• 제목/요약/키워드: energy-transfer

Search Result 4,157, Processing Time 0.036 seconds

Electron Trapping and Transport in Poly(tetraphenyl)silole Siloxane of Quantum Well Structure

  • Choi, Jin-Kyu;Jang, Seung-Hyun;Kim, Ki-Jeong;Sohn, Hong-Lae;Jeong, Hyun-Dam
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.158-158
    • /
    • 2012
  • A new kind of organic-inorganic hybrid polymer, poly(tetraphenyl)silole siloxane (PSS), was invented and synthesized for realization of its unique charge trap properties. The organic portions consisting of (tetraphenyl)silole rings are responsible for electron trapping owing to their low-lying LUMO, while the Si-O-Si inorganic linkages of high HOMO-LUMO gap provide the intrachain energy barrier for controlling electron transport. Such an alternation of the organic and inorganic moieties in a polymer may give an interesting quantum well electronic structure in a molecule. The PSS thin film was fabricated by spin-coating of the PSS solution in THF organic solvent onto Si-wafer substrates and curing. The electron trapping of the PSS thin films was confirmed by the capacitance-voltage (C-V) measurements performed within the metal-insulator-semiconductor (MIS) device structure. And the quantum well electronic structure of the PSS thin film, which was thought to be the origin of the electron trapping, was investigated by a combination of theoretical and experimental methods: density functional theory (DFT) calculations in Gaussian03 package and spectroscopic techniques such as near edge X-ray absorption fine structure spectroscopy (NEXAFS) and photoemission spectroscopy (PES). The electron trapping properties of the PSS thin film of quantum well structure are closely related to intra- and inter-polymer chain electron transports. Among them, the intra-chain electron transport was theoretically studied using the Atomistix Toolkit (ATK) software based on the non-equilibrium Green's function (NEGF) method in conjunction with the DFT.

  • PDF

Thermal Design and Analysis for Space Imaging Sensor on LEO (지구 저궤도에서 운용되는 영상센서를 위한 열설계 및 열해석)

  • Shin, So-Min;Oh, Hyun-Ung
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.39 no.5
    • /
    • pp.474-480
    • /
    • 2011
  • Space Imaging Sensor operated on LEO is affected from the Earth IR and Albedo as well as the Sun Radiation. The Imaging Sensor exposed to extreme environment needs thermal control subsystem to be maintained in operating/non-operating allowable temperature. Generally, units are periodically dissipated on spacecraft panel, which is designed as radiator. Because thermal design of the imaging sensor inside a spacecraft is isolated, heat pipes connected to radiators on the panel efficiently transfer dissipation of the units. First of all, preliminary thermal design of radiating area and heater power is performed through steady energy balance equation. Based on preliminary thermal design, on-orbit thermal analysis is calculated by SINDA, so calculation for thermal design could be easy and rapid. Radiators are designed to rib-type in order to maintain radiating performance and reduce mass. After on-orbit thermal analysis, thermal requirements for Space Imaging Sensor are verified.

A Comparative Study on the Methods Estimating Wave Directional Spectrum (파향스펙트럼 추정법의 비교 연구)

  • 오병철;심재설
    • Journal of Korean Society of Coastal and Ocean Engineers
    • /
    • v.2 no.3
    • /
    • pp.119-127
    • /
    • 1990
  • Wave directional spectrum estimation methods for irregular waves were considered in this study. Until now, the Longuet-Higgins Method (LHM) initiated by Longuet-Higgins et al. (1963) has been widely used, but resolutions of the estimation were found to be low. Kobune's Maximum Entropy Method (MEM) for the estimation of wave directional spectrum, bas-ed on the entropy Principle showed higher resolutions comparing with the LHM . If the wave directional spectrum is of Delta functions, the MEM is exact in its estimation. It was also found that for a unimodal spectrum, if the Mitsuyasu's spreading coefficient is above 5, the estimation resolutions were high. In bimodal spectrum, as the angle difference between the two peaks increased, the resolution improved. The energy seems to transfer to the smoother peak in the smoothing of peak's peakedness. LHM has a tendency to estimate bimodal spectrum as a unimodal spectrum ; thus, except for its computational speed, the resolution of LHM falls far below that of MEM.

  • PDF

A Study on the Relationship between Structural Characteristics of Cotton Fabrics and their Cool-and-Warm Felling (I) - at $65\%$ Relative Humidity- (면직물의 구성특성과 냉온감과의 상관성에 관한 연구( I ) -상대습도 $65\%$하에서-)

  • Chang Jee Hye
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.14 no.2
    • /
    • pp.152-163
    • /
    • 1990
  • The purpose of this study is to experimentally analyze the relationship between structural characteristics of cotton fabrics and their cool-and-warm felling in order to develop more comfortable fabrics. Comfort in textile products has been emphasized as consumers preferred performance to fashion of clothing. