• Title/Summary/Keyword: equivalent concentration

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다변량 통계 분석 및 질량 균형법을 이용한 제주도 지하수의 수질 요소 분리

  • 고동찬;고경석;김용제;이승구
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.450-452
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    • 2004
  • Using factor analysis and bivariate comparisons of major components in ground water, three geochemical processes were identified as controlling factors of ground water chemistry; 1) natural mineralization by water rock interactions, 2) effect of seawater which includes salinization by seawater near seashores and deposition of sea salt, and 3) nitrate contamination by N fertilization. Contribution of rainfall was also estimated from the measured composition of wet deposition. The geochemical processes were separated using total alkalinity as an indicator for natural mineralization, Cl for effect of seawater, and nitrate for N fertilization. Relatively high correlation of major components with nitrate suggests that nitrification of nitrogenous fertilizers significantly affects ground water chemistry. Total cations derived from nitrate sources have good linearity for nitrate in equivalent basis with a slope of 1.8, which is a mean of proton production coefficients in nitrification of two major compounds in nitrogenous fertilizers, ammonium and urea. Contribution of nitrate sources to base cations, Cl, and SO$_4$ in ground water was determined considering maximum contribution of natural mineralization to estimate a threshold of the effect of N fertilization for ground water chemistry, which shows W fertilization has a greatest effect than any other processes in ground water with nitrate concentration greater than 50 mg/L for Ca, Mg, Na and with concentration greater than 30 mg/L for Cl and SO$_4$.

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Combustion Characteristics of Minco Sub-bituminous Coal at Oxy-Fuel Conditions (민코 아역청탄의 순산소 연소특성)

  • Kim, Jae-Kwan;Lee, Hyun-Dong;Jang, Seok-Won;Kim, Sung-Chul
    • Journal of the Korean Society of Combustion
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    • v.14 no.2
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    • pp.1-9
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    • 2009
  • New way to effectively capture $CO_2$ in coal fired power plant is the combustion of coal using oxy-fuel technology. Combustion characteristics of Minco sub-bituminous coal at oxy-fuel conditions using TGA and drop tube furnace (DTF) were included activation energy about the char burnout, volatile yield and combustion efficiency of raw coal, the porosity of pyrolyzed char and fusion temperature of by-product ash. TGA result shows that the effect of $CO_2$ on combustion kinetics reduces activation energy by approximately 7 kJ/mol at air oxygen level(21% $O_2$) and decreases the burning time by approximately 16%. The results from DTF indicated similar combustion efficiency under $O_2/CO_2$ and $O_2/N_2$ atmospheres for equivalent $O_2$ concentration whereas high combustion efficiency under $O_2/N_2$ than $O_2/CO_2$ was obtained for high temperature of more than $1,100^{\circ}C$. Overall coal burning rate under $O_2/CO_2$ is decreased due to the lower rate of oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. By-product ash produced under $O_2/CO_2$ and $O_2/N_2$ was similar IDT in irrelevant to $O_2$ concentration and atmospheres gas during the coal combustion.

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A Coarse Mesh Model for Numerical Analysis of Lead Frame Deformation Due to Blanking Residual Stress (블랭킹 잔류응력에 의한 리드프레임 변형 수치해석을 위한 대격자 모델)

  • Kim Yong Yun
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.133-138
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    • 2005
  • The deformation of sheet metal due to the residual stress during blanking or piercing process, is numerically simulated by means of a commercial finite element code. Two dimensional plain strain problem is solved and then its result is applied to the deformation analysis of the lead frame. The plain strain element is applied to the 2D problem to observe the Von Mises equivalent stress concentration at the both shearing edges. As the punch penetrates into the sheet material, the stress concentration generated on both edges is getting increased to be the shearing surface. The limits of the punching depth applied to the simulation is 16% and 24% of the sheet thickness for the plain strain element and the hexahedral element, respectively. The hexahedral element and the limit of punching depth were applied to the deformation analysis of the lead frame for the blanking process. The FEM results for the lead deformation were very good agreement with the experimental ones. This paper shows that the coarse mesh has enabled to analyze the lead deformation generated due to the blanking mechanism. This simple approach to save the calculation time will be very effective to the design of the blanking tools in industries.

