• Carbon letters
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• v.21
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• pp.1-7
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• 2017

The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine ($C-NH_2$) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04b
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• pp.627-632
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• 1998

This study deals with the effect on adhesive strength properties of waterproofing and reinforcing layer and mortar or concrete substrate applicated by epoxy resin anticorrosive and bonding materials. Properties of adhesive strength change condition of concrete substrate, temperature, moisture, curing and cleaning and so on. The purpose of this study is that it makes the estimation value of bond strength of concrete wall and epoxy resin layer when coated epoxy resin as anticorrosive materials for durability performance estimation depend on concrete watertightness, and when penetrated epoxy resin for the reinforcement of concrete used the carbon fiber sheet.

• Journal of the Korea Institute of Building Construction
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• v.7 no.3
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• pp.107-113
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• 2007

This study is to investigate adhesive properties depending on the temperature, humidity, and freeze-thraw of the Steel plate adhesive strengthening method by the epoxy resin. The results are summarized as following. For the temperature variation, the debonding failure appear only after 1 cycle of temperature varoation because the coefficient of thermal expansion of the epoxy resin is comparatively large, and the bonding strength is decreased. The deformation properties and ultrasonic pulse velocity on each materials are similar until 4 cycles on the dry and moisture test. As the freeze-thraw test, the epoxy resin is degraded easily subjected to freeze-thaw cycle, comparatively easy, so the debonding failure may occur in short term because of the freeze-thaw repeatition.p

• Journal of the Korean Applied Science and Technology
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• v.24 no.3
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• pp.264-271
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• 2007

Effect of dispersion methods for Vapor Grown Carbon Fibers (VGCF) in epoxy caused the change in mechanical properties of VGCF/epoxy nanocomposites, such as tensile modulus and tensile strength. The influence of VGCF types - atmospheric plasma treated (APT) VGCF and raw VGCF - and their contents was discussed in detail. Treating VGCF with atmospheric plasma enhanced the surface energy, therefore improved the bonding strength with epoxy matrix. Two different methods used to disperse VGCF were ultrasonic and mechanical homogenizer methods. When using dispersion solutions, the VGCF demonstrated good dispersion in ethanol in both homogenizer and ultrasonic method. The uniform dispersion of VGCF was investigated by scanning electron microscopy (SEM) which showed well-dispersion of VGCF in epoxy matrix. The tensile modulus of raw VGCF/epoxy nanocomposites obtained by ultrasonic method was higher than that of one obtained by homogenizer method. APT VGCF/epoxy nanocomposites showed higher tensile strength than that of raw VGCF/epoxy nanocomposites.

• Transactions of Materials Processing
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• v.13 no.4
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• pp.342-349
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• 2004

The form-joining process (or clinching) uses a set of die and punch to impose the plastic deformation-induced geometric constraint on a sheet metal pair. The joining strength from the process ranges 50-70 percent of that of the resistance spot welding. In this paper, a new form-joining process with the aid of an adhesive is proposed in which an epoxy adhesive is applied to a sheet metal pair, and before it cures the pair is clinched to cause the geometric constraint in the form of a protrusion. In order to reduce the forming load and the height of protrusions, a new die and punch set with a very small clearance is devised to reduce the depth of drawing and the forming load. Taguchi method is employed to find the optimal values of design parameters. To implement each case of the orthogonal array, the finite element method is used. The experiments show that in the tensile-shear test, the bonding strength of the new form-joining process with an epoxy adhesive is approximately the same as that of the resistance spot welding; and in comparison with the other two form-joining processes with an epoxy adhesive, the height of protrusions is reduced by more than 65 percent and the forming load by 50 percent.

