• 한국과학교육학회지
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• 제20권2호
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• pp.344-352
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• 2000

본 연구에서는 고등학생들의 화학 관련 환경 개념과 환경에 대한 태도를 조사하고, 자아존중감, 과학 수업의 즐거움, 여가 활동에서의 과학 흥미 등의 정의적 변인과의 관계를 조사하였다. 학생들의 환경 개념 이해도가 낮았으며, 남학생의 개념 이해도가 여학생보다 높았다. 그러나 환경에 대한 태도는 여학생이 남학생보다 높았다. 생태중심적 태도에서는 남녀 차이가 없었으나, 남학생이 여학생에 비하여 자기중심적 태도를 더 많이 지니고 있었다. 사전 과학 성취 수준이 높은 학생이 낮은 학생보다 환경 개념 이해도가 높았다. 정의적 변인 중 여가 활동에서의 과학 흥미가 환경에 대한 태도와 유의미한 상관이 있었다.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2005년도 봄 학술발표회지 제14권(제1호)
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• pp.267-271
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• 2005

This experiment was carried out at 450"C, which is relatively lower than the temperature for supercritical water oxidation (600-650$^{\circ}C$). In this experiment, the decomposition rates of various incombustible organic substances were very high. In addition, it was confirmed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium(salt formation).However, to raise the decomposition rate, relatively large amount of sodium nitrate(3-4 times the equivalent weight) was required. When complete oxidation is intended as in the case with PCB, the amount of oxidizer and decomposition cost is important. But when vaporization reduction is required as in the case with nuclear wastes, the amount of radioactive wastes increases instead. But as can be seen in the result of XRD measurement, unreacted sodium nitrate remained unchanged. If oxidation reaction of organic substance simply depends on collision frequency, unreacted sodium nitrate can be recovered and reused, then oxidation equivalent weight would be sufficient. In the gas generated, toxic gas was not found. As the supercritical water medium has high reactivity, it is difficult to generate relatively low energy level SO$_{X}$, and NO$_{X}$.

• Bulletin of the Korean Chemical Society
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• 제31권9호
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• pp.2547-2552
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• 2010

CdS nano-particulate films were prepared at the air/water interface under Langmuir monolayers of arachidic acid (AA) via interfacial reaction between $Cd^{2+}$ ions in the subphase and $H_2S$ molecules in the gaseous phase. The films were made up of fine CdS nanoparticles with hexagonal Wurtzite crystal structure after reaction. It was revealed that the formation of CdS nano-particulate films depends largely on the experimental conditions. When the films were ripened at room temperature or an increased temperature ($60^{\circ}C$) for one day, numerous holes were appeared due to the dissolution of smaller nanoparticles and the growth of bigger nanoparticles with an improved crystallinity. When the films were ripened further, CdS rodlike nanoparticles with cubic zinc blende crystal structure appeared due to the re-nucleation and growth of CdS nanoparticles at the stacking faults and defect structures of the hexagonal CdS grains. These structures were characterized by transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and X-ray diffraction (XRD). These results declare that CdS semiconductor nanoparticles formed at the air/water interface change their morphologies and crystal structures during the ripening process due to dissolution and recrystallization of the particles.

• 공업화학
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• 제28권1호
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• pp.8-16
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• 2017

에너지 저장 및 환경 관련 분야에 응용 흡착매질로 바이오매스 기반 활성탄의 중요성을 살펴보았다. 지금까지 발표된 연구 결과는 바이오매스 기반 활성탄의 표면적과 기공부피 이외에 이들의 표면 화학 특성 또한 다양한 분야에 응용될 수 있는 중요한 역할이 있음이 확인된다. 바이오매스 기반 활성탄의 용량은 바이오매스의 특성 및 이들의 활성화 공정에 따라 달라지므로 다양한 응용 분야에 맞게 제조할 수 있다. 따라서 본 리뷰에서는 다양한 분야에 이용되고 있는 바이오매스 기반 활성탄의 역할을 정리하였다.

• 환경영향평가
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• 제12권1호
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• pp.9-22
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• 2003

To consider environmental characteristics in the scope of geochemistry of streams, Hwasun area, soil, sediment and water samples near/in the streams were analyzed in texture and metal contents of soil and sediment and in quality in water. From those analyses, the soils are loamy sand, sandy loam, loam and silty loam in texture. And, the sediments are slightly gravelly sand, gravelly sand and gravelly muddy sand in facies. Metal contents in soils and sediments are of high near Hwasuneup and Hwasun coalfield. In peculiar, P, Co, Li, Ni, Zn and Pb exceed over crust mean contents. Physico-chemistry of above streams according to pH-Eh and Piper's diagrams indicates that the streams are, typically, assigned to natural river water. Water qualities of BOD, T-N and T-P in areas near Hwasun coalfield, Dongmyeon and Hwasuneup are polluted over V level. Enrichment factor(EF) representing metal condensation in P, Cu, Zn and Pb appear near Hwasun coalfield and Hwasuneup from the soil and sediment samples, in part. Additionally, river water in dry season is very high in BOD, T-N, $Na^+$ and ${SO_4}^{2-}$. It is suggested that the relatively high metal contents in the stream be connected with above coalfield and urban areas.

