• 제목/요약/키워드: excess water

검색결과 793건 처리시간 0.025초

등온 미세열량계를 이용한 n-Hexane-알칸계 이성분 혼합물 및 NaOH/Water/Ethanol계의 과잉 엔탈피 측정 및 계산 (Measurement and Calculation of Excess Enthalpies for n-Hexane/Alkane series and NaOH/Water/Ethanol System using Isothermal Microcalorimeter)

  • 최인규;유성식
    • Korean Chemical Engineering Research
    • /
    • 제55권5호
    • /
    • pp.660-667
    • /
    • 2017
  • 화학공정에서 증류 또는 추출 등 분리 장치의 설계 및 조업에 있어서 혼합물의 평형데이터는 필수적이다. 이들 평형데이터는 실험을 통해서 얻거나 알려진 이성분 매개변수를 이용하여 모델에 의한 계산으로 얻을 수 있다. 일반적으로 이들 매개변수를 구하기 위해서 기-액, 액-액 등의 상평형 실험 데이터를 주로 이용하지만, 본 연구에서는 보다 간편한 방법으로서 흐름형 미세열량계를 이용하여 혼합물의 과잉엔탈피 실험데이터를 얻고, 이 데이터를 이용하여 여러 이론들의 매개변수를 구하고자 하였다. 더불어, 알칸계의 경우 탄소의 사슬길이와 엔탈피 그리고 이성분 매개변수간의 관계를 알아보고자 하였으므로 n-hexane + alkane (n-pentane, n-heptane, n-octane, n-dodecane)계들에 대해서 298.15 K에서 과잉엔탈피를 측정하였으며, 이 실험데이터로부터 Wilson, NRTL, UNIQUAC의 매개변수를 구하였다. 또한, 다양한 분야에 적용 가능한 전해질 계의 상호작용 및 회합현상에 대한 기본정보를 과잉엔탈피 실험 데이터들과 기존 이론을 이용하여 얻고자 하였다. 우선은 기초적인 실험으로서 NaOH/Water/Ethanol 계에 대한 과잉 엔탈피를 측정하고, electrolyte-NRTL(eNRTL) 이론을 이용하여 응용성을 검토하고자 하였다.

DSC구성방정식을 이용한 포화사질토의 액상화 거동 예측 (A Study on Prediction of the Liquefaction Behavior of Saturated Sandy Soils Using DSC Constitutive Equation)

  • 박인준;김수일;정철민
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 2000년도 가을 학술발표회 논문집
    • /
    • pp.201-208
    • /
    • 2000
  • In this study, the behavior of saturated sandy soils under dynamic loads - pore water pressure and effective stress - was investigated using Disturbed State Concept(DSC) model. The model parameters are evaluated from laboratory test data. During the process of loading and reverse loading, DSC model is utilized to trace strain-hardening and cyclic softening behavior. The procedure of back prediction proposed in this study are verified by comparing with laboratory test results. From the back prediction of pore water pressure and effective mean pressure under cyclic loading, excess pore water pressure increases up to initial effective confining pressure and effective mean pressure decrease close to zero in good greement with laboratory test results. Those results represent the liquefaction of saturated sandy soils under dynamic loads. The number of cycles at initial liquefaction using the model prediction is in good agreement with laboratory test results. Therefore, the results of this study state that the liquefaction of saturated sandy soils can be explained by the effective tress analysis.

  • PDF

유성지역 소유역에서 추적자(Cl)를 이용한 강우사상에 따른 지표수로부터 기저유출의 분리

  • 조성현;하규철;고동찬;조민조;송무영
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2005년도 총회 및 춘계학술발표회
    • /
    • pp.352-358
    • /
    • 2005
  • This study aims to separate hydrograph into baseflow and event water to calculate baseflow rate during a rainfall in small catchments, Yuseong, Daejeon, The hydrograph of stream during a period with no excess rainfall will decay. The discharge is composed entirely of groundwater contributions. During the period, the Cl concentration of the stream water can be regarded as being in equilibrium with that of the groundwater. Using Cl as a conservative tracer, two-component hydrograph separations were performed from end point of the period to next end point. The required data were obtained by monitoring of the surface water table, along with discharge rate of stream. Cl concentration of rainfall, surface water were measured and recorded. Hydrograph separation, a mixing model using chemical tracer is applied to chemical hydrograph separation technique. These results show that baseflow rates are 31.6% of rainfall in the catchments during study period.

