• Title/Summary/Keyword: engineered surface

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Improvement of Mechanical Property by Single Ion Exchange Process in Substrate Glass

  • Lee, Hoi-Kwan;Kang, Won-Ho;Green, David J.
    • Journal of Information Display
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    • v.4 no.3
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    • pp.12-16
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    • 2003
  • In connection with the ion exchange strengthening on soda-lime-silicate, substrate glass for display use was investigated. In the processing, the temperature was varied during the ion exchange in order to make stress profile and to determine optimum condition. In the present work, we found that the maximum value of strength was 617.8 MPa after an ion exchange process at 470 $^{\circ}C$ for 1h, and then, at 450 $^{\circ}C$ for 24h. Also, the effect of residual stress placed on the near surface was measured by analyzing the number of crack branches and brittleness. This approach allowed us the residual stress profile to be engineered to improve mechanical reliability.

Developing a Virus-Binding Bacterium Expressing Mx Protein on the Bacterial Surface to Prevent Grouper Nervous Necrosis Virus Infection

  • Lin, Chia-Hua;Chen, Jun-Jie;Cheng, Chiu-Min
    • Journal of Microbiology and Biotechnology
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    • v.31 no.8
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    • pp.1088-1097
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    • 2021
  • Grouper nervous necrosis virus (GNNV) infection causes mass grouper mortality, leading to substantial economic loss in Taiwan. Traditional methods of controlling GNNV infections involve the challenge of controlling disinfectant doses; low doses are ineffective, whereas high doses may cause environmental damage. Identifying potential methods to safely control GNNV infection to prevent viral outbreaks is essential. We engineered a virus-binding bacterium expressing a myxovirus resistance (Mx) protein on its surface for GNNV removal from phosphate-buffered saline (PBS), thus increasing the survival of grouper fin (GF-1) cells. We fused the grouper Mx protein (which recognizes and binds to the coat protein of GNNV) to the C-terminus of outer membrane lipoprotein A (lpp-Mx) and to the N-terminus of a bacterial autotransporter adhesin (Mx-AIDA); these constructs were expressed on the surfaces of Escherichia coli BL21 (BL21/lpp-Mx and BL21/Mx-AIDA). We examined bacterial surface expression capacity and GNNV binding activity through enzyme-linked immunosorbent assay; we also evaluated the GNNV removal efficacy of the bacteria and viral cytotoxicity after bacterial adsorption treatment. Although both constructs were successfully expressed, only BL21/lpp-Mx exhibited GNNV binding activity; BL21/lpp-Mx cells removed GNNV and protected GF-1 cells from GNNV infection more efficiently. Moreover, salinity affected the GNNV removal efficacy of BL21/lpp-Mx. Thus, our GNNV-binding bacterium is an efficient microparticle for removing GNNV from 10‰ brackish water and for preventing GNNV infection in groupers.

One-Step β-Li2SnO3 Coating on High-nickel Layered Oxides via Thermal Phase Segregation for Li-ion Batteries

  • Seongmin Kim;Hanseul Kim;Sung Wook Doo;Hee-Jae Jeon;In Hye Kim;Hyun-seung Kim;Youngjin Kim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.293-300
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    • 2023
  • The global energy storage markets have gravitated to high-energy-density and low cost of lithium-ion batteries (LIBs) as the predominant system for energy storage such as electric vehicles (EVs). High-Ni layered oxides are considered promising next-generation cathode materials for LIBs owing to their significant advantages in terms of high energy density. However, the practical application of high-Ni cathodes remains challenging, because of their structural and surface instability. Although extensive studies have been conducted to mitigate these inherent instabilities, a two-step process involving the synthesis of the cathode and a dry/wet coating is essential. This study evaluates a one-step β-Li2SnO3 layer coating on the surface of LiNi0.8Co0.2O2 (NC82) via the thermal segregation of Sn owing to the solubility limit with respect to the synthesis temperature. The doping, segregation, and phase transition of Sn were systematically revealed by structural analyses. Moreover, surface-engineered 5 mol% Sn-coated LiNi0.8Co0.2O2 (NC82_Sn5%) exhibited superior capacity retention compared to bare NC82 owing to the stable surface coating layer. Thus, the developed one-step coating method is suitable for improving the properties of high-Ni layered oxide cathode materials for application in LIBs.