Studies on Molecular Improvement of Cellulose Utilizing Bacterial Strain -Molecular cloning of ${\beta}$-glucosidase gene of Cellulomonas sp. in E. coli- (纖維質 資化性菌의 分子育種에 관한 硏究 -Cellulomonas속균의 ${\beta}$-glucosidase gene의 E. coli에의 cloning -)

  • Bae, Moo;Lee, Jae-Moon
    • Korean Journal of Microbiology
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    • v.22 no.3
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    • pp.167-173
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    • 1984
  • The cellabiase (${\beta}$-glucosidase) gene in a Cellulomonas sp. CS1-1 was cloned into E. coli HB101 using the vector plasmid pBR322, and the expression of the gene in E. coli studied. The chromosomal DNA of the cellulomonas was digested by seveal restriction enzymes, each of which has only one cleaving site in plasmid pBR322. The recombinant plasmid, pSB2, created with Sal I frament, was expressed for the cellobiase gene in E. coli. The recombiant plasmid was estimated to contain 6.4 Kb foreign DNA at the Sal I site of plasmid pBR322 and the inserted DNA was mapped by single and double digestion with several enzymes. E. coli HB101(pSB2) has slowly grown in a mineral liquid medium containing cellobiose as a sole carbon source. The cellobiase activity in the transformed E. coli was 132 units per liter, which is equivalent to one twenty fifth of that in doner strain Cellulomonas sp. CS1-1. The transforned cell with plasmid containing cellulase gene grow well in the LB mediuns. The synthesis of cellobiase in the strain, E. coli HB101 (pSB2), was inhibited by glucose and at high concentration of cellobiose, and induced by cellobiose at low concentration.

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An Experimental Study on Erosion and Deposition of Estuarial Cohesive Sediment (하구점성토의 침식 및 퇴적에 관한 실험적 연구)

  • 안수한;김재중
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.1 no.1
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    • pp.44-49
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    • 1989
  • Cohesive sedimentation mechanism is affected by various physico-chemical factors. Thus, the field observations and the laboratory experiments for cohesive sediment have been reported for decades. Erosion and deposition test was carried out with cohesive sediment material sampled in the Keum River Estuary in this study. The change of the suspended cohesive sediment concentration was measured for various flow conditions, which have the purpose to determine the critical shear stress and the coefficients for erosion and deposition . The critical shear stress and the coefficient for erosion were determined in the flume test. The equilibrium concentration was determined for each shear stress and the relationship between the normalized equilibrium cocentration with the initial cocentration (Ceq/co) and the equivalent shear stress was obtained. The experimental results were compared with the other results and showed fairly well agreements with them.

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Effect of Initial Diameter on the Soot Generation of Toluene Fuel Droplet (초기 직경 변화가 Toluene 액적의 Soot 생성에 미치는 영향)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.20 no.4
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    • pp.261-267
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    • 2015
  • The main purpose of this study is to provide the information of soot generation of toluene fuel droplet. To achieve this, this paper provides the experimental results on the different initial diameter of toluene droplet combustion characteristics conducted under equivalent ambient pressure ($P_{amb}$) and oxygen concentration ($O_2$) conditions. Visualization of single fuel droplet was performed with high resolution CCD camera and visualization system. At the same time, ambient pressure ($P_{amb}$) and oxygen concentration ($O_2$) were maintained by ambient condition control system. Soot volume fraction ($f_v$) was analyzed and compared on the basis of intensity ratio ($I/I_0$) of background image. The result of soot generation was almost the same regardless of initial droplet diameter since thermophoretic flux is not much changed under the same ambient conditions. Soot standoff ratio (SSR) of 2 mm diameter showed unstable variation characteristics due to the short available measuring time.

Ionic composition of aerosol particles under urban atmospheres of Seoul, Korea (서울시 대기중 입자상 오염물질의 조성에 관한 연구)

  • 한진석;김신도
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.389-398
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    • 1996
  • In order to understand the relative importance of various pathways leading to the production and transformation of aerosols under different atmospheric conditions, the behavior of atmospheric aerosols have been investigated using a high volume tape sample in Seoul for a week period during August 1990. The concentrations of anion $(SO^{2-}_4, NO^-_3, CI^-)$ and cation $(Ca^{2+}, Na^+, NH^+_4)$ species of aerosol samples were analyzed to identify the ionic composition of aerosols and to estimate their relative contributions to aerosol formation. The concentrations of aerosol species were calculated by a multiple regression model. The results of our calculations indicate the existence of various chemical species such as $(NH_4)_2SO_4, Na_2SO_4, CaSO_4, NH_4NO_3, NaNO_3, Ca(NO_3)_2, NH_4Cl$, and NaCl salts. According to our calculations, the most dominant species of aerosol was $(NH_4)_2SO_4$ with the mean concentration of 23.3 $/mu g/m^3$ (66.9%). The proportion of different componts with aerosol (e.g., $NH_4NO_3$ and $NH_4Cl$) was strongly affected by temperature, relative humidity, and partial presure of gases.

