• Title/Summary/Keyword: essential metals

Search Result 173, Processing Time 0.024 seconds

The Heavy Metals Recovery from Carbonized CCA Treated Wood (CCA방부목재의 탄화가 중금속 회수에 미치는 영향)

  • Son, Dong-won;Cheon, Seon-Hae;Lee, Myung Jae;Lee, Dong-heub
    • Journal of the Korean Wood Science and Technology
    • /
    • v.33 no.6 s.134
    • /
    • pp.95-100
    • /
    • 2005
  • The using amount of preservative-treated wood equipments has been increased. Specially, chromate copper arsenate (CCA) has been widely used to exterior wood. We are faced to the disposal problem after service period of CCA treated wood due to its toxic heavy metals. For the disposal of end-used treated wood, land-filling and incinerating methods are mainly applied. The essential problem of incinerating is an arsenic release into atmosphere. Low pyrolysis is suggested as the methods of protecting arsenic release during incineration. The heavy metals were recovered after combustion of the treated wood at the low temperature which arsenic can not released. The recovery amounts of effectiveness compounds was determined in various solvents (citric acid, nitric acid, sulfuric acid, acetic acid, phosphoric acid) and different temperature (300, 400, $500^{\circ}C$). The higher temperature was applied, the more copper was recovered. The chromium was difficult to be recovered on the carbonized CCA treated wood at 0.5% acid concentration. The recovery mass of arsenic decreased on the higher combustion treated wood. The recovery of chromium was difficult due to the chemical change of the chromium arsenate during pyrolysis.

Trends of Thermochemical Technology for the Recovery of Phosphorus from Sewage Sludge Ash (열화학적 방법에 의한 하수 슬러지 소각재에서의 인 회수 기술 동향)

  • Jeon, Seulki;Shin, Hyuna;Kim, Dong-Jin
    • Clean Technology
    • /
    • v.24 no.2
    • /
    • pp.87-98
    • /
    • 2018
  • Phosphorus (P) is an essential and irreplaceable element for all living organisms, and it is widely used as a fertilizer. Unfortunately, it is estimated that phosphate reservoir is depleted within about 100 years. Sewage sludge ash (SSA) is an alternative resource for P recovery because of its high P content. However, SSA cannot be directly used as a fertilizer due to heavy metals in it and low P bioavailability. Thermochemical treatment with Cl donor is known to reduce heavy metal contents and increase P bioavailability of SSA. Literature review on thermochemical technologies of SSA for the reduction of heavy metals and bioavailability enhancement has been carried out to estimate the status of current P recovery technology and to develop strategic future research plan for P recovery. The review showed that $CaCl_2$ and $MgCl_2$ were the most effective Cl donors and reaction temperature (< $1000^{\circ}C$) was the critical operation condition for the reduction. The removal efficiency depends on the species of heavy metals. Thermochemical technology of SSA for P recovery showed the possibility of commercial application in the near future to overcome the coming crisis of human sustainability by P depletion, but it needs cost effectiveness and more ecofriendly process to reduce energy consumption.

Study on the Changes of the Mineral Contents in Tap-water Drinking with Diverse Teas (차를 이용한 수돗물 간접 음용시 수돗물 중 미네랄 함량 변화 연구)

  • Kim, Jeonghee;Ryoo, Rina;Song, Daesung;Lee, Jeongyeop;Lee, Young-Joo
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.37 no.9
    • /
    • pp.511-516
    • /
    • 2015
  • On this study, we investigated the removal characteristics of residual chlorine and DBPs in tap-water during boiling. Also we investigated the releasing characteristics of essential minerals in infusion tea. While recent studies focused on removal mechanisms of harmful heavy metals in infusion tea, this study tried to suggest the way to drink tap-water healthier and safer by examining releasing mechanisms of essential minerals in infusion tea. As a result, residual chlorine(initial conc. was 0.7 mg/L) was all removed in 20 minutes after heating and DBPs (the sum of THMs, HAAs and CH) were removed up to 65%. 6 kinds of essential minerals (Ca, K, Na, Mg, S, P) were released from 5 kinds of infusion tea (barley tea, corn tea, brown rice tea, cassia seed tea, solomon's seal tea) on the market. In cassia seed tea, the amount of essential minerals released from tea showed the highest values, 9.6 mg/g, and brown rice tea was the lowest, 1.6 mg/g. Particularly, the released amounts of potassium, playing a key role in human body in maintaining normal blood pressure, cell metabolism and enzyme action, showed relatively high. Through this study, we got to know that essential minerals can be obtained up to 40% of recommended nutritional intake for Korean by boiling tap-water with infusion tea.

Risk Assessment of Explosion of Mixed Dust Generated in Semiconductor Manufacturing (반도체 공정에서 발생하는 혼합분진의 폭발 위험성평가)

  • Park, Chang-Sup;Kim, Chan-O
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.67 no.3
    • /
    • pp.474-478
    • /
    • 2018
  • The use of metals such as aluminum and titanium and the related industrial facilities have been continuously increasing to meet the requirements of the improvement of high-tech products due to the development of industry, and explosion of metal dust. Semiconductor process Metal dust is essential, but research is insufficient. The purpose of this study is to identify risk by analyzing the quantitative risk such as maximum explosion pressure and minimum explosion concentration applied international test standard in order to select the semiconductor process facilities handling dust and to predict possible risk of accidents.

Development of Drawbead Expert Models for Finite Element Analysis of Sheet Metal Forming Processes (Part1:Experiment) (박판성형공정의 유한요소해석을 위한 드로우비드 전문모델 개발(1부: 실험))

  • Lee, Jae-U;Keum, Yeong-Tak
    • Transactions of Materials Processing
    • /
    • v.7 no.1
    • /
    • pp.3-11
    • /
    • 1998
  • During the forming process of sheet metals, the drawbead in the die face controls a restraining force so that the sheet flows into the die cavity with tension. In order to investigate a drawgbead restraining force and a pre-strain just after drawbeads which are essential in the finite element analysis of form-ing processes, the friction test and drawing test are employed. The experiments performed with a cir-cular bead stepped bead double circular bead and circular-and-stepped bead in the various forming conditions and bead sizes show that the restraining force varies linearly with the blank holding force. bead radius blank thickness and friction but the pre-strain nonlinearly does with them.

  • PDF

Determination of EDM Parameters based on Electrode Wear (전극 소모비에 기초한 방전 조건 생성)

  • 주상윤;이건범;왕지남
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 1995.10a
    • /
    • pp.1154-1158
    • /
    • 1995
  • Electrical Discharge Machining, with its ability to machine hard metals and tough shapes has become a very desirable process. In the past few years, Electrical Discharge Machining (EDM) has been solidly established in tool-room and large-scale production. However, in spite of its indispensability in many areas of metal removal applications, the theoretical basis of EDM process is yet to be established. More importantly, the information regarding essential technology parameters such as machining rate and resulting surface roughness integrity, has not been raised to the level of a general technical science. The paper presents a method, which can be determining approprate machining parameters for the given parameters such as electrode wear and surface roughness based on machining guideline utilizing neural networks.

  • PDF

A Study on the Formation Mechanism of Microconstituents in Brazed Joint of Duplex Stainless Steel and Cr-Cu Alloy (2상 스테인리스강과 크롬동합금의 브레이징부 생성상의 생성기구에 관한 연구)

