• Journal of Bio-Environment Control
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• v.15 no.1
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• pp.78-83
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• 2006

The objective of this study was to examine effect of ethylene removal apparatus on fruit quality of 'Niitaka' pear (Pyrus pyrifolia) in case of a double storage of apples and pears in a storage room. Ethylene and carbon dioxide concentration were efficiently decreased by the ethylene removal apparatus. Fruit weight loss was high at double storage of apples and pears (DAP) in a storage room compared with storage of pears. Fruit core browning was $5{\sim}22.5%$ at the fruits in DAP, but as setting ethylene removal apparatus it was not occurred till 90 days after storage. Soluble solids content and fruit peel hardness were not different among the treatments. Accordingly, a double storage of apples and pears in a storage room is possible as setting ethylene removal apparatus.

• 한국생물공학회:학술대회논문집
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• 2001.11a
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• pp.505-508
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• 2001

An microorganism able to degrade ethylene glycol(EG) was developed. Using this microorganism, biological treatment of ethylene glycol was studied in Erlenmeyer flasks and a laboratory scale stirred loop bioreactor. The removal efficiencies of ethylene glycol from synthetic wastewater were 91.6% ${\sim}$ 97.7% at $30^{\circ}C$ ${\sim}$ $40^{\circ}C$, and 96.3% ${\sim}$ 97.9% at initial pH 9 ${\sim}$ 11 respectively. Also the removal efficiencies of ethylene glycol were found to be more then 92% at initial ethylene glycol concentration of 300mg/L ${\sim}$ I400mg/L. In treatment of weight loss treatment wastewater using Erlenmeyer flasks, the removal efficiencies of ethylene glycol were 79.6%. 82.5%. 77.6%. and 71.3% at initial pH 9. 10. 11. and 12.4 after 11 days of reaction. Moreover in treatment of complex dyeing process wastewater. the residual ethylene glycol was not detected at the initial pH 10.0 and pH 11.3 after 4 days of reaction. When stirred loop bioreactor was used for removing ethylene glycol, the residual ethylene glycol was not detected after 108 hrs and 60 hrs of reaction in batch treatment of weight loss treatment wastewater and complex dyeing process wastewater.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.3
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• pp.325-331
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• 2003

A biofilter study was conducted by changing inlet concentration and residence time for the removal of gaseous benzene and ethylene. In addition, carbon dioxide produced from the biofilters was investigated. Over 96% of benzene was removed at the residence times of 2 and 4.3 min, and inlet benzene concentrations of 220∼300 ppm. The ethylene biofilter was capable of achieving ethylene removal efficiency as much as 100％ at a residence time of 14 min, and inlet concentrations of 99∼290 ppm. At a steady state, the carbon dioxide of 409∼611 ppm was produced with an ethylene inlet concentration of 290 ppm. Most of benzene and ethylene were degraded at lower part of the biofilters where more microbial activity occurred.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.6
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• pp.577-585
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• 2014

A series of experiments using atmospheric-pressure non-thermal plasma coupled with transition metal catalysts were performed to remove ethylene from agricultural storage facilities. The non-thermal plasma was created by dielectric barrier discharge, which was in direct contact with the catalyst pellets. The transition metals such as Ag and $V_2O_5$ were supported on ${\gamma}-Al_2O_3$. The effect of catalyst type, specific input energy (SIE) and oxygen content on the removal of ethylene was examined to understand the behavior of the hybrid plasma-catalytic reactor system. With the other parameters kept constant, the plasma-catalytic activity for the removal of ethylene was in order of $V_2O_5/{\gamma}-Al_2O_3$ > $Ag/{\gamma}-Al_2O_3$ > ${\gamma}-Al_2O_3$ from high to low. Interestingly, the rate of plasma-catalytic ozone generation was in order of $V_2O_5/{\gamma}-Al_2O_3$ > ${\gamma}-Al_2O_3$ > $Ag/{\gamma}-Al_2O_3$, implying that the catalyst activation mechanisms by plasma are different for different catalysts. The results obtained by varying the oxygen content indicated that nitrogen-derived reactive species dominated the removal of ethylene under oxygen-lean condition, while ozone and oxygen atoms were mainly involved in the removal under oxygen-rich condition. When the plasma was coupled with $V_2O_5/{\gamma}-Al_2O_3$, nearly complete removal of ethylene was achieved at oxygen contents higher than 5% by volume (inlet ethylene: 250 ppm; gas flow rate: $1.0Lmin^{-1}$; SIE: ${\sim}355JL^{-1}$).

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.E2
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• pp.79-84
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• 2002

The objective of this study was to investigate the biodegradation of ethylene in an activated carbon biofilter inoculated with immobilized microbial consortium. The biofilter performance was monitored in terms of ethylene removal efficiency and carbon dioxide production. The biofilter was capable of achieving ethylene removal efficiency as much as 100% at a residence time of 14 min and an inlet concentration of 290 ppm. Under the same conditions, carbon dioxide with a concentration of up to 546 ppm was produced. Its was found that carbon dioxide was produced at a rate of 87 mg day$\^$-1/, which corresponded to a volume of 0.05 L day$\^$-1/. During operation with an inlet ethylene of 290 ppm, the maximum elimination capacity of the biofilter was 34 g of C$_2$H$_4$m$\^$-3/ day$\^$-1/. The biofilter could provide an attractive treatment technology for removing ethylene, an extremely volatile and slowly adsorbed compound.

• Journal of Korean Society for Atmospheric Environment
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• v.17 no.3
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• pp.269-276
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• 2001

The objective of this study was to investigate the biodegradation of ethylene in an biofilter inoculated with ethylene-oxidizing microorganisms. The biofilter performance was monitored in terms of ethylene removal efficiency and carbon dioxide production. The biofilter was capable of achieving the ethylene removal efficiency as much as 100% at a residence time of 14 min and an inlet concentration of 290 ppm. Under the same conditions, carbon dioxide with a concentration of up to 546 ppm was produced. It was found that carbon dioxide was produced at a rate of 87 mg/day, which corresponded to a volume of 0.05 L/day. Observable features of the ethylene-oxidizing microorganisms, meaning microbial activity occurrence in the biofilter, were investigated with the microscopy analysis.

• KSBB Journal
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• v.13 no.5
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• pp.518-523
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• 1998

A large quantity of ethylene glycol(EG) is remained in the effluent after pretreating polyester weight-loss wastewater physicochemically in the fist stage and must be treated biologically in the second stage. Therefore, an excellent EG-utilizing bacteria strain was isolated from the natural system and the optimal culture conditions of the strain were investigated. The optimal culture conditions of temperature, pH, and nitrogen source were found to be 35$^{\circ}C$, 7.5 and ammonium chloride, respectively, when CODCr removal efficiency was more than 90%. The growth of stains and EG removal efficiency was slightly improved by adding elements such as niacin and biotin. With increasing inoculation size in a batch culture, the removal efficiency of EG was conspicuously increased. Growth rate was inhibited when the initial concentration of EG was more then 30g/L. The strain was identified as Pseudomonas sp. based on morphological and biological characteristics and named as Pseudomonas sp. EG1.

• Journal of Environmental Health Sciences
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• v.27 no.3
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• pp.43-48
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• 2001

Terephthalic acid and ethylene glycol resulting form the weight-reduction process of polyester make trouble in the operation of activated sludge process. Also, polyester weight loss wastewater shows high pH, high organic strength and wide variation of organic loading. Therefore, this study was conducted in order to improve treatment efficiency by activated sludge process with Pseudomonas sp degrading components of polyester weight loss wastewater. The CO $D_{Mn}$ and BO $S_{5}$ of the waste wastewater were 560~3,000 mg/$\ell$ and 8000~3,000 mg/$\ell$, respectively. pH was 11.8~12.3. COD removal efficiency by activated sludge-coagulation process with Pseudomonas sp was 94.1~95.8% for 35 hr of hydraulic retention time. Total organic carbon removal efficiency was 97.1%. Ethylene glycol and terephthalic acid in the wastewater were completely degraded during 32 hr of hydraulic retention time.e.

• Journal of the Korean Society of Industry Convergence
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• v.6 no.4
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• pp.277-289
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• 2003

This study proposes a mathematical model to characterize the removal of nitrogen oxides in a dielectric barrier discharge plasma process. As well as the reactions between nitrogen oxides, water vapor, oxygen and nitrogen, the model takes into account the effect of ethylene often used as a chemical additive to reduce the power consumption of the process on the removal of nitrogen oxides. Since the concentrations of the radicals concerned in the main reactions including O, OH, H and N should be calculated to predict the removal efficiency of nitrogen oxides, they were theoretically derived. The parameters affecting the removal of nitrogen oxides, such as initial concentration, discharge power, humidity, and ethylene concentration were experimentally evaluated, which were compared with the calculated results to verify the validity of the model proposed. The predicted concentrations of several byproducts formed in this process were also presented and discussed. The effects of several parameters mentioned above on the removal of nitrogen oxides were reasonable described by the proposed model.

• Textile Coloration and Finishing
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• v.13 no.4
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• pp.264-271
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• 2001

Catalytic wet oxidation of ethylene glycol as refractory compound was studied in a batch slurry reactor using lwt% $Pt/A1_2O_3$, lwt% $Pt/TiO_2,\;Mn/CeO_2$(1:1) and 5wt% $Mn/Al_2O_3$. Experiments were conducted to investigate theeffects of temperature, initial ethylene glycol concentration, catalyst dosage and PH on the ethylene glycol decomposition. When compared with the uncatalyzed reaction, the use of catalysts could increase the rate of ethylene glycol decomposition. The lwt% $Pt/A1_2O_3$ catalyst was preferable to the other catalysts for the destructive oxidation of ethylene glycol. The reaction rate was first order with respect to initial concentration of ethylene glycol. In acidic condition the removal efficiency of ethylene glycol was good, but there was a significant leaching of platinum. Small amount of acetic acid, oxalic acid, masonic acid and formic acid as intermediates were detected during catalytic wet air oxidation of ethylene glycol.