• Title/Summary/Keyword: enhanced degradation

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Experimental investigation on the degradation of SiGe LNAs under different bias conditions induced by 3 MeV proton irradiation

  • Li, Zhuoqi;Liu, Shuhuan;Ren, Xiaotang;Adekoya, Mathew Adefusika;Zhang, Jun;Liu, Shuangying
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.661-665
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    • 2022
  • The 3 MeV proton irradiation effects on SiGe low noise amplifier (LNA) (NXP BGU7005) performance under different voltage supply VCC (0 V, 2.5 V) conditions were firstly experimental studied in this present work. The S parameters including S11, S22, S21, 1 dB compression point and noise figure (NF) of the test samples under different bias voltage supply were measured and compared before and after 3 MeV proton irradiation. The total proton irradiation fluence was 1 × 1015 protons/cm2. The maximum degradation quantities of the gain S21 and NF of the test samples under zero bias are measured respectively 1.6 dB and 1.2 dB. Compared with the samples under 2.5 V bias supply, the maximum degradation of S21 and NF are respectively 1.1 dB and 0.8 dB in the whole frequency band. It is noteworthy that the gain and NF of SiGe LNAs under zero-bias mode suffer enhanced degradation compared with those under normal bias supply. The key influence factors are discussed based on the correlation of the SiGe device and the LNA circuit. Different process of the ionization damage and displacement damage under zero-bias and 2.5 V bias voltage supply contributed to the degradation difference. The underlying physical mechanisms are analyzed and investigated.

An Experimental Study on the Removal of Chlorophenol by TiO2/H2O2/UV Using Continuous flow Reactor (연속흐름식 반응기를 이용한 TiO2/H2O2/UV에 의한 클로로페놀 제거(除去)에 관한 실험적(實驗的) 연구(硏究))

  • Lee, Sang-Hyup;Park, Joo-Suk;Park, Chung-Hyun;Kim, Dong Ha
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.3
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    • pp.55-64
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    • 1998
  • The degradation efficiency of chlorophenolic compounds in $TiO_2/H_2O_2$ combined system was compared with that of in $TiO_2$ sole system. As a result, the addition of hydrogen peroxide in photocatalytic oxidation reaction greatly enhanced the degradation efficiency of chlorophenolic compounds due to the availability of the hydroxyl radical formed on the $TiO_2$ surface. The hydrogen peroxide under UV illumination produces hydroxyl radicals that appear to be another source of hydroxyl radical formation. These results indicated the $TiO_2/H_2O_2$ combined system shows higher degradation efficiency than the $TiO_2$ sole system. Compared to another oxidation reaction, hydrogen peroxide assisted photocatalytic oxidation is more promising in practical aspect.

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Enhanced Photocatalytic Properties of Visible Light Responsive La/TiO2-Graphene Composites for the Removal of Rhodamin B in Water

  • Areerob, Yonrapach;Oh, Won-Chun
    • Journal of the Korean Chemical Society
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    • v.61 no.4
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    • pp.168-178
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    • 2017
  • $La/TiO_2$ - graphene composites were synthesized in this study, and applied to the photocatalytic degradation of Rhodamine B (RhB) under UV-visible light irradiation. X-ray diffraction (XRD), surface analysis, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) analysis demonstrated that $La/TiO_2$ nanoparticles were well distributed on the surface of graphene, and formed the heterostructure of $La/TiO_2$-graphene. Compared to the pure $TiO_2$, $La/TiO_2$-graphene composites displayed much higher photocatalytic activities in RhB degradation under UV-visible light irradiation. The photocatalytic data of $La/TiO_2$-graphene composites exhibit extended light absorption in the visible light region, and possess better charge separation capability than that of pure $TiO_2$. The high photocatalytic activity was attributed to the composite's high adsorptivity, extended light absorption, and increased charge separation efficiency, due to the excellent electrical properties of graphene, and the large surface contact between graphene and $La/TiO_2$ nanoparticles.

Ceramic-Ceramic Wear Zirconia/Alumina Composites For The Application Of Total Hip Joint Implant (인공 고관절 골두용 세라믹 복합재료에 대한 세라믹-세라믹 접촉 마멸 특성 분석)

  • Kim H.;Lee K.Y.;Kim D. J.;Lee M. H.;Seo W. S.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.355-361
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    • 2004
  • Ceramic femoral heads in the total hip replacement have been developed to reduce the polyethylene liner wear, Alumina and zirconia (3Y-TZP) having the excellent tribological properties are coupled against acetabular cups of polyethylene and are used in clinical application worldwide. However, alumina has a risk of catastrophic failure, and zirconia has the low temperature degradation in spite of enhanced fracture toughness. Recently, novel zirconia/alumina composite is very attractive due to the low temperature degradation (LTD)-free character and high fracture toughness. In the present study, we focus on the wear of ceramic on ceramic, which are able to be used as femoral heads and acetabular cups. Therefore, LTD-free zirconia/alumina composites with three compositions are made in a form of disk and cylinder, and the wear of the composites is performed on pin-on-disk type wear tester. The wear is conducted with or without lubricant. All the composites fabricated with the different composition show the good wear resistance.

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Effect of Ensiling with Acremonium Cellulase, Lactic Acid Bacterial and Formic Acid on Tissue Structure of Timothy and Alfalfa

  • Asian, Aniwaru;Okamoto, M.;Yoshihira, T.;Ataku, K.;Narasaki, N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.6
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    • pp.593-598
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    • 1997
  • The changes of tissue structure in timothy and alfalfa during ensiling process with silage additives; lactic acid bacteria, cellulase and formic acid, were observed with a video microscope. Stem samples were obtained from the second internode, and cut to divide into 2 pieces. One piece was for observation of ensiled material and the other was for silage. The latter piece was put into a nylon cloth bag, and ensiled with grass for 50 days in a small experimental silo Lignification of the plant tissues was checked by acid phloroglucinol. Natural silage fermentation resulted in some degradation of less lignified parenchyma in both plant species. However, lignified sclerenchyma and vascular bundles remained intact. The cellulase enhanced the degradation of parenchyma tissue, while the formic acid suppressed the degradation. The effect of lactobacillus was small. The percentage of remained cross sectional area of stem and the loss of NDF and ADF by silage fermentation confirmed the observation. High negative correlations were obtained between the remained area and loss of fibrous components during silage fermentation in both plants, and between the loss of fibrous components and in vitro dry matter digestibility in timothy but not in alfalfa.

Photocatalytic Characteristics of PbS/ZnO/TiO2 Nanotube Composite (PbS/ZnO/TiO2 나노복합체의 광촉매 특성)

  • Lee, Jong-Ho;Heo, Sujeong;Youn, Jeong-Il;Kim, Young-Jig;Kim, In-Ki;Jang, Kyung-Wook;Oh, Han-Jun
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.569-575
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    • 2017
  • To improve photocatalytic performance, a $PbS/ZnO/TiO_2$ nanotube catalyst was synthesized, and its surface characteristics and photocatalytic efficiency were investigated. The hybrid photocatalysts were produced by anodic oxidation and successive ionic layer adsorption and reaction(SILAR). The photocatalytic efficiency was evaluated using the dye degradation rate. The $PbS/ZnO/TiO_2$ photocatalyst significantly enhanced the photocatalytic activity for dye degradation, which was ascribed to the synergistic effect of their better absorption of solar light and a decrease in the rate of excited electron-hole recombination.

The Degrdation of Pigment-Producing Furfural in Aquatic Waste (환경오염 유해색소의 미생물학적 분해)

  • 하영칠;홍순우;한홍의
    • Korean Journal of Microbiology
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    • v.21 no.4
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    • pp.207-212
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    • 1983
  • Isolated Gram-negative bacteria, being capable of degrading toxic, recalcitrant, and pigment-producing furfural, were tentatively identified as Pseudomonas testosteroni, Pseudomonas maltophilia, Klebsiella Pneumoniae, and Pseudomonas fluorescens. They exhibited synergistic effects between P. testosteroni and the others in the degradation of colourproducing furfural. Synergistic effects and possible sequence of its degradation were attempted by manometric technique. P. testosteroni could degrade furfural to decolourize it and produce ninhydrin-reaction postive substance (NPS) which could be utilized by P. maltophilia and K. pneumoniae and the latter two bacteria could ,degrade furfural to 2-furoic acid as an oxidized form. Finally 2-furoic acid was further oxidized by P. fluorescens. Once NPS and 2-furoic acid were produced, the degradation efficiency was enhanced by competing four bacteria against furfural and 2-furoic acid.

