• 제목/요약/키워드: equilibrium analysis

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A Study of the Institutional Changes in the Aviation Safety Management System

  • Kim, Maeng-Sern
    • 한국항공우주법학회:학술대회논문집
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    • 한국항공우주법학회 2008년도 제40회 국제학술발표대회
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    • pp.165-182
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    • 2008
  • The purpose of this study is to review the changes in the aviation safety management system, how that system has evolved and what forces caused these changes to take place. Also included is an examination of the development process of the aviation safety management system in view of the new institutionalism, identifying the patterns of change. Based on the results of this study, I propose policy methods to design a desirable civil aviation safety system with a view toward raising the safety standards in the Korean civil aviation community. The major analysis variables are as follows: first, aviation accidents caused by external factors and international standards as independent variables; second, environmental changes and political processes affecting aviation safety management system as major mediating variables; and third, the aviation safety management legal system, the aviation safety management organizations and an expert participation system as dependent variables. The institutional changes and continuance of the aviation safety management system show that when specific circumstances arise, the continuance lasts depending on the path dependency, and in a certain circumstance, when immanent changing factors reach a critical point, the system suddenly changes by a punctuated equilibrium, which are all included in this study.

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고성능 이온 크로마토그래피에서 유기산의 크로마토그램 예측 연구 (Prediction of Organic Acid Chromatogram in High Performance Ion Chromatography)

  • 원혜진;한선호;박양순;조기수;김인호
    • KSBB Journal
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    • 제15권1호
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    • pp.60-65
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    • 2000
  • 크로마토그래피의 거동을 수치 모사하기 위하여, retention time method와 moment method에 의해 계산된 파라미터들을 흡착 등온선 모델식에 사용하였다. 이 경우, 이론치와 비교하기 위해서 등용매 조건하게 유기산 이온 크로마토그래피 실험을 수행하였고, 크로마토그램의 거동을 설명하는 수학적 모델로 equilibrium-dispersive model을 사용하였다. Moment method에서는 평균체류시간을 나타내는 1차 모멘트, $m^2$1와 분배 계수 K의 관계로 나타낼 수 있으며, 실험을 통해 분배 계수는 쉽게 구해 질 수 있다. 운전 변수의 변화에 따른 크로마토그램의 특성을 살펴보기 위해서 유기산의 농도, 이동상의 유속, 용리액의 이온 강도 그리고 용질의 주입량을 변화시켜 수치모사를 수행하였다. 각각의 조건에 대해서 크로마토그램은 용질의 농도가 증가할수록, 유속이 증가할수록, 이온 강도가 증가할수록 평균 체류 시간이 감소하고 날카로운 피크를 얻을 수 있었으며, retention time method에서 보다 moment method와 data fitting에 의해 계산된 파라미터들이 실험치와 더 잘 일치함을 볼 수 있었다. 본 연구를 바탕으로, gradient 조건에서 유기산에 대한 이온 크로마토그래피의 거동 연구로 확장할 수 있다.

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분사연소합성(SCS)을 위한 평형종 계산과 용액연소공정 (Calculations of Equilibrium Species and Solution Combustion Process for Spray Combustion Synthesis (SCS))

  • 전병세;이상진;윤존도;권혁보
    • 한국세라믹학회지
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    • 제38권6호
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    • pp.545-550
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    • 2001
  • 본 연구에서는 분사연소합성(SCS)을 위한 기초단계로서 용액연소합성에 대한 거동을 살펴보고자 알루미나 합성을 모델로 하였으며 이를 위해 전구체에 대한 열분해거동, 그리고 각 온도에서의 평형종 분압 계산 및 합성과정을 조사하였다. 각각의 열중량 분석(TGA) 결과 산화제와 환원제(연료)의 열분해 이력이 서로 다르게 나타났으며, 열역학 응용 프로그램인 ChemSag에 의한 평형종 분압의 계산에서 연소속도를 저하시킬 수 있는 $CO_2$와 수증기 가스 분압이 상당부분 존재하였다. 산화제/환원제 혼합물의 열분석(DTA/TG) 결과 산화제와 환원제의 열분해 거동의 차이, 그리고 매우 작은 시료의 양으로 인해 263$^{\circ}C$에서 발열피크가 매우 작게 나타났다. 열분석 시료에 비해 발열 에너지를 높이기 위해 산화제와 환원제 혼합 전구체를 비이커에서 증기압을 조절하며 가열시켜 본 결과 27$0^{\circ}C$에서 $\alpha$-Al$_2$O$_3$생성물을 얻을 수 있었다. 따라서 분사연소합성 반응을 통해 세라믹 원료를 합성하기 위해서는 연소과정 중 열분해 거동과 평형종의 분압을 고려하여야 한다.

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표면에 수직한 계면방향 표면균열의 해석 (Analysis of Interfacial Surface Crack Perpendicular to the Surface)

  • 최성렬
    • 대한기계학회논문집
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    • 제17권2호
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    • pp.277-284
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    • 1993
  • 본 연구에서는 적분변환에 의한 해법을 사용하여 폐형으로 주어지는 엄밀해를 얻었다. 먼저 평면에 수직한 방향의 변위를 도입하여 주어진 문제를 Mellin 변환하 고 수식화 하면 Wiener-Hopf 방정식이 주어진다.이 방정식을 푼 다음 변위에 관한 적분 표현식을 점근(asymptotic)전개하여 평가하면 균열선단 부근의 변위가 결정된다. 이로부터 폐형(closed form)으로 구성되는 균열선단부근의 응력확대계수(stress in- tensity factor)를 얻었다. 이 결과를 가지고 특정한 경우에 해당되는 기존의 연구 결과와 비교하였다. 특별히 가해진 하중이 자기평형(self equilibrium)을 이루는 경 우에 한정하여 계면에 인접한 재료의 결과와 동일함을 무한고체물에 대한 해석에서 보 인 바 있는데, 이와같은 정성적인 결과가 본문제와 같이 계면방향 표면균열을 지니는 반무한 크기의 고체물에서도 유지되는가를 검토하였다. 아울러 본 연구와 동일한 모 양의 균열이라면 고체물표면 혹은 균열면에 임의로 분포하는 비평면하중문제에 대한 응력확대계수는 본 연구의 결과를 가지고 간단한 적분을 수행함으로써 용이하게 계산 됨을 보였다.

An element-based 9-node resultant shell element for large deformation analysis of laminated composite plates and shells

  • Han, S.C.;Kim, K.D.;Kanok-Nukulchai, W.
    • Structural Engineering and Mechanics
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    • 제18권6호
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    • pp.807-829
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    • 2004
  • The Element-Based Lagrangian Formulation of a 9-node resultant-stress shell element is presented for the isotropic and anisotropic composite material. The effect of the coupling term between the bending strain and displacement has been investigated in the warping problem. The strains, stresses and constitutive equations based on the natural co-ordinate have been used throughout the Element-Based Lagrangian Formulation of the present shell element which offers an advantage of easy implementation compared with the traditional Lagrangian Formulation. The element is free of both membrane and shear locking behavior by using the assumed natural strain method such that the element performs very well in thin shell problems. In composite plates and shells, the transverse shear stiffness is defined by an equilibrium approach instead of using the shear correction factor. The arc-length control method is used to trace complex equilibrium paths in thin shell applications. Several numerical analyses are presented and discussed in order to investigate the capabilities of the present shell element. The results showed very good agreement compared with well-established formulations in the literature.

A Study on the Determinants of Bilateral Trade : Evidence from China and US

  • He, Yugang
    • 동아시아경상학회지
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    • 제7권1호
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    • pp.27-38
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    • 2019
  • Purpose - Recently, the trade war between China and US has been escalating, which has also attracted worldwide attention. Based on this background, this paper sets China and US as an example to explore the determinants of bilateral trade between China and US. Research design, date, and methodology - A quarterly data from the 2000-Q1 to the 2017-Q4 will be used to perform an empirical analysis under some econometric approaches such as the fully modified least squares and the vector error correction estimates. Result - The results illustrate that the two economic entities of China and US have the greatest positive effect on bilateral trade between China and US. The real exchange rate has a positive effect on bilateral trade between China and US. The nominal exchange rate has a negative effect on bilateral trade between China and US in the short run. US's average price has a positive effect on bilateral trade between China and US in the short run. China's average price has a negative effect on bilateral trade between China and US in the short run. Meanwhile, the bilateral trade between China and US also suffers from the economic crisis happened in 2008. Even through the bilateral trade between China and US in the short run is deviate from the long-run equilibrium, there exist an error correction mechanism back to the long-run equilibrium. Conclusion - This paper provides some empirical evidences for both governments. Based on the results of this paper, both governments should take corresponding measures to promote the development of bilateral trade between China and US.

