• Title/Summary/Keyword: ethanol solution

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Photochemical Reaction of Aqueous Ethanol in the Presence of CO (일산화탄소가 포함된 에탄올 수용액의 광화학 반응)

  • Kim, Hui Jeong;Lee, Hyeong Cheol;Park, Hyeong Ryeon
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.271-275
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    • 1994
  • The photochemical reaction of aqueous ethanol saturated with argon and carbon monoxide has been investigated using 184.9 nm UV light. The photochemical reaction of $1{\times}10^{-2}$ M aqueous ethanol saturated with argon results in the formation on the acetaldehyde and 2,3-butanediol. The irradiation of the solution saturated with carbon monoxide causes the formation of carbonylation and carboxylation products such as ${\alpha}$-hydroxypropionaldehyde, formaldehyde, glyoxal, formic acid, oxalic acid and glyoxylic acid in addition to above two products. But in the case of concentrated ethanol solutions, the irradiation did not give carbonylation and carboxylation products. The initial quantum yields of the products were determined and probable mechanisms for the reaction were presented on the basis of product analysis.

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Antioxidative Effects of Green Tea Powder Diet Against Ethanol-Induced Oxidative Damage in Rat Brain Regions (뇌 조직에서 알코올 투여에 대한 녹차 건분의 항산화 효과)

  • 장남수;류선미
    • Journal of Nutrition and Health
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    • v.34 no.5
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    • pp.525-531
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    • 2001
  • The present study investigated the protective effects of green tea against acute ethanol-induced lipid peroxidation and the change of antioxidative enzyme activities in various regions of rat brain : cortex, cerebellum, striatum and hippocampus. The following parameters were examined : malondialdehyde(MDA) levels and activities of superoxide dismutase(SOD), catalase and glutathione peroxidase(GSH-Px). Male Sprague-Dawley rats were given the experimental containing 1% green tea powder or control diet for 4 weeks, and at the end of feeding diet group received acute ethanol(5g/kg body weight) or equicaloric sucrose solution intragastrically. Green tea powder significantly decreased MDA levels in the striatum compared to control-non alcohol treated group to 1% green tea-non alcohol treated group without altering the antioxidative enzyme activities. Green tea resulted in a significant increase in GSH-Px activities in the hippocampus compared to either control-non alcohol treated group(0.043units/mg protein) or 1% green tea-non alcohol treated group(0.071units/mg protein). In conclusion, these results suggest that moderate consumption of green tea leaves can exert protective effects against ethanol-induced oxidative stress in brain regions, by reducing MDA concentrations in the striatum and enhancing GSH-Px activities in the hippocampus. (Korean J Nutrition 34(5) : 525∼531, 2001)

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Release of Nifedipine from Poly(ethylene oxide) Tablets (폴리에칠렌 옥사이드 정제로부터 니페디핀의 방출양상)

  • Hong, Sung-In;Hur, Young-Lim;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
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    • v.30 no.3
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    • pp.207-211
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    • 2000
  • The objective of this work is to investigate the effect of molecular weight of poly(ethylene oxide) (PEO) and release medium on the release of nifedipine (NP) from PEO tablets containing NP and to get some mechanistic insights into the release of NP. The tablets containing NP were prepared by direct compression, using a flat-faced punch and die. The molecular weights of PEOs used were 200K, 900K, 2000K and 7,000K. The release kinetics were studied for 24 hours in aqueous ethanol solution, using a dissolution tester at $36.5^{\circ}C$ and 100 rpm. Drug release rate increased, as the concentration of ethanol in the dissolution medium increased, due to the increased solubility of NP. As the molecular weight of PEO increased, release rate decreased, due to the slower swelling and dissolution of PEO. The power values obtained by fitting data to the power law expression $(M_t/M_{\infty}=kt^n)$ indicated that, at low ethanol concentration, the release of NP is governed by anomalous diffusion. However, as the ethanol concentration increases, diffusional release becomes to prevail over anomalous or zero-order release. Overall, these results provided some insights into the release of NP from PEO tablet.