  • 김대업
    • Journal of Welding and Joining
    • /
    • v.19 no.5
    • /
    • pp.534-539
    • /
    • 2001
  • The formation mechanism of microconstituents in brazed joints of duplex stainless steel and Cr-Cu alloy which is an essential process of rocket engine manufacturing was investigated using Cu base insert metal. $SUS329J_3L$ and C18200 were used for base metal and AMS 4764 was used for insert metal. The brazing was carried out under various conditions. There were various phases in the joints, because of reaction between liquid insert metal and base metals. Since liquid insert metal reacts with duplex stainless steel, liquid Cu from insert metal infiltrated into the $\alpha/\beta$ interface of duplex stainless steel. Through the process of Cu infiltration, isolated stainless steel pieces come into the liquid insert metal. Since liquid insert metal reacts with Cr-Cu alloy. Cr precipitates from C18200 come into the liquid insert metal. With increment of bonding temperature and holding time, amounts and sizes of phases increased. but Cr-Mn compounds decreased at 1303k for 1.2ks and Mn-rich phases disappeared Fe-Cr compounds formed.

  • PDF

Determination of Trace Metals in Formula Feed by Atomic Absorption Spectrophotometry (원자흡광 분광광도계에 의한 사료중 중김속의 정량)

  • Park, Sung Woo;Lee, Wan Koo
    • Journal of Environmental Health Sciences
    • /
    • v.11 no.2
    • /
    • pp.55-63
    • /
    • 1985
  • The quantities of chrome, lead, iron, copper and manganese in the formula feed were determined by A.A.S. and the results were summarized as follows 1. The content of chromium in the leather and meat meals(SN-2) were 13-66 times as much as the level of permission. 2. In the meantime, lead content in the meat meal (SN-1) was about 20 times as much as permitted level. 3. The iron which is essential constituent of the formula feed was contained in the meat and leather meals and these values were 2-10 times as much as feeding regulations, on the contrary copper and manganese content in the shaving and flesh were below the feeding regulations.

  • PDF

Manganese and Iron Interaction: a Mechanism of Manganese-Induced Parkinsonism

  • Zheng, Wei
    • Environmental Mutagens and Carcinogens
    • /
    • v.23 no.4
    • /
    • pp.115-130
    • /
    • 2003
  • Idiopathic Parkinson's disease (IPD) represents a common neurodegenerative disorder. While epidemiological studies have suggested a number of risk factors including age, gender, race, and inherited disorder, the cumulative evidence supports the view that environmental or occupational exposure to certain chemicals may contribute to the initiation and progress of Parkinsonism. More recently, clinical and laboratory investigations have led to the theory that dysregulation of iron, an essential metal to body function, may underlie IPD by initiating free radical reaction, diminishing the mitochondrial energy production, and provoking the oxidative cytotoxicity. The participation of iron in neuronal cell death is especially intriguing in that iron acquisition and regulation in brain are highly conservative and thus vulnerable to interference from other metals that bear the similar chemical reactivity. Manganese neurotoxicity, induced possibly by altering iron homeostasis, is such an example. In fact, the current interest in manganese neurotoxicology stems from two primary concerns: its clinical symptoms that resemble Parkinson's disease and its increased use as an antiknock agent to replace lead in gasoline. This article will commence with addressing the current understanding of iron-associated neurodegenerative damage. The major focus will then be devoted to the mechanism whereby manganese alters iron homeostasis in brain.

  • PDF

Adaptive Identification Method of EDM Parameters Using Neural Network (신경망을 이용한 방전 조건의 적응적 결정 방법)

  • 이건범;주상윤;왕지남
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.15 no.5
    • /
    • pp.43-49
    • /
    • 1998
  • Adaptive neural network approach is presented for determining Electrical Discharge Machining (EDM) parameters. Electrical Discharge Machining has been widely used with its capability of machining hard metals and tough shapes. In the past few years, EDM has been established in tool-room and large-scale production. However. in spite of it's wide application, an universal selection method of EDM parameters has not been established yet. No attempt has been tried before to suggest a logical method in determining essential machine parameters considering the machining rate and resulting surface roughness integrity. The paper presents a method, which is focusing on determining appropriate machining parameters. Depending on the electrode wear and surface roughness, an adaptive neural network is designed for providing suitable machining guideline.

  • PDF