• Title/Summary/Keyword: environmental VOCs

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Practical Usage of Low-Temperature Metal Catalyst for the Destruction of Volatile Organic Compounds (VOCs) (휘발성 유기화합물(VOCs) 제거를 위한 저온금속촉매 실용화에 관한 연구)

  • Jung, Sung-Chul;Lee, Seung-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.6
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    • pp.397-405
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    • 2012
  • In this study, performance evaluation of newly developed technology for the economical and safe removal of volatile organic compounds (VOCs) coming out from electronic devices washing operation and offensive odor induction materials was made. Metal oxidization catalyst has shown 50% of removal efficiency at the temperature of $220^{\circ}C$. Composite metal oxidization catalyst applied in this study has shown that the actual catalysis has started at the temperature of $100^{\circ}C$. Comprehensive analysis on the catalyst property using Mn-Cu metal oxidization catalyst in the pilot-scale unit was made and the removal efficiency was variable with temperature and space velocity. Full-scale unit developed based on the pilot-scale unit operation has shown 95% of removal efficiency at the temperature of $160^{\circ}C$. Optimum elimination effective rates for the space velocity was found to be $6,000hr^{-1}$. The most appropriate processing treatment range for the inflow concentration of VOCs was between 200 ppm to 4,000 ppm. Catalyst control temperature showed high destruction efficiency at $150{\sim}200^{\circ}C$ degrees Celsius in 90~99%. External heat source was not necessary due to the self-heat reaction incase of VOCs inflow concentration is more than 1,000 ppm. Equipment and fuel costs compared to the conventional RTO/RCO method can be reduced by 50% and 75% respectively. And it was checked when there was poisoning for sulfide and acid gas.

Emission Characteristics of Volatile Organic Compounds from Building Flooring Materials (건축용 바닥재로부터의 휘발성유기화합물 방출특성)

  • Yun, Joong-Seop;Lee, Myong-Hwa;Eom, Seok-Won;Kim, Min-Young;Kim, Jong-Ho;Kim, Shin-Do
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.973-978
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    • 2010
  • The emission of volatile organic compounds (VOCs) from building materials is one of great concerns due to maintain airtight condition of a building to reduce energy consumption, and it causes the deterioration of indoor air quality. Therefore, the emission characterization of VOCs from building materials is necessary to improve indoor air quality. Emission characteristics of VOCs from a plywood flooring that is one of the most commonly used materials in an under-heating system, and from an adhesive that is generally used to stick a plywood flooring to a concrete floor were investigated using an emission chamber test in this study. It was found that the VOCs emission factor was dependent upon and proportional to indoor temperature, and the emission characteristics were closely related to the existing places and conditions of VOCs sources inside the building materials. Maximum emission factors of hexane and toluene from building materials were generally observed at the beginning, however, only that of toluene from a plywood flooring was shown after 6 hours from the beginning. It could be considered that the existing place and condition of toluene source inside a plywood flooring could influence on the VOCs emission. From this study, bake-out time more than 72 hours could be recommended before moving in to avoid the exposure to high concentration of VOCs emitted from an under-heating system.

Measurement of VOCs Concentrations at Jeonju Industrial Area and Emission Characteristics (전주공단지역의 주요VOCs 배출농도 측정 및 배출원별 특성 분석)

  • Kim, Deug-Soo;Yang, Go-Soo;Park, Bi-O
    • Journal of Environmental Science International
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    • v.16 no.3
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    • pp.299-310
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    • 2007
  • It will be necessary to make proper management plans to preserve the air quality in good level for the public. In order to make these plans, source information and detail emission inventories of the city and near industrial areas should be given. However, lack of the source measurements data makes us more difficult to complete the source inventory. VOC source Inventory could be utilized for the feasibility study to estimate the contribution of VOC sources presenting to the receptor such as residential area. It may give policy maker an idea how to control the air quality, and improve their social environment in the area. This study shows data that measured VOCs concentrations from the local industrial areas in Jeonju during from May 2005 to January 2006. The samples were collected from the near sources in 7 major factories in the industrial park as well as 5 general sources in near city Jeonju area to elucidate the abundances of speciated VOCs and their spacial and temporal distributions depending on source bases. Industrial sources are as follows; chemical, food, paper, wood, metal, non-metal (glass), and painting (coating) industries. The 5 general sources are sampled from tunnel, gasoline gas station, dry cleaning shop, printing (copy) shop, and road pavement working place in urban area. To understand the near source effect at receptor, samples from the 2 receptor sites (one is at center of the industrial complex and the other site is at distance residential area downwind from the center) were collected and analyzed for the comparison to source concentration. The mass contributions of the speciated VOC to total mass of VOCs measured from the different sources and ambient (2 receptors) were presented and discussed.