  • PDF

배합수량 변동에 따른 콘크리트의 경화성상 및 내구성에 관한 연구 (A Study on Hardened Properties and Durability of Concrete according to Unit-Water Content)

  • 구경모;임창혁;이의배;김영선;김영선;김규용
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
    • /
    • pp.45-48
    • /
    • 2009
  • The performance of concrete mainly depend upon its water-cement ratio. If water percentage is excess in concrete, it may cause the degradation of performance. Because of these reasons, the change of water content is managed by using various evaluation method of unit water content. And criterion for the change of water content is regulated and used. However the criterion is set only considering production error and measurement error but criterion does not consider performance degradation of concrete. Therefore this study tries to investigate degradation of performance while adding extra water by artificial manipulation or management error in concrete, The contents of extra water for tests are set as 0, 20, 40, 60kg/m3, to examine the performance degradation of concrete, strength, shrinkage, cracks, carbonation are tested This study conclude that, when extra water content is excess than 20kg/m3 in concrete, then performance level of concrete declined rapidly. 80 it is very important to maintain quality of concrete for its better performance.

  • PDF

Response of Millet and Sorghum to Water Stress in Converted Poorly Drained Paddy Soil

  • Jung, Ki-Yuol;Yun, Eul-Soo;Park, Chang-Young;Hwang, Jae-Bok;Choi, Young-Dae;Oh, In-Seok
    • 한국토양비료학회지
    • /
    • 제46권6호
    • /
    • pp.409-416
    • /
    • 2013
  • Millet and sorghum are major dryland cereal crops, however their growth and productivity is limited by soil water stress with varying intensity. The major objective of this study was to evaluate water stress of millet and sorghum yield under drainage classes of poorly drained soil and to test the effect of the installed pipe drainage in poorly drained paddy soil to minimize crop stress. The research was carried out in poorly drained paddy fields located at alluvial slopping area resulting in non-uniform water content distribution by the inflow of ground water from the upper part of the field. Stress Day Index (SDI) was determined from a stress day factor (SD) and a crop susceptibility factor (CS). SD is a degree of measurement by calculating the daily sum of excess water in the profile above 30cm soil depth ($SEW_{30}$). CS depends on a given excess water on crop stage. The results showed that sum of excess water day ($SWD_{30}$) used to represent the moisture stress index was lower on somewhat poorly drained soil compared with poorly drained soil on 117 days. CS values for sorghum were 57% on $3^{rd}$ leaf stage, 44% on $5^{th}$ leaf stage, 37% on panicle initiation, 23% on boot stage, and 16% on soft dough stage. For proso millet CS values were 84% on $3^{rd}$ leaf stage, 70% on $5^{th}$ leaf Stage, 65% on panicle initiation, 53% on boot stage, and 28% on soft dough stage. And for foxtail millet the values were 73% on $3^{rd}$ leaf stage, 61% on $5^{th}$ leaf stage, 50% on panicle initiation, 29% on boot stage, and 15% on soft dough stage. SDI of sorghum and millet was more susceptible to excess soil water during panicle initation stage more poorly drained soil than somewhat poorly drained soil. Grain yield was reduced especially in proso millet and Foxtail millet compared to Sorghum.

공동확장이론에 의한 Sand Pile 주변지반에서의 압밀특성에 관한 연구 (A Study on Consolidation Characteristics at Sand Pile Adjacent Ground by Cavity Expansion Theory)

  • 천병식;여유현
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 2000년도 봄 학술발표회 논문집
    • /
    • pp.231-238
    • /
    • 2000
  • Sand piling method is one of the most widely used methods to improve soft soils. There are several methods to install sand piles, but driven pile method is considered as one of the easiest method. This method simply pushes down the sand piles into soft soils, so that the excess pore pressure would be generated if the soil is saturated. This pore pressure acts as consolidation load. If the amount of sand pile induced pore pressure can be predicted in reasonable ways, the effects of sand piling to improve soft soils would be predicted, and the height of preload can be reduced. In this article, sand pile induced excess pressure was predicted by cavity expansion theory, and the predicted values were compared with the field measured values. The results showed fair agreements between the measured and the predicted excess pore pressure.

  • PDF

가스 하이드레이트가 매장된 해저사면의 붕괴에 관한 기초적 연구 (A Preliminary Study on Submarine Slope Failure of Gas Hydrate-bering Sediments)

  • 박성식
    • 한국지반공학회:학술대회논문집
    • /
    • 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
    • /
    • pp.399-404
    • /
    • 2008
  • The influence of gas hydrate dissociation on submarine slope stability was studied in this paper. Gas hydrates are stable under high pressure and low temperature conditions. Once gas hydrate dissociates due to natural or human activities, it generates large amount of gas and water. During gas hydrate dissociation, a pore pressure between soil particles increases and results in the loss of an effective stress and degradation of soil stiffness. A pore pressures model was proposed to calculated excess pore pressures generated by gas hydrate dissociation at the Storegga Slide. A slope stability analysis for the Storegga Slide using a two dimensional finite difference method was carried out by considering excess pore pressures due to gas hydrate dissociation. Since the excess pore pressure calculated by the proposed method resulted in the considerable loss of stiffness and strength in slope, a submarine slope failure occurred at the Storegga slide was well simulated.

