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유/무기하이브리드 용액에 의한 SPCC, SPFC590, SPFC780 강판의 내식성 (일정한 멜라민에서 SiO2 polysilicate 양이 다른 경우) (Corrosion Resistance of SPCC, SPFC590, SPFC780 Steel by Organic/Inorganic Hybrid Solution (Case of different SiO2 polysilicate under a constant melamin))

  • 남기우;정희록;이광호
    • 동력기계공학회지
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    • 제21권2호
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    • pp.5-13
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    • 2017
  • This study has developed an organic/inorganic hybrid solution according to amount of $SiO_2$ polysilicate, and the amount of melamine is constant. The three types of cold rolled steel were evaluated a corrosion resistance properties by using these solutions. $US_3M_3$ and $US_{11}M_3$ solutions were generate a lot of corrosion. $US_7M_3$ solution was excellent in corrosion resistance, regardless of the steel type. The appearance of coating by $US_3M_3$ and $US_{11}M_3$ solutions were bumpy surface, and were a lot of fine defects. $US_7M_3$ solution was made a sophisticated molecular cross-linking structure inside the coating, it was a slick surface. Other characteristics are exhibited the excellent property for all solutions.

염산(鹽酸)Promazine 주사제(注射劑)의 안정화(安定化)에 관한 연구(硏究) (Study on Stabilization of Promazine Hydrochloride Injection)

  • 이완하;지웅길;양재헌
    • Journal of Pharmaceutical Investigation
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    • 제3권3호
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    • pp.5-15
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    • 1973
  • The stabilizing effect of promazine hydrochloride injectin was tested by irradiation of sun lamp(5,000 Lux) on their acid solution sealed in ampules under various stabilizers. The result of experimentation on the color change, the remaining proportion and the half life of promazine hydrochloride solution is as follows. 1. Instability of promazine hydrochloride solution is mainly caused by the sunlight and oxygen. 2. The pH range of promazine hydrochloride injection is recommended to $pH\;4.4{\sim}5.2$ 3. The decomposition of promazine hydrochloride by the sunlight is composed of pseudo zero order reaction when It maintains colorless solution. 4. The half life of 0.5% promazine hydrochloride injection was 30 hrs. under sun lamp irradiation, but it was delayed to 84 hrs. by the simple stabilizer and to 175 hrs. by compound stabilizer. 5. The stabilizing effect of promazine .hydrochloride injection adding sod. metabisulfite$(Na_2S_2O_5)$ was most excellent in various simple stabilizers and adding $Na_2S_2O_5$ to nicotinic acid, $Na_2S_2O_5$ to nicotinamide were more excellent than other compound stabilizers.

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Cr-free 코팅액에 의한 아연도금강판의 열처리 온도에 따른 내식특성 (Evaluation of the Corrosion Resistance of Zn-Coated Steel as a Function of the Temperature of the Cr-free Solution Used to Coat the Steel)

  • 서현수;문희준;김종순;안석환;문창권;남기우
    • 한국해양공학회지
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    • 제24권5호
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    • pp.60-66
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    • 2010
  • Zinc has a number of characteristics that make it well suited for use as a coating to protecting iron and steel products from corrosion. Its excellent corrosion resistance in most environments accounts for its successful use as a protective coating on a variety of products and in many exposure conditions. The excellent field performance of zinc coatings results from their ability to form dense, adherent films that corrode at a rate that ranges from 1% to 10% of the corrosion rate of ferrous materials, depending on the environment. Recently, EU RoHS and EU ELV prohibited the use of materials that adversely affect the environment, such as Pb, Hg, Cd, and $Cr^{+6}$. In this study, environmentally-friendly, Cr-free solutions (epoxy solution, acrylic solution, and urethane solution S-700) and organic/inorganic solution with Si; LRO-317) were used to evaluate the corrosion resistance of zinc-coated steel subjected to a saltwater spray for 72 hours. The coating of urethane solution (S-700) was best among the three kinds of solution with heat treatment during five minutes at $190^{\circ}F$. Test specimens with S-700 and LRO-317 coating were heat treated in a drying oven at 170, 180, 190, 200, and $210^{\circ}C$ for five minutes. The results show that the optimum corrosion resistance was $190^{\circ}C$ in EGI and $170^{\circ}C$ in HDGI, respectively.

An analytical solution of the annular plate on elastic foundation

  • Pavlou, D.G.;Vlachakis, N.V.;Pavlou, M.G.
    • Structural Engineering and Mechanics
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    • 제20권2호
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    • pp.209-223
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    • 2005
  • A new method for deriving analytical solution of the annular elastic plate on elastic foundation under axisymmetric loading is presented. The formulation is based on application of Hankel integral transforms and Bessel functions' properties in the corresponding boundary-value problem. A representative example is studied and the obtained solution is compared with published numerical results indicating excellent agreement.

수정 유전자 알고리듬을 이용한 중복방문, 다중차고 차량경로문제 (A Vehicle Routing Problem with Double-Trip and Multiple Depots by using Modified Genetic Algorithm)

  • 전건욱;심재영
    • 산업공학
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    • 제17권spc호
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    • pp.28-36
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    • 2004
  • The main purpose of this study is to find out the optimal solution of the vehicle routing problem considering heterogeneous vehicle(s), double-trips, and multi depots. This study suggests a mathematical programming model with new numerical formula which considers the amount of delivery and sub-tour elimination and gives optimal solution by using OPL-STUDIO(ILOG). This study also suggests modified genetic algorithm which considers the improvement of the creation method for initial solution, application of demanding point, individual and last learning method in order to find excellent solution, survival probability of infeasible solution for allowance, and floating mutation rate for escaping from local solution. The suggested modified genetic algorithm is compared with optimal solution of the existing problems. We found the better solution rather than the existing genetic algorithm. The suggested modified genetic algorithm is tested by Eilon and Fisher data(Eilon 22, Eilon 23, Eilon 30, Eilon 33, and Fisher 10), respectively.

천연염료에 관한 연구(8) - 양파 Quercetin 색소에 의한 견섬유의 처리 - (Studies on the Natural Dyes(8) - Treatment of Silk with Ouercetin Color of Onion′s Coats -)

  • 조경래
    • 한국염색가공학회지
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    • 제7권3호
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    • pp.1-10
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    • 1995
  • The optical behavior of coloring matter extracted from onion's coats, the depression effects of destruction, yellowing and W transmittance of silk treated with color solution of onion's coats color difference of silk fabrics dyed with acid dyes and drycleaning fastness of silk treated with color solution has been investigated. The results are as follows : 1) The coloring matter extracted from onion's coats by alkali-acid method appeared properties of aglycon type. 2) &{\lambda}_{max}&of color solution extracted by distilled water was found at 280 and 327nm. 3) The decrease of tensile strength and the elongation of the silk treated with color solution were depressed but those of untreated silk were increased by irradiation of UV light. 4) The yellowness index of silk treated with color solution showed a little change by irradiation. 5) The UV transmittance of silk treated with color solution was decreased as increasing concentration of color solution. 6) The color difference after dyeing with several acid dyes on treated and untreated silk fabrics showed remarkable changes. 7) Drycleaning fastness of silk treated by color solution was excellent.