Evaluation of the Safty for the Disposal of High-level Nuclear Waste in the Granite (화강암지역에 고준위 원자력 폐기물 처리에 대한 안정성 평가)

  • Oh, Chang Whan
    • Economic and Environmental Geology
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    • v.29 no.2
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    • pp.215-225
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    • 1996
  • All the radionuclides in high-level nuclear waste will decay to harmless levels eventually but for some radionuclides decay is so slow that their radiation remains dangerous for times on the order of tens or hundreds of thousands of years. At the present time, the most favorite disposal plan for high-level radioactive waste is a mined geological disposal in which canister enclosing stable solid form of radioactive waste is placed in mined cavities locating hundred meters below the surface. The chief hazard in such disposal is dissolution of radionuclides from the waste in the groundwater that will eventually carry the dissolved radionuclides to surface environments. The hazard from possible escape of the radionuclides through groundwater can be delayed by engineered and geologic barriers. The engineered barriers can become useless by unexpected geologic catastrophe such as volcanism, earthquake, and tectonic movement and by fraudulent work such as careless construction, improperly welded canisters within the first few decades or centuries. As a result, dangerously radioactive waste which is still intensively radioactive is directly exposed to attack by moving groundwater. All the more, it is almost impossible to control repositories for times more than 10,000 years. Therefore, naturally controlled geologic, barriers whose properties will not be changed within 10,000 years are important to guarantee the safety of repositories of high-level radioactive waste. In Sweden and France, the suitability of granite for the mined geological disposal of high-level waste has been studied intensively. According to the research in Sweden and France, granites has the following physio-chemical characteristics which can delay the transportation of radionuclide by groundwater. First, the permeabilities of granites decreases as the depth increases and is $10^{-8}{\sim}10^{-12}m/s$ at depth below 300 m. Second, groundwater at depth below 300 m has pH=7-9 and reducing condition (Eh=-0.1~0.4). This geochemical condition is desirable to prevent both canister and solid waste from corrosion. Third most radionuclides are not transported by low solubilities and some radionuclide with high solubility such as Cs and Sr are retarded by absorption of geologic media through which ground water flows. Therefore, if high-level waste is disposed at depth below 300 m in the granite body which has a low permeability and is geologically stable more than 10,000 years, the safety of repositories from the hazard due to radionuclide escape can guaranteed for more than 10,000 years.

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Exposure of Laboratory Workers to Airborne Nanoparticles during Acid Treatments on Engineered Carbon Nanotubes (탄소나노튜브 표면 처리 실험실 종사자의 공기중 나노입자 노출에 관한 연구)

  • Ha, Ju-Hyun;Shin, Yong-Chul;Lee, Seung-Chul;Paik, Samuel Y.;Kim, Boo-Wook;Choi, Byung-Soon;Kang, Dong-Mug;Paik, Nam-Won
    • Journal of Environmental Health Sciences
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    • v.36 no.5
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    • pp.343-350
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    • 2010
  • This study was performed to investigate laboratory workers' exposures to airborne nanoparticles at a university laboratory where acid treatment experiments were conducted on the surfaces of engineered carbon nanotubes (CNTs). The surface area concentrations, number concentrations, and mass concentrations of airborne nanoparticles were measured at personal breathing zones (PBZs) for various tasks using direct reading instruments. For all three metrics, airborne nanoparticle concentrations during the experiments were higher than background levels measured before and after the experiments for all three metrics. Among the various tasks that were performed as part of these experiments, one task that involved filtering a mixture of acid and CNTs showed the highest concentrations in all three metrics, with concentrations of $116.6\;{\mu}m^2$/cc, 24320 pt/cc, and $9.0\;{\mu}g/m^3$, respectively. Nanoparticle surface area concentrations measured at a representative area fluctuated with those at the PBZs in the laboratory. This result indicates that nanoparticles generated during the experiments were not just limited to the PBZs of the workers but were also present throughout the room, potentially exposing co-located workers. CNTs were detected by a transmission electron microscope in an air sample collected while handling the CNTs. All the tasks were performed inside fume hoods, with the sliding sashes open to their required heights. It was noted that the capture velocities of the fume hoods were much lower than the American National Standards Institute (ANSI)'s recommendation level (0.4 to 0.6 m/s). In conclusion, this study showed that, due to inadequate control, laboratory researchers performing acid treatment experiments on surfaces of CNTs were exposed to airborne nanoparticles generated during the tasks.