• Proceedings of the KAIS Fall Conference
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• 2010.11a
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• pp.470-473
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• 2010

Graphene, consisting of a single layer of carbon in a two-dimensional lattice, has been emerging as a fascinating material with many unique physical, chemical and mechanical properties. In this study, graphenes were prepared by a chemical method. To develop high performance polymer nanocomposites reinforced by graphenes, adequate dispersion of the fillers and strong interfacial bonding between the fillers and the polymer matrix are essential. The purpose of this study was to examine the influence of introducing amine groups on the surfaces of graphenes. FT-IR spectroscopy, SEM were used to confirm the functionalization. Epoxy nanocomposites comprising the graphenes were prepared and their characteristics were investigated by DSC, DMA and TMA. Fracture surfaces of the nanocomposites were investigated by SEM. The functionalized graphenes induced strong interfacial bonding than the pristine graphenes and resulted in considerable improvements in the performance of the nanocomposites.

• Computers and Concrete
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• v.18 no.5
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• pp.951-968
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• 2016

In this study, pullout capacities of post-installed deformed bars anchored in low strength concrete using different bonding materials are investigated experimentally. The experimental study was conducted under outdoor and indoor conditions; on the beams of an actual reinforced concrete building and on concrete bases constructed at Istanbul Technical University (ITU). Ready-mixed cement based anchorage mortar with modified polymers (M1), ordinary cement with modified polymer admixture (M2), and epoxy based anchorage mortar with two components (E) were used as bonding material. Furthermore, test results are compared with the predictions of current analytical models. Findings of the study showed that properly designed cement based mortars can be efficiently used for anchoring deformed bars in low quality concrete. It is important to note that the cost of cement based mortar is much lower with respect to conventional epoxy based anchorage materials.

• International journal of steel structures
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• v.18 no.4
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• pp.1410-1419
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• 2018

Recently, a repair method by bonding patch plates is being applied to corroded steel structures. However, one of the issues of patch plate bonding repair is the brittle debonding of the patch plates. Generally, when the delamination of the patch plates occurs, the composite effect acting between the steel members and patch plates abruptly decreases. Therefore, to prevent the brittle debonding of the patch plates, a repair method combining an adhesive and stud bolts is proposed. Till date, tensile and compressive tests have been performed for the proposed method. In this study, plate bending tests were conducted to verify the effectiveness of this method under bending conditions. Furthermore, two types of epoxy resin-based adhesives were prepared to evaluate the effectiveness of the proposed method with different adhesive properties. The test results show that the proposed method is able to prevent the brittle debonding of the patch plates in the case of both epoxy resins.

• Transactions of the Korean Society of Mechanical Engineers
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• v.8 no.5
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• pp.425-434
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• 1984

The concept of intermittent interlaminar bonding is investigated as a means of improving the fracture toughness of cross-ply Gr/Ep composites without significant loss of tensile strength and modulus. The concept of linear elastic fracture mechanics(LEFM)is used to study the effects of strong bonded area and bonding composites. The experimental results indicate that the fracture toughness and notch strength of intermittent interlaminar bonded composities are improved and the tensile strength only decreased by 3-8% in comparison to those of the fully bonded composites. Damage zones around the crack tip are detected by the modified X-Ray non-destructive testing technique and the fractography. The improvement of toughness is explained based on the damage zones. The mechanisms of damage zone are shown to be caused by subcrack along the fiber on the 0.deg. ply, matrix cracking along the fiber on the 90.deg. ply, interlaminar delamination, and ply pull-out of the 0.deg. ply.

• Computers and Concrete
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• v.4 no.2
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• pp.119-134
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• 2007

External bonding of steel or FRP plates to reinforced concrete (RC) structures has been a popular method for strengthening RC structures; however, unexpected premature failure often occurs due to debonding between the concrete and the epoxy. We proposed a Coulomb criterion with a constant failure surface as the debonding failure criterion for the concrete-epoxy interface. Diagonal shear bonding tests were conducted to determine the debonding properties that were related to the failure criterion, such as the angle of internal friction and the coefficient of cohesion. In addition, an interface element that utilized the Coulomb criterion was implemented in a nonlinear finite element analysis program to simulate debonding failure behavior. Experimental studies and numerical analysies on RC beams strengthened by an externally bonded steel or FRP plate were used to determine the range of the coefficient of cohesion. The results that were presented prove that premature failure loads of strengthened RC beams can be predicted with using the bonding properties and the finite element program with including the proposed Coulomb criterion.