• Elastomers and Composites
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• 제58권3호
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• pp.142-151
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• 2023

In this study, we investigate the thermal and mechanical properties of composites comprising ethylene propylene diene monomer (EPDM) and polybutadiene (PB) obtained using carbon black (CB) as a reinforcing and compatibilizing filler. Owing to the significance of elastomeric materials in various industrial applications, blending of EPDM and PB has emerged as a strategic method to optimize the material properties for specific applications. This study offers insights into the blend composition, its microstructure, and the resulting macroscopic behaviors, focusing on the synergetic effects of composite materials. Furthermore, this study delves into curing and rheological behaviors, crosslink densities, and mechanical, thermal, and elastic properties of the elastomeric composites. Through systematic exploration, we believe that this study will be beneficial to material scientists and engineers working on developing advanced elastomeric composites.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.449-452
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• 2009

EPDM(Ethylene-propylene diene monomer)계 고무의 난연성 향상을 위하여 무기계 난연재료인 $Al(OH)_3$와 $Sb_2O_3$를 첨가하여 물성 및 열적 특성을 조사하였다. 각 시편의 물성은 큰 차이를 보이지 않았으나, 난연재료의 함량이 증가할 수 록 비중과 경도는 높아지는 반면에 신율은 낮아지는 경향이 있었다. 본 연구에서는 열분석과 난연성 시험을 실시하였고, 결과적으로 난연재료의 함량이 10phr 이상에서는 난연 효과가 확연히 나타나는 것으로 판단되었다.

• 폴리머
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• 제25권2호
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• pp.233-239
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• 2001

Mechanical mixing법으로 ethylene propylene diene terpolymer (EPDM)과 ethylene propylene diene terpolymer (EPDM)과 acrylonitrile butadiene rubber (NBR) 블렌드 혼련물을 제조하여, 이들의 무늬 점도, 가교 거동, 영구 압축 줄음율 및 동적 기계적 성질 등을 검토하였다. Rheovibron에 의한 동적 특성 측정의 결과로부터 EPDM/NBR 블렌드는 -43$^{\circ}C$ 및 -4$^{\circ}C$ 부근에서 두 개의 전이를 보였으며 이를 각각 NBR 고무 및 EPDM 고무의 T$_{g}$로 해석하였다. tan${\delta}$ 피크의 위치는 NBR 고무의 함량이 증가함에 따라 고온 쪽으로 이동함을 확인할 수 있었다. 또한 NBR 고무량이 증가할수록 최적 가황시간이 단축되는 경향을 보였다.

• 한국재료학회지
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• 제9권4호
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• pp.409-413
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• 1999

Recently, the polymeric insulators have been accepted in several countries for the outdoor high voltage applications. In comparison with the conventional porcelain, polymeric insulators offer various advantages such as light weight, superior vandal resistance and better contamination performance. The outdoor polymeric insulating materials such as silicone rubber, ethylene propylene diene monomer(EPDM), ethylene vinyl acetate(EVA) and epoxy are aged such as silicone rubber, ethylene propylene diene monomer(EPDM), ethylene vinyl acetate(EVA) and epoxy are aged under the various natural environment with the long-term performance in outdoor. In this paper, the effects of UV-under the various natural environment with the long-term performance in outdoor. In this paper, the effects of UV-ray on the surface of silicone rubber were investigated by using the weather-Ometer. The accelerated aging stresses were simulated by UV radiation, high temperature and humidity as well as water spray. These aging characteristics were examined through contact angle measurements, tracking resistance test, FT-IR and SEM/EDS analysis. The experimental results showed that tracking resistance decreases with increase in the UV-ray irradiation period. But the surface of silicone rubber kept hydrophobicity. It is found that the inorganic filler such as)$ Al(OH_3$ improves tracking resistance and the $Tio_2$is very effective in preventing degradation of silicone rubber surface from UV-ray.

• Elastomers and Composites
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• 제51권2호
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• pp.93-98
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• 2016

The composites of EVA/EPDM including aluminum trioxide (ATH) as a fire retardant were manufactured for the purpose of improving low temperature property and flame resistance in the rubbery materials. The ratio of EVA to EPDM didn't affect the flame resistance of the rubber composites. The addition of ATH resulted in increase of the flame resistance. In the evaluation of the cold resistance, the increasing EPDM content showed enhancement of cold resistance in the composites due to increasing low Tg EPDM. It was found out that tensile strengths of the composites showed a maximum value at 100 phr of ATH by reinforcing effect, but a minimum value at 200 phr of ATH owing to slippage between the flame retardant by the external stress. In the measurement of solvent resistance in tetrahydrofuran, the increasing ATH content yielded enhancement of solvent resistance by reducing swelling of the composite, and increasing EPDM content also resulted from increase of the solvent resistance by reduction of polarizability as well as increase of crosslink in the composites.