Beneficial Effects of Microwave-Induced Argon Plasma Treatment on Cellular Behaviors of Articular Chondrocytes Onto Nanofibrous Silk Fibroin Mesh

  • Jin, Soo-Chang;Baek, Hyun-Sook;Woo, Yeon-I;Lee, Mi-Hee;Kim, Jung-Sung;Park, Jong-Chul;Park, Young-Hwan;Rah, Dong-Kyun;Chung, Kie-Hyung;Lee, Seung-Jin;Han, In-Ho
    • Macromolecular Research
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    • v.17 no.9
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    • pp.703-708
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    • 2009
  • Silk fibroin scaffolds were examined as a biomaterial option for tissue-engineered cartilage-like tissue. In tissue engineering for cartilage repair using a scaffold, initial chondrocyte-material interactions are important for the following cell behaviors. In this study, the surface of nanofibrous silk fibroin (NSF) meshes was modified by a microwave-induced argon plasma treatment in order to improve the cytocompatibility of the meshes used as cartilaginous grafts. In addition, the effects of a plasma treatment on the cellular behavior of chondrocytes on NSF were examined. The plasma treatment resulted in an increase in the hydrophilicity of NSF meshes suggesting that the cytocompatibility of the mesh might be improved. Furthermore, the human articular chondrocytes showed higher viability on the surface-modified NSF meshes. These results suggest that the surface modification of NSF meshes by plasma can enhance the cellular behavior of chondrocytes and may be used in tissue engineering.

Reliability and risk assessment for rainfall-induced slope failure in spatially variable soils

  • Zhao, Liuyuan;Huang, Yu;Xiong, Min;Ye, Guanbao
    • Geomechanics and Engineering
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    • v.22 no.3
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    • pp.207-217
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    • 2020
  • Slope reliability analysis and risk assessment for spatially variable soils under rainfall infiltration are important subjects but they have not been well addressed. This lack of study may in part be due to the multiple and diverse evaluation indexes and the low computational efficiency of Monte-Carlo simulations. To remedy this, this paper proposes a highly efficient computational method for investigating random field problems for slopes. First, the probability density evolution method (PDEM) is introduced. This method has high computational efficiency and does not need the tens of thousands of numerical simulation samples required by other methods. Second, the influence of rainfall on slope reliability is investigated, where the reliability is calculated from based on the safety factor curves during the rainfall. Finally, the uncertainty of the sliding mass for the slope random field problem is analyzed. Slope failure consequences are considered to be directly correlated with the sliding mass. Calculations showed that the mass that slides is smaller than the potential sliding mass (shallow surface sliding in rainfall). Sliding mass-based risk assessment is both needed and feasible for engineered slope design. The efficient PDEM is recommended for problems requiring lengthy calculations such as random field problems coupled with rainfall infiltration.