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Spectrophotometric Determination of Trace Hg(II) in Cetyltrimethylammonium Bromide Media

  • Jeoung, Moon-Sook;Choi, Hee-Seon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.12
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    • pp.1877-1880
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    • 2004
  • The simple and convenient determination of trace Hg(II) with its 2-mercaptobenzothiazole (MBT) complex in cetyltrimethylammonium bromide (CTAB) media has been studied. The UV-visible spectrum of Hg(II)-MBT complex in CTAB media had a good sensitivity and reproducibility. The Hg(II)-MBT complex in CTAB solution was very stable at pH 10.0 and could be quantitatively complexed if MBT were added to the sample solution more than 10 equivalent of Hg(II). The optimum concentration of CTAB was 0.001%. The calibration curve of Hg(II)-MBT complex with good linearity ($R^2$ = 0.9985) was obtained at the concentration range between $1.0{\times}10^-7$ and $1.0{\times}10^-5$ M in 0.001% CTAB media. The detection limit was $3.1{\times}10^-8$ M (6.2 ng m$L^{-1}$). Hg(II) in the synthetic samples and in the wastewater of the university's wastewater tank and the industrial wastewater tank could also be determined. Based on the experimental results, this proposed technique could be applied to the simple and convenient determination of trace Hg(II) in real samples.

The Impact of Supertall Density on City Systems

  • Price, Bill;Bickerdyke, Andrew;Borchers, Meike;Gabbitas, Tim;Hailey, Lee
    • International Journal of High-Rise Buildings
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    • v.6 no.4
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    • pp.327-332
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    • 2017
  • This paper discusses several topics associated with the densification caused by supertall buildings and their impact on city systems. The paper covers five key areas where a supertall tower creates a concentration of needs and effects. First, the paper comments on population shifts towards the city and how they affect carbon footprint, utilities infrastructure and transport. The effect of single- and mixed-use towers is discussed in the context of population density. The second section brings the issues of transit, accessibility and master planning into focus. The use and criticality of public transport, cycling and walking is described. Servicing and deliveries using freight consolidation and shared systems is also discussed along with their contribution to the culture of sustainable travel. In the third section the paper reflects on supertall buildings' below-ground utilities and drainage provision, particularly the challenges faced in established city infrastructures. The utilities issues associated with supertall concentration (in land-use terms) compared to equivalent low-rise distribution is also commented on in the context of surface water runoff. In the fourth section, the topic of supertall sustainability is discussed and how city systems need to respond to create desirable and affordable space for occupiers. The changing need for vertical communities, 'stacked neighbourhoods' and the notion of a micro-city is described. Finally, the paper considers the energy consumption and resilience of supertall buildings in the context of basic geometry, façade design, climate and mixed-use benefits as they impact city systems.

Bioavailability of Commercially Available Aspirin Tablets in Human (시판 아스피린 정제의 생체내 이용율)

  • Lee, Jin-Hwan;Choi, Jun-Shik;Baik, Chai-Sun;Burm, Jin-Pil
    • Journal of Pharmaceutical Investigation
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    • v.19 no.3
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    • pp.131-136
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    • 1989
  • This study was attempted to investigate the dissolution rate and the bioavailability after oral administration of commercially available aspirin tablets in normal volunteers. The dissolution test was conducted in artificial gastric juice using basket method with three aspirin preparations (A, B and C) which were chemically equivalent. The results were as follows; The dissolution rate was higher in the order of three different brand B>A >C. Area under the blood concentration and peak blood concentration were larger in the order of brand A>B>C. Absorption rate constant and peak time were larger in the order of brand B>A>C, and there was a little difference in elimination rate constant and biological half-life. The correlation of the dissolution rate and absorption rate constant, as well as correlation of the dissolution rate and peak time showed significant linear relationship respectively. From the results of this experiment, it can be concluded that the bioavailability of aspirin tablets showed much difference according to commercial preparations, and that the bioavailability of aspirin tablets in human may be predicted from the results of dissolution rate studies.

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