Construction of the VOC Analytical System and Evaluation of its Performance (휘발성유기화합물(VOCs) 분석 시스템의 구성 및 성능 평가)

  • 이수형;송희남;김희갑
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2001.05a
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    • pp.119-119
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    • 2001
  • 휘발성유기화합물(VOCs)은 음용수의 소독 과정, 자동차 및 공장의 배기가스로부터의 배출 등 다창한 경로를 거쳐 대기 중에 존재하면서 인체에 직접적인 영향을 미치거나, 오존과 같은 물질와 생성에 관여하는 것으로 알려져 있다. 따라서, 이러한 화합물들에 대한 분석 및 관리의 중요성이 증가되면서, VOCs 분석에 필요한 장치의 구성이 절실히 요구되고 있다. (중략)

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$TiO_2$-태양광을 이용한 VOCs 분해연구

  • 박상은;주현규;정희록;전명석;강준원
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.11a
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    • pp.48-49
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    • 2001
  • 광촉매 분해반응시 광원으로서 기존의 UV램프의 사용에서 벗어나 인공적인 에너지가 필요없는 태양광을 VOCs 광분해에 solar simulator에서 타당성을 검토하고 태양광에 직접 적용하여 확인하였다. $TiO_2$-UVA 시스템에서 보다 $TiO_2$-태양광을 적용한 실험에서 분해반응속도의 증가를 보였다. 결과적으로 VOCs처리에 있어서 태양광의 적용이 가능하며 최대 4.514${\times}$$10^{-5}$ Einstein $min^{-1}$의 photon flow를 필요로 하는 광촉매분해반응에서 $TiO_2$ UVA시스템보다 태양광을 이용한 적용이 더 효과적인 것으로 사료된다.

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Characteristics of Air Quality in the West Coastal Urban Atmosphere; Characteristics of VOCs Concentration Measured from an Industrial Complex Monitoring Station at Gunsan and a Roadside Station at Jeonju (서해연안 도시지역의 대기질 특성 연구: 군산시 산업단지와 전주시 도로변에서 VOCs 농도분포 특성 연구)

  • Ryoo, Jae-Youn;Kim, Deug-Soo;Chae, Soo-Cheon;Nam, Tu-Cheon;Choi, Yang-Seock
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.6
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    • pp.633-648
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    • 2010
  • The study was performed to elucidate the characteristics of VOCs at distinct monitoring sites in urban atmosphere; one is at a roadside in downtown inland city of Jeonju, and the other is at an industrial site in Gunsan near coastal area. The ambient samples were collected for 24 hours in two-bed adsorbent tubes by using MTS-32 sequential tube sampler equipped with Flex air pump every 16 days in a roadside and a industrial complex from February to November in 2009. VOCs were determined by thermal desorption coupled with GC/MSD. Major individual VOCs in roadside samples were shown as following order in magnitude: toluene>m,p-xylene>ethyl benzene>decanal; and those in the industrial complex samples were as follows: toluene>ethanol>ethyl acetate>decanal>m,pxylene. High benzene concentration in the roadside was more frequently occurred than in the industrial complex. However ambient level of toluene in the industrial complex was higher than that in the road side. Results from roadside sample analysis showed that nonane and 1,2,4-trimethylbenzene were very frequently observed with higher concentrations than those in the industrial complex. It seems that nonane and 1,2,4-trimethylbenzene could be the source characteristics for the roadside air. From the diurnal variation, it was found that concentrations of benzene, ethylbenzene, xylene, nonane and 1,2,4-trimethylbenznene in the roadside were higher during rush hours; but those in the industrial complex were higher from 10 to 16 LST when the industrial activities were animated. On weekly base, the concentration of benzene, toluene, ethylbenzene and m,p-xylene in the roadside were higher specifically on Wednesday, but those in the industrial complex were higher on Sunday. It was found that the general trends of VOCs levels at both sites significantly influence on seasonal changes. The results of factor analysis showed that the VOCs in the roadside were mainly affected by the emission of vehicles and the evaporation of diesel fuel, meanwhile those in the industrial complex were influenced by the evaporation of solvents and vehicular emission.