Analysis of Flow and Heat Transfer in Swirl Chamber for Cooling in Hot Section (고온부 냉각을 위한 스월챔버내의 유동 및 열전달 해석)

  • Lee K. Y.;Kim H. M.;Han Y. M.;Lee S. Y.
    • Journal of computational fluids engineering
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    • v.7 no.3
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    • pp.9-16
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    • 2002
  • Most of modem aerospace gas turbines must be operated at a gas temperature which is several hundreds of degrees higher than the melting temperatures of the materials used in their construction. Complicated cooling schemes need to be employed in the combustor walls and in the high pressure turbine stages. Internal passages are cast or machined into the hot sections of aero-gas turbine engines and air from the compressor is used for cooling. In many cases, the cooling system is engineered to utilize jets of high velocity air, which impinge on the internal surfaces of the components. They are categorized as 'Impinging Cooling Method' and 'Vortex Cooling Method'. Specially, research of new cooling system(Vortex Cooling Method) that overcomes inefficiency of film cooling and limitation of space. The focus of new cooling system that improves greatly cooling efficiency using less amount of cooling air on surface heat transfer elevation. Therefore, in this study, a numerical analysis has been peformed for characteristics of flow and heat transfer in the swirl chamber and compared with the flow measurements by LDV. Especially, for understanding high heat transfer efficiency in the vicinity of wall, we considered flow structure, vortex mechanism and heat transfer characteristics with variation of the Reynolds number.

Nanowastes treatment in environmental media

  • Kim, Younghun
    • Environmental Analysis Health and Toxicology
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    • v.29
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    • pp.15.1-15.7
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    • 2014
  • Objectives This paper tried to review a recent research trend for the environmental exposure of engineered nanomaterials (ENMs) and its removal efficiency in the nanowaste treatment plants. Methods The studies on the predicted environmental concentrations (PEC) of ENMs obtained by exposure modeling and treatment (or removal) efficiency in nanowaste treatment facilities, such as wastewater treatment plant (WTP) and waste incineration plant (WIP) were investigated. The studies on the landfill of nanowastes also were investigated. Results The Swiss Federal Laboratories for Materials Science and Technology group has led the way in developing methods for estimating ENM production and emissions. The PEC values are available for surface water, wastewater treatment plant effluents, biosolids, sediments, soils, and air. Based on the PEC modeling, the major routes for the environmental exposure of the ENMs were found as WTP effluents/sludge. The ENMs entered in the WTP were 90-99% removed and accumulated in the activated sludge and sludge cake. Additionally, the waste ash released from the WIP contain ENMs. Ultimately, landfills are the likely final destination of the disposed sludge or discarded ENMs products. Conclusions Although the removal efficiency of the ENMs using nanowaste treatment facilities is acceptable, the ENMs were accumulated on the sludge and then finally moved to the landfill. Therefore, the monitoring for the ENMs in the environment where the WTP effluent is discharged or biomass disposed is required to increase our knowledge on the fate and transport of the ENMs and to prevent the unintentional exposure (release) in the environment.

Bioremediation of metal contamination groundwater by engineered yeasts expressing phytochelatin synthase (Phytochelatin synthase 발현을 통한 효모의 중금속 처리에 관한 연구)

  • ;;;Wilfred Chen
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.290-292
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    • 2004
  • Heavy metal contamination has been increased in aqueous environments near many industrial facilities, such as metal plating facilities, mining operations, and tanneries. The soils in the vicinity of many military bases are also reported to be contaminated and pose a risk of groundwater and surface water contamination with heavy metals. The biological removal of metals through bioaccumulation has distinct advantages over conventional methods; the process rarely produces undesirable or deleterious chemical byproducts, it is highly efficient, easy to operate and cost-effective in the treatment of large volumes of wastewater containing toxic heavy metals. In addition, a recent development of molecular biology shed light on the enhancing the microorganism's natural remediation capability as well as improving the current biological treatment. In this study, characteristics of the cell growth and heavy metal accumulation by Saccharomyces cerevisiae strains expressing phytochelatin syntahse (PCS) gene were studied in batch cultures. The AtCRFI gene was demonstrated to confer substantial increases in metal tolerance in yeast. PCS-expressing cells tolerated more Cd$^{2+}$ than controls.

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