• Title/Summary/Keyword: evolution heat

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Effect of Sodium Gluconate on the Hydration of Tricalcium Aluminate(II) Early Hydration Behavior (3CaO.$Al_2O_3$의 수화반응에 미치는 글루콘산 나트륨의 영향(II) 초기 수화 거동)

  • 김창은;이승헌
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.1-6
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    • 1986
  • The hydration of $C_3A$ and $C_3A-CaSO_4$.$2H_2O$ was investigated with varying concentration (0.1-1.0%) of sodium gluconate solution. gluconate solution. Sodium gluconate accelerates cation dissolution from $C_3A$ for the first several minutes but depresses the rate of heat evolution in the course of $C_3A$ hydration. The hydration of $C_3A$ in the presence of sodium gluconate was modified such that the formation of the intermediate hydrate C4AH$\chi$ crystal was much reduced and most of the product became amorphous. The retardation of $C_3A-CaSO_4$.$2H_2O$ hydration in the presence of sodium gluconate was controlled by the competitive adsorption between gluconate anion and $SO_4^{-2}$ onto $C_3A$ surface.

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An Integrated System to Predict Early-Age Properties and Durability Performance of Concrete Structures

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.465-466
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    • 2010
  • In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

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The effect of steam condensation on the behavior of an hygroscopic aerosol (흡습성 에어로졸의 거동에 미치는 수증기 응축의 영향)

  • Park, J.W.
    • Journal of ILASS-Korea
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    • v.3 no.3
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    • pp.14-22
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    • 1998
  • The growth by steam condensation of an hygroscopic aerosol is investigated using the condensation rate model which has been derived from the mass and heat transfer equations. The present model accounts for both the solute and Kelvin effects. When the hygroscopicity is considered, condensation can occur on hygroscopic seed particles even under subsaturated steam conditions. This study focuses on the effect of hygroscopicity on the evolution of the particle size distribution and decay of the total aerosol concentration. It is found that hygroscopicity causes the particle size distribution to rapidly move upward even in a very short time, resulting in substantially higher decay of the total aerosol concentration than the case without considering hygroscopicity.

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Evolution of "Medicinal Material Usage Targeted at Infantile Convulsion" of the Chosun Dynasty (조선시대(朝鮮時代) 소아경풍(小兒驚風)에 사용된 약재의 변화)

  • Lee, Ga Eun;Ahn, Sang Woo
    • The Journal of Korean Medical History
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    • v.21 no.1
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    • pp.71-76
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    • 2008
  • Infantile convulsion has always been the subject of concern as it is a common yet fatal disease among infants. During the Koryo dynasty and the early years of Chosun dynasty animal and mineral medicinal materials were used to relieve heat. These are replaced with more subtle medicinal materials later on in the Chosun dynasty when differentiation of chronic and acute infantile convulsion first emerged. As such, perception on appropriate medicinal materials is constantly renovated in the course of time.

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The stability analysis of high-temperature superconductor tape (고온 초전도체 테이프의 안정성 해석)

  • Jeong, S.G.;Seol, S.Y.
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.186-191
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    • 2000
  • Stability of a Bi-2223/Ag tape was studied by using a numerical method. A numerical modeling has been developed to analyze the dynamic evolution of normal zone in a composite tape Bi-2223/Ag. In this paper, the stability of HTS tape is studied by considering the non-uniform temperature distribution in a cross-sectional area. The finite-difference method(FDM) is used to solve the two-dimensional heat conduction equation. Two kinds of analyses are compared to quantify the critical disturbance energy fur quenching HTS tapes. One is the length-thickness(x-y) side and the other is the length-width(x-z) side. The results of analyses shows that the critical disturbance energies for each cases seem to be very close for considered Bi-2223/Ag tape.

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Numerical implementation of a constitutive equation of transformation plasticity in welding (용접공정에서 발생하는 변태 소성 구성방정식의 수치적 구현에 관한 연구)

  • Kim, Ju-Wan;Im, Se-Young;Kim, Hyun-Gyu;Choi, Kang-Hyouk
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1154-1158
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    • 2003
  • Finite element analysis of welding processes, which entail phase evolution, heat transfer and deformations, is considered in this paper. Attention focuses on numerical implementation of the thermo-elastic-plastic constitutive equation proposed by Leblond in consideration of the transformation plasticity. Based upon the multiplicative decomposition of deformation gradient, hyperelastic formulation is employed for efficient numerical integration, and the algorithmic consistent moduli for elastic-plastic deformations including transformation plasticity are obtained in the closed form. The convergence behavior of the present implementation is demonstrated via a couple of numerical examples.