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화학적 공정을 이용한 Y2Ti2O7 분말과 후막 제조 및 특성 (Fabrication and Characterization of Y2Ti2O7 Powder and Thick Film by Chemical Processing)

  • 이원준;최연빈;배동식
    • 한국재료학회지
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    • 제27권5호
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    • pp.289-293
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    • 2017
  • $Y_2Ti_2O_7$ nanoparticles (0.3 mol%) have been successfully synthesized by the co-precipitation process. The samples, adjusted to pH7 with ammonia solution as catalyst and calcined at $700{\sim}900^{\circ}C$, exhibit very fine particles with close to spherical shape and average size of 10-30 nm. It was possible to control the size of the synthesized $Y_2Ti_2O_7$ particles by manipulating the conditions. The $Y_2Ti_2O_7$ nanoparticles were coated on a glass substrate by a dipping coating process with inorganic binder. The $Y_2Ti_2O_7$ solution coated on the glass substrate had excellent adhesion of 5B; pencil hardness test results indicated an excellent hardness of 6H. The thickness of the thick film was about $30{\mu}m$. Decomposition of MB on the $Y_2Ti_2O_7$ thin film shows that the photocatalytic properties were excellent.

천연염료에 관한 연구 (V) - 동백잎색소처리에 의한 견직물의 광취화 억제효과에 관하여 - (Studies on the Natural Dyes (V) - Depression of Silk Yellowing and Destruction by the Treatment with Color of Camellia Leaf-)

  • 조경래;장정대;박종범
    • 한국염색가공학회지
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    • 제5권2호
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    • pp.91-98
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    • 1993
  • The silk fabrics were treated with color solution extracted from leaf of Camellia. The depression effect of destruction and yellowing of silk treated with color solution, shift of UV-VIS spectra of color solution, color difference of silk fabrics by dyeing with acid dyes and drycleaning fastness of silk treated with color solution were studied. UV-VIS spectra appeared to hypsochromic shift by irradiation. The decrease of tensile strength and the elongation of the silk treated with color solution showed depressed but those of untreated silk increased by irradiation. The yellowness index of silk treated with color solution showed a little change by irradiation. The color difference after dyeing with several acid dyes on treated and untreated silk showed not remarkable changes. Dsrycleaning fastness of silk treated by color solution was excellent.

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복합금속비누와 안정화조제를 이용한 PVC의 열안정화에 대한 연구 (Study of thermal stability on PVC using mixed metal soap and stabilizer)

  • 전인기;안성환;정광보
    • 한국응용과학기술학회지
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    • 제27권4호
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    • pp.552-558
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    • 2010
  • Zinc soap and Zn/Ba mixed metal soap were synthesized and PVC plastisol with mixed metal soap and various costabilizers were also synthesized with good structures and characterized by IR and $^1H$-NMR. The IR spectrums and $^1H$-NMR spectrums of the synthesized soaps were in very good accordance with the structures proposed by earlier workers. In using phosphite as a costabilizer, TIDP phosphite was shown to be the excellent thermal stabilization effect at the low temperature and TNPP phosphite was shown to be the excellent thermal stabilization effect at the high temperature. In case of antioxidant, it was revealed that antioxidant was not effective in the low temperature thermal stabilization effect while highly effective in the high temperature thermal stability. $NaClO_4$ solution with sorbitol solvent had the best thermal stabilization effect among $NaClO_4$ solution series at low and high temperature.

K-GIC의 합성 및 리튬이온이차전지에서의 부극특성 (The Preparation of K-GIC and its Anodic Characteristics of Lithium Ion Secondary Battery)

  • 김현중;이철태
    • 공업화학
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    • 제9권5호
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    • pp.786-790
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    • 1998
  • 리튬이온이차전지에 사용되는 탄소부극의 성능을 향상시키기 위하여 새로운 탄소부극으로서 K-GIC를 합성하여 전기화학적 특성을 조사하였다. K의 삽입량은 KCl 수용액의 농도가 $2>3>1mole/{\ell}$의 순으로 증가하였으며 $1mole/{\ell}$의 KCl 수용액으로 처리하였을 때 K와 C의 mole 비는 156~388 carbon/potassium이었다. K-GIC의 합성조건을 $1mole/{\ell}$ KCl 수용액으로 $700^{\circ}C$에서 1시간으로 처리하였을 때 가장 우수한 리튬의 삽입과 탈삽입 거동을 나타냈으며 가역성 또한 우수하였다.

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