• 한국환경과학회지
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• 제17권9호
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• pp.981-992
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• 2008

This study examined how to produce new methods of copper (II) sulfate crystallization by using a small-scale chemistry tool such as small-scale reaction surface and petri dish. The making of copper(II) sulfate is included in the 5th grade elementary science textbooks. Various copper(II) compounds were reacted with a 2 M sulfuric acid solution. The result of this study is as follows: Seven small amounts of copper(II) compounds were reacted with a few drops of 2 M sulfuric acid solution at room temperature to make a copper(II) sulfate crystal of triclinic shape. Using the petri dish method, a copper(II) sulfate crystal could be identified within one hour of reacting copper(II) hydroxide, copper(II) carbonate, copper(II) nitrate, copper(II) perchlorate, cupric(II) formate from a few drops of 2 M sulfuric acid solution at room temperature. When using the lap top method for copper(II) perchlorate, cupric formate, a proper crystal could be identified within one hour as well. SSC methods were used for the first time to make a copper sulfate crystal via chemical reaction. We can make a copper(II) sulfate crystal using a simple method which is easier, safer and saves time in class. And since a small quantity of chemicals are being used in SSC chemical methods, waste is greatly reduced. This lessens the amount of environmental problems caused by the experiment. This can be helpful in preserving nature. In addition the cost of chemical and laboratory equipment is greatly reduced because it uses material that we find in our daily lives. There will be continued study of small-scale methods such as improvement of new programs, study and training of teachers, and securing SSC tools. I would like to suggest such as SSC methods are applicable in elementary School Science. I would like it to become a wide spread program.

• Nano
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• 제13권11호
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• pp.1850132.1-1850132.14
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• 2018

The direct synthesis of metal-organic frameworks (MOFs) with acidic and basic active sites is challenging due to the introduction of functional groups by post-functionalization method often jeopardize the framework integrity. Herein, we report the direct synthesis of acid-base bifunctional MOFs with tuning acid-base strength. Employing modulated hydrothermal (MHT) approach, microporous MOFs named $UiO-66-NH_2$ was prepared. Through the ring-opening reaction of 1,3-propanesultone with amino group, $UiO-66-NH_2-SO_3H-type$ catalysts can be obtained. The synthesized catalysts were well characterized and their catalytic performances were evaluated in one-pot glucose to 5-HMF conversion. Results revealed the acid-base bi-functional catalyst possessed high activity and excellent stability. This work provides a general and economically viable approach for the large-scale synthesis of acid-base bi-functional MOFs for their potential use in catalysis field.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제1권2호
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• pp.167-175
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• 1997

This study was conducted for an efficient utilization of waste fly ash obtained from the power plant. Fly ash was used for synthesizing zeolite. Na-P1 zeolite could be easily synthesized from waste fly ash and showed the potential to remove heavy metal ions. The synthetic zeolite showed good adsorption property for heavy metal much better than raw fly ash and natural zeolites. Na-P1 exhibited the high adsorption efficiency with a maximum value of 260 Pb mg/g and strong affinity for $Pb^{2+}$ ion. The metal ion selectivity of Na-P1 was determined in a decreasing order : $Pb^{2+}>Cd^{2+}>Cu^{2+}>Zn^{2+}>Fe^{3+}$.

• 대한화학회지
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• 제60권6호
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• pp.428-435
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• 2016

Effective mastering and learning of basic organic chemical concepts is pivotal to ensure students continue to excel to the higher levels of organic chemistry learning. Concept learning is crucial for first-year organic chemistry students so that they can comprehend and understand a concept better and able to make connection to problems. In the present paper, the authors have implemented the Interactive Anonymous Quiz (IAQ) with "must-have" features in the organic chemistry course as a teaching tool to instill students' interest and enhance conceptual understanding in organic chemistry. The effectiveness of this activity was examined and evaluated through students' reflective writing. Students showed positive learning outcome on the implemented activity as reflected by the reflective writings. In addition, this activity could be employed as an activity to check on students' concept understanding, to instill students' interest in organic chemistry course and to improve on students' weakest topic in organic chemistry in the future classes.

• 한국환경과학회지
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• 제14권10호
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• pp.919-928
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• 2005

This study introduces the development of new supercritical water oxidation(SCW)(multiple step oxidation) to destruct recalcitrant organic substances totally and safely by using sodium nitrate as an oxidant. This method has solved the problems of conventional SCW, such as precipitation of salt due to lowered permittivity, pressure increase following rapid rise of reaction temperature, and corrosion of reactor due to the generation of strong acid. Destruction condition and rate in the supercritical water were examined using Polyvinyl Chloride(PVC) and ion exchange resins as organic substances. The experiment was carried out at $450^{\circ}C$ for 30min, which is relatively lower than the temperature for supercritical water oxidation $(600-650^{\circ}C)$. The decomposition rates of various incombustible organic substances were very high [PVC$(87.5\%)$, Anion exchange resin$(98.6\%)$, Cationexchange resin$(98.0\%)$]. It was observed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium (salt formation). However, relatively large amount of sodium nitrate (4 equivalent) was required to raise the decomposition ratio. For complete oxidation of PCB was intended, the amount of oxidizer was an important parameter.