A Lattice-Based Monte Carlo Evaluation of Canada Deuterium Uranium-6 Safety Parameters

  • Kim, Yonghee;Hartanto, Donny;Kim, Woosong
    • Nuclear Engineering and Technology
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    • 제48권3호
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    • pp.642-649
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    • 2016
  • Important safety parameters such as the fuel temperature coefficient (FTC) and the power coefficient of reactivity (PCR) of the CANada Deuterium Uranium (CANDU-6) reactor have been evaluated using the Monte Carlo method. For accurate analysis of the parameters, the Doppler broadening rejection correction scheme was implemented in the MCNPX code to account for the thermal motion of the heavy uranium-238 nucleus in the neutron-U scattering reactions. In this work, a standard fuel lattice has been modeled and the fuel is depleted using MCNPX. The FTC value is evaluated for several burnup points including the mid-burnup representing a near-equilibrium core. The Doppler effect has been evaluated using several cross-section libraries such as ENDF/B-VI.8, ENDF/B-VII.0, JEFF-3.1.1, and JENDL-4.0. The PCR value is also evaluated at mid-burnup conditions to characterize the safety features of an equilibrium CANDU-6 reactor. To improve the reliability of the Monte Carlo calculations, we considered a huge number of neutron histories in this work and the standard deviation of the k-infinity values is only 0.5-1 pcm.

SELECTIVE REDUCTION OF ACTIVE METAL CHLORIDES FROM MOLTEN LiCl-KCl USING LITHIUM DRAWDOWN

  • Simpson, Michael F.;Yoo, Tae-Sic;Labrier, Daniel;Lineberry, Michael;Shaltry, Michael;Phongikaroon, Supathorn
    • Nuclear Engineering and Technology
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    • 제44권7호
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    • pp.767-772
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    • 2012
  • In support of optimizing electrorefining technology for treating spent nuclear fuel, lithium drawdown has been investigated for separating actinides from molten salt electrolyte. Drawdown reaction selectivity is a major issue that requires investigation, since the goal is to remove actinides while leaving the fission products and other components in the salt. A series of lithium drawdown tests with surrogate fission product chlorides was run to obtain selectivity data with non-radioactive salts, develop a predictive model, and draw conclusions about the viability of using this process with actinide-loaded salt. Results of tests with CsCl, $LaCl_3$, $CeCl_3$, and $NdCl_3$ are reported here. Equilibrium was typically achieved in less than 10 hours of contact between lithium metal and molten salt under well-stirred conditions. Maintaining low oxygen and water impurity concentrations (<10 ppm) in the atmosphere was observed to be critical to minimize side reactions and maintain stable salt compositions. An equilibrium model has been formulated and fit to the experimental data. Good fits to the data were achieved. Based on analysis and results obtained to date, it is concluded that clean separation between minor actinides and lanthanides will be difficult to achieve using lithium drawdown.

Head Space Analysis에 의한 n-Dodecane-1-Decanol, n-Dodecane-1- Dodecanol과 1-Decanol-1-Dodecanol계의 등온 기액 평형 (Isothermal vapor-liquid equilibria of n-Dodecane-1-Decanol, n-Dodecane-1 -Dodecanol and 1-Decanol-1-Dodecanol systems by Head Space Analysis)

  • 박소진;강용;이태종;최명재;이규완
    • 에너지공학
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    • 제2권2호
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    • pp.225-230
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    • 1993
  • n-dodecane-1-decanol, n-dodecane-1-dodecanol 및 1-decanol-1-dodecanol계 의 14$0^{\circ}C$ 등온 기액평형 데이타를 static method로써 Head Space Gas Chromatography (H.S.G.C)를 이용하여 측정하였다. 액상의 비이상성을 고려하여 계산된 활동도계수는 Margules, Van Laar, Wilson, NRTL g$^{E}$ 모델을 이용하여 상관관계를 구하였으며, Redlich-Kister의 열역학적 일치성 시험을 통해 데이타의 신빙성을 확인하였다. 측정한 이성분계중 n-dodecane-1-decanol계는 최소 공비점을 가짐을 알 수 있었다.

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물중의 잔류농약 분석을 위한 SPME의 최적조건 선정에 관한 연구 (Preparation of Optimal Condition for Residual Pesticides Analysis by Solid-Phase Microextraction in Water)

  • 장미라;정효준;이홍근
    • 한국물환경학회지
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    • 제18권4호
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    • pp.421-433
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    • 2002
  • This study was conducted to develope a simple, rapid and solvent-free solid-phase microextraction(SPME) procedure for extracting three organochlorine, one triazine and nine organophosphorus pesticides from water. The optimal conditions of SPME for analyses of organochlorine pesticides were obtained at $250^{\circ}C$ of desorption temperature, 45 minutes of equilibrium time, pH 6 and NaCl 0% addition using $100{\mu}m$ polydimethylsiloxane fiber and those of triazine and organophosphorus pesticides were obtained at $270^{\circ}C$ of desorption temperature, 60 minutes of equilibrium time, pH 6 and NaCl 0% addition using $100{\mu}m$ polydimethylsiloxane fiber. This method showed good lineality for organochlorine pesticides between 0.0001 and $10{\mu}g/L$ with regression coefficients ranging 0.9986~0.9992 and for triazine and organophosphorus pesticides between 0.01 and $10{\mu}g/L$ with regression coefficients ranging 0.9867~0.9998.