• 한국안전학회지
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• 제18권3호
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• pp.69-74
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• 2003

To investigate the partial discharge and electric field distribution in cable joint parts, we measured the partial discharge and electric field in specimen. The specimens which cross-linked polyethylene(XLPE) and ethylene propylene diene ethylene(EPDM) are used to insulating material for underground cable md cable jointing parts. The polymers are used to insulating material in switchgear which is a kind of transformer equipment and in ultra-high voltage cable. Its using is increasing gradually, the electrical insulation properties are not only excellent but also mechanical property is excellent. And because it is possible to be made void of several type in insulator while it is produced, which the electrical field distribution is changed by void, it has a critical influence to insulator performance. The underground cable is connecting by the jointing material, insulating breakdown and the electric ageing which are caused by several mixing impurity and the damage of cable insulator layer, which reduced the life of cable while intermediate joint kit is connected. Therefore, the computer simulation is used to estimating insulator performance, XLPE is used to the insulating material of ultra-high voltage cable and EPDM is used to insulator layer in joint material kit, and which are produced as specimen. And it is analyzed the electric field concentrating distribution and partial discharge by modeling of computer simulation in void and cable joint kit.

• Elastomers and Composites
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• 제29권2호
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• pp.121-130
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• 1994

The physical properties of rubber blend between natural rubber(NR) and ethylene propylene diene terpolymer(EPDM) were investigated as a study of EPDM composite materials. For EPDM/NR blends, the effects of ethylene and diene contents in EPDM, blend ratio, dicumyl peroxide(DCP) curing system on the physical properties, interfacial adhesion force and dynamic crack growth etc. were studied. EPDM/NR blends loaded with carbon black were prepared by mechanical mixing and cured by plate heating cure press. Crosslinking density was measured by swelling method with toluene. The physical properties of all blends were measured with Instron, fatigue to failure(FTF), Demattia flex cracking tester(DMFC), scanning electron microscopy (SEM), etc. As the ethylene and diene contents in EPDM increased, the physical properties, such as dynamic crack growth, adhesion to other component were increased too. Interfacial adhesion force of EPDM/NR blends to dissimilar layer was improved by the use of optimum peroxide curing system.

• 한국응용과학기술학회지
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• 제28권4호
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• pp.410-417
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• 2011

Effects of ethylene-propylene diene monomer (EPDM)/polypropylene (PP), zinc oxide, stearic acid, and clay on the combustive properties based on EDPM/PP were investigated. The EDPM/PP/clay nanocomposites was compounded to prepare specimen for combustive analysis by cone calorimeter (ISO 5660-1). It was found that the specific mass loss rate (SMLR) in the nanocomposites decreased due to the fire resistance compared with unfilled EDPM/PP, while the nanocomposites showed the higher total heat release (THR), higher CO production release, and higher specific extinction area (SEA) than those of virgin EPDM/PP. The stearic acid for softening ruber increased the THR and amount of smoke by itself, combustible.

• 폴리머
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• 제25권3호
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• pp.406-413
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• 2001

고분자의 블렌드는 새로운 성질을 가지는 재료의 제조를 위한 하나의 방법으로 제시되고 있다. 그러나 대부분의 재료는 재료사이의 점탄성, 표면에너지 그리고 상호결합력의 차이로 인하여 비상용성을 지니며, 이로 인하여 블렌드물은 예상되는 물성을 나타내지 못하는 경우가 있다. 실리콘 고무는 우수한 내열성과 전기적 성질을 가지며, ethylene propylene diene monomer (EPDM) 고무는 우수한 기계적 물성을 지니고 있다. 본 실험에서는 실리콘과 EPDM 고무의 블렌드를 통한 전기적 성질과 기계적 물성이 우수한 새로운 기능성 재료의 개발에 목적을 두었다.

• International Journal of Precision Engineering and Manufacturing
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• 제7권4호
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• pp.23-27
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• 2006

Rubber is used in many industrial products, such as hoses, rubber belts, and oil seals. In particular, more than 200 rubber parts are used in automobiles. The design technology of these parts is largely dependent on field experience, which leads to lengthy and expensive developing procedures. However, with the help of recent developments in nonlinear computer analysis, new rubber products can be developed at low cost. In this study, rubber injection molding design variables, such as location and number of gates, were optimized using computer-aided engineering with the cross-WLF equation to produce CLIP rubber products made from ethylene propylene diene monomer(EPDM). The validity of the proposed design was evaluated by comparison with actual forming results.