  • PDF

퍼지-트랩 기체크로마토그래프/질량분석계에 의한 물시료 중 Trihalomethanes의 분석 및 위해성 평가 (The Analysis of Trihalomethanes in Water Sample by Purge-and-Trap Gas Chromatograph/Mass Spectrometer and Risk Assessment)

  • 곽선영;표희수;박송자
    • Environmental Analysis Health and Toxicology
    • /
    • 제20권1호
    • /
    • pp.29-37
    • /
    • 2005
  • Recently, significant contamination problems by residual chemicals have occasionally been occurred from major rivers and drinking water in Korea. Therefore, the management for use of them and risk assessment should be more strictly performed. In this study, we have analyzed trihalomethanes in treated water samples taken from water plants located in the region of four major rivers (i.e. Han river, Geum river, Youngsan river and Nakdong river) in Korea for eight years (1997~2004). From the data, we could assess the excess cancer risk by calculating the chronic daily intakes (CDI) multiplied by individual oral slope factors, Q₁*, for the cancer suspected matters such as trihalomethanes, moreover the hazard index which is calculated by dividing the CDI by the acceptable daily reference dose (R/sub f/D) was determined for the risk assessment. As a result, in the case of 95 percentile excess cancer risk, it was shown that the excess cancer risk for dichlorobromomethane in the Nakdong river region is highest among the tested samples as 8.73 x 10/sup -6/. The 95 percentile total hazard index (the sum of individual hazard indices considering R/sub f/D), in addition, was below 1.0 for all samples, and therefore it was assessed that water samples taken from treatment plants of four major rivers are not harmful.

전전환답 포장에서의 지하수위 및 토양수분 변화 특성 (Variational Characteristics of Water-Table and Soil Moisture in Paddy-Upland Rotational Fields)

  • 권순국;윤경섭
    • 한국농공학회지
    • /
    • 제36권2호
    • /
    • pp.123-131
    • /
    • 1994
  • Experimental studies were conducted to make clear the soil moisture environment under the condition of paddy-upland rotational fields by investigating water-table depths and soil moisture contents during growing season of crops in two kinds of soil. The following results were obtained. 1.Although water-table depths fluctuated with the amount of rainfall in the experimental field, it seemed that the variation of vater4able depths in the paddy-upland rotational, field was strongly affected by the condition of locations on paddy fields. 2.It is recognized that the concept of sum of excess water depth(SEWxx) and sum of excess water day(SEDxx) can be used to represent the soil moisture stress index due to the fluctuation of water-table depths. 3.The results of this study clearly indicate that drainage in paddy-upland rotational field to maintain an optimum soil moisture content must be made by introducing the concept of block drainage which needs both subsurface drainage and intercept drainage around a field. 4.Soil moisture contents were affected by both the amount of rainfall and water-table depths, however, the moisture content for top soil showed higher correlation with the amount of rainfall while that for subsoil with water-table depths.

  • PDF

막결합형 생물반응조에서 슬러지 전처리가 잉여슬러지 발생량에 미치는 영향 (Effects of Sludge Pre-Treatment on the Excess Sludge Production in a Membrane-Coupled Bioreactor)

  • 이강훈;김주현;;염익태
    • 상하수도학회지
    • /
    • 제25권4호
    • /
    • pp.565-572
    • /
    • 2011
  • The effects of chemical pretreatments on the excess sludge production in the membrane-coupled bioreactor were investigated. In addition, their effects on membrane fouling were also evaluated. Two membrane bioreactors were operated. In one reactor, a part of the mixed liquor was t reated with NaOH and ozone gas consecutively and was returned to the reactor. T he f lowrate of the chemical pretreatment stream was 1.5% of the influent flowrate. During the 200days of operation, the MLSS level in the bioreactor with mixed liquor pretreatment was maintained relatively constant at the range of 8,000 ~ 10,000$mg/{\ell}$ while it increased steadily up to 26,000 $mg/{\ell}$ in the absence of the pretreatment. Each reactor was equipped with two laboratory membrane modules where the flux for each module was 20, and 30 ${\ell}/m^2{\cdot}h$, respectively. With pretreatment, almost constant transmembrane pressure(TMP) was observed throughout the operation at the flux of 20 ${\ell}/m^2{\cdot}h$. Without pretreatment the membrane module at the same flux could also be operated at relatively stable condition. However, as the MLSS increases up to 25,000 $mg/{\ell}$, a fast TMP increase was observed. In conclusion, a complete control of excess sludge production in the membrane-coupled bioreactor was possible without significant deterioration of the treated water quality. In addition, it was shown that stable operation in terms of TMP is possible with sludge pretreatment and recirculation.