation)

  • 최왕규;남혁;박상윤;이근우;오원진
    • 전기화학회지
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    • 제2권4호
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    • pp.183-189
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    • 1999
  • 원자력 시설의 가동 및 유지보수 중에 중$\cdot$저준위 방사성폐기물로 다량 생성되는 폐 유기이온교환수지를 상온의 수용 상 내에서 분해 처리하는 공정을 개발할 목적으로, 전기화학적으로 생성되는 Ag(II)를 매개산화제로 사용하여 양이온 및 음이온교환수지의 분해 연구를 수행하였다. Ag(II) 매개산화 공정에서 제어 가능한 인자인 전류, 온도 및 전해질 농도가 이온교환수지의 분해거동에 미치는 영향을 고찰하였다. 양이온교환수지는 거의 대부분 $CO_2$로 분해되었으며, 전류밀도가 감소할수록 전류효율이 증가됨을 보인 반면에 양극전해질로 사용된 질산의 농도 및 온도가 증가하더라도 분해거동에는 영향을 미치지 않았다. 양이온교환수지와는 달리 음이온교환수지의 분해시에는 온도와 무관하게 약 $10\%$ 정도가 CO로 분해되었고, $CO_2$로의 분해효율은 온도에 의존하는 경향을 보였으며, $60^{\circ}C$ 이상에서 효과적으로 분해가 가능하였다.

$^{13}C$ NMR Studies of the Chelate Ring Opening-Closing Process in (Nitrilotriacetato)vanadate(V) dioxovandate(V) Ion

  • Lee, Man-Ho;Schaumburg, Kjeld
    • Bulletin of the Korean Chemical Society
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    • 제11권5호
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    • pp.399-402
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    • 1990
  • Activation parameters of the exchange between two types of glycinate groups in (nitrilotriacetato)dioxovanadate(V) ion, $[VO_2(NTA)]^{2-}$, have been determined as the results of $^{13}C$ NMR measurements over a range of temperatures between 277 and 306$^{\circ}K$. The exchange mechanism is proposed on the basis of the chelate ring opening-closing process, assuming rupture of the metal-oxygen (glycinate) bond trans to V = O bond to give a five-coordinated intermediate.

STEP표준과 Web을 이용한 RPD환경 구축 (Development of a STEP-compliant Web RPD Environment)

  • 강석호;김민수;김영호
    • 한국CDE학회논문집
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    • 제5권1호
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    • pp.23-32
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    • 2000
  • In this paper, we present a Web-enabled product data sharing system for the support of RPD (Rapid Product Development) process by incorporating STEP (STandard for the Exchange of Product model data) with Web technology such as VRML (Virtual Reality Markup Language), SGML (Structured Generalized Markup Language) and Java. Extreme competition makes product life cycle short by incessantly deprecating current products with a brand-new one, and thus urges enterprises to devise a new product faster than ever. In this environment, an RPD process with effective product data sharing system is essential to outstrip competitors by speeding up the development process. However, the diversity of product data schema and heterogeneous systems make it difficult to exchange the product data. We chose STEP as a neutral product data schema and Web as an independent exchange environment to overcome these problems. While implementing our system, we focused on the support of STEP AP 203 UoF (Units of Functionality) views to efficiently employ STEP data models that are maximally normalized, and therefore very cumbersome to handle. Our functionality-oriented UoF view approach can increase users'appreciation since it facilitates the modular usage of STEP data models. This can also enhance the accuracy of product data. We demonstrate that our view approach is applicable to the configuration control of mechanical assemblies.

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The Relationship Between Corporate Governance and Underpricing: A Case Study in Ho Chi Minh Stock Exchange

  • TRAN, Khang Hoang;NGUYEN, Diep Thi Ngoc;KNAPKOVA, Adriana;ALIU, Florin
    • The Journal of Asian Finance, Economics and Business
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    • 제8권7호
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    • pp.375-381
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    • 2021
  • Underpricing signifies that IPO share prices do not reflect the fundamental value of the listed company. Corporate governance plays an essential role in IPOs where the board of directors, the independent board of directors, and the board of supervisors are significant elements of accurate share pricing. The study investigates the underpricing phenomena and short-term performance of the IPO companies during the listing process in the Ho Chi Minh Stock Exchange (HOSE). The work outcomes illustrate the role of the corporate organizational structure in the period of the IPO process that may attract potential investors. The hypothesis testing is conducted with a multiple regression model including 100 observations from enterprises doing IPO listed on HOSE. The study results generate signals for the investors and regulators that the board of directors holds a strong negative influence on the underpricing process. Secondly, the level of the independent board of directors and stock exchange in itself has no significant impact on the underpricing process. Underpricing is one of the many anomalies of the stock exchanges that provide wrong signals for the market participants. Identifying stock prices that reflect their intrinsic value is an ongoing debate among scholars, investors, and other market participants.