Paint booth volatile organic compounds emissions in an urban auto-repair center

  • Cho, Minkyu;Kim, Ki-Hyun;Szulejko, Jan E.;Dutta, Tanushree;Jo, Sang-Hee;Lee, Min-Hee;Lee, Sang-hun
    • Analytical Science and Technology
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    • v.30 no.6
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    • pp.329-337
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    • 2017
  • A major concern regarding most auto-repair shops in residential areas is the emission of odorous volatile organic compounds (VOCs) into the local atmosphere, especially during painting operations. VOCs contribute to poor local air quality and are responsible for the perceived odor and discomfort experienced by local residents. Sixteen major VOCs (6 aromatic hydrocarbons and 10 aliphatic carbonyl compounds) were selected as potential target compounds. The site was an auto-repair shop located in a central region of Seoul, South Korea, where the air quality of the site has been a subject of residents' complaints. The sampling points were as follows: 1) in the painting booth with new (NB) or old (OB) removal system, (2) in the exhaust duct after new (ND) or old (OD) odor removal filter, and (3) 2 m below the discharge vent (4 m above the ground) (outdoor air, OA). Each sample was coded: (1) before painting (BP), (2) during painting (DP), and (3) after painting (AP). The toluene level in the duct with the new removal filter during painting (ND-DP) was 1.5 ppm (v/v), while it was 3.8 ppm (v/v) in the right duct with an old removal filter during painting (OD-DP). Accordingly, the effect of filter replacement was reflected by differences in VOC levels. Therefore, accurate monitoring of odorous VOCs is an important step to reduce odor nuisance from local sources.

A Study on the removal characteristics of VOCs and Odors with Biofilter (Biofilter에 의한 VOCs 및 악취물질의 제거특성에 관한 연구)

  • Park Jin-Do;Suh Jung-Ho;Lee Hak-Sung
    • Journal of Environmental Science International
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    • v.14 no.9
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    • pp.843-849
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    • 2005
  • The objective of this research was to investigate the removal efficiencies ofVOCs and odors with newly developed biofilter which was designed to sustain the biofilm constantly on the packed media. Initially, four types of media, for example, fiber, activated carbon, ceramic and the mixture of activated carbon and ceramic(AIC mixture J, were used for packed materials of biofilter. When ethylalcohol was selected as a test gas for media efficiency, fiber and AIC mixture had better removal efficiencies of ethyl alcohol than others. Removal efficiencies for acetaldehyde, ethyl alcohol, butylalcohol, ethylacetate and diethylamine in biofilter with fiber and AIC mixture as packed media were increased as the residence time increased. Butylalcohol, especially, showed the maximum removal efficiency among all used VOCs and odors. In case of ethyl acetate, the difference of removal efficiencies between low and high residence times was wide remarkably.

A Study on the Characteristics of Monoterpene Emissions from Different Wood Species (건조목재의 모노테르펜 배출특성에 관한 연구)

  • Park Hyun Ju;Kim Jo Chun;Park Byung Dae;Park Kang Nam
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.145-151
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    • 2006
  • As the concerns about indoor air quality (IAQ) increase in recent years, lots of research works are under way to investigate the influence of volatile organic compounds (VOCs) emitted from building products on the IAQ. One of the regulations for the IAQ is the level of total VOCs (TVOCs) from building products, assuming that the TVOCs are suspected to cause many health problems such as skin irritation, asthma, and allergy. However, the presence of biogenic VOCs, or natural VOCs (NVOCs) is believed to be beneficial to human health. Therefore, this study attempted to investigate chemical species and the NVOCs compositions of solid lumbers from different wood species. It was found that major VOC components were monoterpenes such as $\alpha$-pinene, $\beta$-pinene, d-limonene, camphene, $\alpha$-terpinene, $\gamma$-terpinene etc.

Effect of Temperature, Pressure, and Air Flow Rate on VOCs Desorption for Gasoline Vapor Recovery (유증기 회수를 위한 VOCs 탈착에 미치는 온도, 압력 및 공기유량의 영향)

  • Lee, Song-Woo;Na, Young-Soo;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.22 no.9
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    • pp.1131-1139
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    • 2013
  • Desorption characteristics of VOCs were investigated for the effective recovery of gasoline vapor. The adsorption capacity and desorption capacity were excellent at relatively low temperatures. The differences in the desorption capacity were not large in the condition; desorption temperature $25^{\circ}C$, desorption pressure 760 mmHg, inlet air flow rate 0.5 L/min, but were relatively great in the condition; desorption temperature $0^{\circ}C$, desorption pressure 60 mmHg, inlet air flow rate 1.0 L/min. The desorption ability of pentane was increased to about 81.4%, and the desorption ability of hexane was increased to about 102%, also the desorption ability of toluene was increased to about 156.7% by changes of temperature, pressure, inlet air flow rate in the experimental conditions. The optimum desorption condition for the effective recovery of VOCs was in the conditions; desorption temperature $0^{\circ}C$, desorption pressure 60 mmHg, inlet air flow rate 1.0 L/min.