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Optimization of Explosive Compounds (TNT and RDX) Biodegradation by Indigenous Microorganisms Activated by External Carbon Source (외부탄소원으로 활성화된 토착미생물에 의한 화약물질(TNT and RDX) 분해 최적화)

  • Park, Jieun;Bae, Bumhan
    • Journal of Soil and Groundwater Environment
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    • v.19 no.3
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    • pp.56-65
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    • 2014
  • Contamination of explosive compounds in the soils of military shooting range may pose risks to human and ecosystems. As shooting ranges are located at remote places, active remediation processes with hardwares and equipments are less practical to implement than natural solutions such as bioremediaton. In this study, a series of experiments was conducted to select a suitable carbon source and to optimize dosing rate for the enhanced bioremediation of explosive compounds in surface soils and sediments of shooting ranges with indigenous microorganisms activated by external carbon source. Treatability study using slurry phase reactors showed that the presence of indigenous microbial community capable of explosive compounds degradation in the shooting range soils, and starch was a more effective carbon source than glucose and acetic acid in the removal of TNT. However, at higher starch/soil ratio, i.e., 2.0, the acute toxicity of the liquid phase increased possibly due to transformation products of TNT. RDX degradation by indigenous microorganisms was also stimulated by the addition of starch but the acute toxicity of the liquid phase decreased with the increase of starch/soil ratio. Taken together, the optimum range of starch/soil ratio for the degradation of explosive compounds without significant increase in acute toxicity was found to be 0.2 of starch/soil.

Fabrication of Ag/In2O3/TiO2/HNTs hybrid-structured and plasma effect photocatalysts for enhanced charges transfer and photocatalytic activity

  • Wang, Huiqin;Wu, Dongyao;Liu, Chongyang;Guan, Jingru;Li, Jinze;Huo, Pengwei;Liu, Xinlin;Wang, Qian;Yan, Yongsheng
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.164-174
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    • 2018
  • The purpose of this work designed hybrid-structured and plasma effect photocatalyst of $Ag/In_2O_3/TiO_2/HNTs$ via sol-gel and photo-reduction methods. The structures, morphologies, optical and photoelectric performances of as-prepared photocatalysts were characterized via XRD, TEM, XPS, BET, UV-vis DRS, PL and photocurrents. The photocatalytic activity was evaluated by degradation of TC. The results showed that the hybrid-structure and plasma effect can effectively cause the multi-transfer of electrons and increase the separation rate of electron and hole pairs which obtained high photocatalytic activity. The photocatalytic degradation processes reveal that $^{\bullet}O_2{^-}$ and $h^+$ are major active species.

Photocatalytic Degradation of Methylene Blue in Presence of Graphene Oxide/TiO2 Nanocomposites

  • Kim, Sung Phil;Choi, Hyun Chul
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2660-2664
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    • 2014
  • A simple method of depositing titanium dioxide ($TiO_2$) nanoparticles onto graphene oxide (GO) as a catalytic support was devised for photocatalytic degradation of methylene blue (MB). Thiol groups were utilized as linkers to secure the $TiO_2$ nanoparticles. The resultant GO-supported $TiO_2$ (GO-$TiO_2$) sample was characterized by transmission electron microscopy (TEM), near-edge X-ray absorption fine structure (NEXAFS), and X-ray photoelectron spectroscopy (XPS) measurements, revealing that the anatase $TiO_2$ nanoparticles had effectively anchored to the GO surface. In the photodegradation of MB, GO-$TiO_2$ exhibited remarkably enhanced photocatalytic efficiency compared with thiolated GO and pure $TiO_2$ nanoparticles. Moreover, after five-cycle photodegradation experiment, no obvious deactivation was observed. The overall results showed that thiolated GO provides a good support substrate and, thereby, enhances the photodegradation effectiveness of the composite photocatalyst.