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Finite Element Analysis for Pearlite Transformation of Carbon Steel (탄소강의 펄라이트 변태에 대한 유한요소 해석)

  • 탄소강
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.3
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    • pp.69-75
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    • 2000
  • The object of the research is to estimate for pearlite structure of quenched carbon steels. The effects of temperature on physical properties metallic structures and the latent heat by phase transformation were considered. In this study a set of constitutive equations relevant to the analysis of thermo-elasto plastic materials with pearlite phase transformation during quenching process way presented on the basis of continuum thermo-dynamics. The iso-thermal transformation curve of the SM50C was formlated by cubic spline curve. The formulated equations of evolution in pearlite transformation was used for structure analysis. The volume fraction of pearlite was obtained from the results of calculated metallic structure by Finite element equation.

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Fundamental Properties High-Strength Antiwashout Underwater Concrete (고강도 수중불분리성콘크리트의 기초물성에 대한 연구)

  • Moon, Han-Young;Kim, Seong-Soo;Song, Yong-Kyu;Jeon, Joong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.195-198
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    • 2000
  • Recently, the anriwashout underwater concrete has been increasingly used for underwater structures such as vary high diaphrame walls of high strength massive concrete structures. In this study, experiments were made on the fundamental properties of antiwashout underwater concrete replaced with Fly Ash from 10% to 30% to improve its properties. Resultant to the test, we got the results as follows; the value of slump flow wasi ncreased, the setting, time was very delayed, and the heat evolution amount decreased, whereas the amount of suspended solids became high, and pH value became low as to increasing the replacement ratio of Fly Ash. Also the ratios of compressive strength (in water compared to in air) at 28day were obtained over 90%, and these values were satisfied with 70% of a criterion.

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Synthesis and electromagnetic properties of FeNi alloy nanofibers using an electrospinning method

  • Lee, Young-In;Choa, Yong-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.5
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    • pp.218-222
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    • 2012
  • FeNi alloy nanofibers have been prepared by an electrospinning process followed by air-calcination and H2 reduction to develop electromagnetic (EM) wave absorbers in the giga-hertz (GHz) frequency range. The thermal behavior and phase and morphology evolution in the synthetic processes were systematically investigated. Through the heat treatments of calcination and H2 reduction, as-spun PVP/FeNi precursor nanofiber has been stepwise transformed into nickel iron oxide and FeNi phases but the fibrous shape was maintained perfectly. The FeNi alloy nanofiber had the high aspect ratio and the average diameter of approximately 190 nm and primarily composed of FeNi nanocrystals with an average diameter of ~60 nm. The FeNi alloy nanofibers could be used for excellent EM wave absorbing materials in the GHz frequency range because the power loss of the FeNi nanofibers increased up to 20 GHz without a degradation and exhibited the superior EM wave absorption properties compared to commercial FeNi nanoparticles.

Effects of nanomaterials on hydration reaction, microstructure and mechanical characteristics of cementitious nanocomposites: A review

  • Kim, Gwang Mok
    • Journal of Urban Science
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    • v.9 no.1
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    • pp.7-16
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    • 2020
  • Application of nanomaterials to cementitious composites has been attempted with the rapid development of nanotechnology since the 1990s. Various nanomaterials such as carbon nanotube, graphene, nano-SiO2, nano-TiO2, nano-Al2O3, nano-Clay, and nano-Magnetite have been applied to cementitious composites to improve the mechanical properties and the durability, and to impart a variety of functionality. In-depth information on the effect of nanomaterials on the hydration reaction, the microstructure, and the mechanical properties of cementitious nanocomposites is provided in the present study. Specifically, this paper mostly deals with the previous studies on the heat evolution characteristics of cementitious nanomaterials at an early age of curing, and the pore and the compressive strength characteristics of cementitious nanocomposites. Furthermore, the effect of nanomaterials on the cementitious nanocomposites was systematically discussed with the reviews.