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The Study on Cooling Characterics of TMA Clathrate with Ethanol (에탄올을 첨가한 TMA 포접화합물의 냉각특성에 대한 연구)

  • 김창오;김진흥;정낙규;김석현
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.14 no.8
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    • pp.634-640
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    • 2002
  • The purpose of this study is to investigate the propriety of TMA clathrate as a cold storage medium. Particularly, this is to examine the extent of subcooling improvement when the additives is added to the TMA clathrate, because water used for cold storage ma terial has low phase change temperature and subcooling. This study has been analyzed and compared pure water with TMA 30 wt% clathrate how phase change temperature, subcooling and specific heat in the various concentrations are changed. This results prove low phase change temperature and subcooling control effect when the ethanol is added to the TMA 30 wt% clathrate than the TMA 30 wt% clathrate. In addition, it results low specific heat when there is added to the TMA 30 wt% clathrate over 0.5 wt% ethanol in the cold heat source temperature under $-7^{\circ}C$. The other side, it results high specific heat when the ethanol is added in it at the cold heat source temperature under $-5^{\circ}C$. Therefore, it is found that the additive must be controlled by available solution limit and study for new additive must be lasted to know its effect.

Some Physical Properties of Koran Red Ginseng Extract as Affected by Extracting Conditions (추출조건에 따른 홍삼(紅蔘)엑기스의 물리적 성질의 변화)

  • Sung, Hyun-Soon;Kim, Na-Mi;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.18 no.3
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    • pp.241-244
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    • 1986
  • Some physical properties of Korean red ginseng extract was investigated for their changes during extraction with ethanol solution having a concentration range of 0-90% at $70-100^{\circ}C$ during 5 times of 8 hours extraction. The intrinsic viscosity was ignificantly decreased as the ethanol concentration and measuring temperature increased, while it was affected relatively less by the extraction temperature. However the effect of measuring temperature on the intrinsic viscosity was greatly reduced for the extract obtained with higher than 50% a ethanol. The turbidity and pH were also decreased as the ethanol concentration and extraction time increased.

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Photofading of Wool Colored by Tryptophan Color Reactions

  • Shosenji, Hideto;Anpo, Masafumi;Kuwahara, Yutaka;Sawada, Tsuyoshi;Donowaki, Kiyoshi
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.11a
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    • pp.103-104
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    • 2009
  • Treatment of wool fabric with aromatic aldehydes followed by oxidation with hydrogen peroxide gave rise to coloring reaction. The colored fabric was bleached by reduction and recovered the color by oxidation. The oxidation in ethanol solution gave higher k/s values than that in aqueous solution. Photo-stability of the colored fabric was improved by treating with nickel sulfate.

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Characteristics of Volatile Compound Adsorption from Alcoholic Model Solution onto Various Activated Carbons (알코올모델용액을 이용한 여러 종류 활성탄의 휘발성화합물 흡착특성)

  • Park, Seung-Kook;Lee, Myung-Soo;Kim, Byung-Ho;Kim, Dae-Ok
    • Food Engineering Progress
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    • v.14 no.3
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    • pp.249-255
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    • 2010
  • Ten commercial activated carbons (ACs) prepared from four different sources (bamboo, wood, peat, and coal) were evaluated for their adsorptive efficiency of six volatile compounds (isoamyl alcohol, hexanal, furfural, ethyl lactate, ethyl octanoate, 2-phenyl ethanol) which were dissolved in a 30% alcoholic model solution. These six volatile compounds are frequently found in alcoholic beverages and possibly contribute to physiological hangover due to their high concentrations. They are also generally regarded as off-flavor compounds at certain levels in alcoholic beverages such as whisky and vodka. Two hundred mL of 30% alcoholic solutions containing these six volatile compounds were treated with 0.2 g of ACs while stirring for 16 hr; the treated solutions were then measured for their adsorptive efficiencies (or removal efficiencies) by gas chromatographic analysis using two different sampling methods (direct liquid injection and headspace-solid phase microextraction). The adsorptive efficiencies of the ACs varied depending on the identity of the volatile compounds and the source material used for making the ACs. Ethyl octanoate, 2-phenyl ethanol, and hexanal were removed at high efficiencies (34-100%), whereas isoamyl alcohol, ethyl lactate, and furfural were removed at low efficiencies (5-13%). AC prepared from bamboo showed a high removal efficiency for isoamyl alcohol, aldehydes (hexanal and furfural), and 2-phenyl ethanol; these major fusel oils have been implicated as congeners responsible for alcohol hangover.

Transarterial embolization of renal artery in dogs with experimental hydronephrosis (개의 실험적 수신증에 실시한 신동맥 색전술)

  • Chang, Dongwoo
    • Korean Journal of Veterinary Research
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    • v.41 no.3
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    • pp.437-445
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    • 2001
  • This study was performed to validate the procedure of transarterial embolization of the renal artery (TAE-RA) using iohexol-ethanol solution in dogs with unilateral experimental hydronephrosis and to evaluate the embolized kidney using B-mode ultrasonography and selective angiography. Experimental hydronephrosis was induced by ligation of unilateral ureter in 12 dogs. Ultrasonographic findings revealed that size of the kidney was significantly increased at 9 days and 17 days and the length of renal cortex was significantly decreased at 17 days after ligation of the unilateral ureter and it was in accordance with dilation of ipsilateral renal pelvis. No significant change of BUN, creatinine, ALT, calcium, and phosphorus was found immediately after unilateral experimental hydronephrosis. Therefore, it was concluded that unilateral hydronephrosis was established in 12 dogs at 17 days after ligation of ureter. Renal artery embolization was performed using selective catheterization in the hydronephrotic kidney of seven dogs and EKG, $SpO_2$, body temperature, pulse, and respiratory rate were within normal ranges during procedures. Iohexol-ethanol solution was used as embolic material. Average ethanol dose for renal artery embolization was $1.94{\pm}1.24ml/kg$. There were no dogs expired after TAE-RA and no side effects associated with regurgitation of iohexol-ethanol solution. Revascularization of renal artery was not found in angiography in dogs treated by TAE-RA at immediately after TAE-RA and 14 days after TAE-RA. Ultrasonographically, the mean longitudinal length of the embolized kidney decreased significantly at 2 and 3 months after TAE-RA compared to that of contralateral normal kidney. In summary, marked shrinkage of the embolized kidney was observed in dogs with unilateral experimental hydronephrosis treated by TAE-RA with iohexol-ethanol and no adverse effects were observed throughout the observation period. It is concluded that TAE-RA with iohexol-ethanol solution is a viable alternative to nephrectomy in dogs with unilateral hydronephrosis.

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Cell Immobilization of Zyrnornonas rnobilis by Entrapment (포괄담체에 의한 Zymomonas mobilis 균체의 고정화)

  • 한면수;정동효
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.459-469
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    • 1992
  • The immobilization characteristics of Zymomonas mobilis for ethanol production were examined. Four different strains of Zymomonas mobilis have been used for ethanol production. Among those, Zymomonas mobilis KCTC 1534 has been selected as the best strain for the highest ethanol productivity from glucose and sucrose. The optimum temperature and pH of the selected strain for ethanol production were $37^{\circ}C$ and 5.0 respectively for both free and immobilized cells. When the cells were immobilized by the gel entrapment method, the immobilized cells could produce ethanol at a little higher temperature than free cells. Calcium alginate was selected as the best gel for immobilizing cells. The immobilized cells could maintain the viability of 80% in 10 weeks storage at $4^{\circ}C$ in the medium with 2% calcium chloride. 20-25 hours of preincubation in 10% glucose solution was required for the activation of immobilized cells entrapped within calcium alginate gel.

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Improvement of Anthocyanin Encapsulation Efficiency into Yeast Cell by Plasmolysis, Ethanol, and Anthocyanin Concentration Using Response Surface Methodology

  • Dong, Lieu My;Hang, Hoang Thi Thuy;Tran, Nguyen Huyen Nguyet;Thuy, Dang Thi Kim
    • Microbiology and Biotechnology Letters
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    • v.48 no.3
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    • pp.267-275
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    • 2020
  • Anthocyanins are antioxidant compounds susceptible to environmental factors. Anthocyanin encapsulation into yeast cells is a viable solution to overcome this problem. In this study, the optimal factors for anthocyanin encapsulation were investigated, including anthocyanin concentration, plasmolysis contraction agent, and ethanol concentration, and response surface methodology was evaluated, for the first time. Anthocyanin from Hibiscus sabdariffa L. flowers was encapsulated into Saccharomyces cerevisiae using plasmolysis contraction agent (B: 3%-20% w/v), ethanol concentration (C: 3%-20% v/v), and anthocyanin concentration (A: 0.15-0.45 g/ml). The encapsulation yield and anthocyanin loss rate were determined using a spectrometer (520 nm), and color stability evaluation of the capsules was performed at 80℃ for 30 min. The results of the study showed that these factors have a significant impact on the encapsulation of anthocyanin, in which ethanol agents have the highest encapsulation yield compared to other factors in the study. Statistical analysis shows that the independent variables (A, B, C), their squares (A2, B2, C2), and the interaction between B and C have a significant effect on the encapsulation yield. The optimized factors were anthocyanin, 0.25 g/ml; NaCl, 9.5% (w/v); and ethanol, 11% (v/v) with an encapsulation yield of 36.56% ± 0.55% and anthocyanin loss rate of 15.15% ± 0.98%; This is consistent with the expected encapsulation yield of 35.46% and loss rate of 13.2%.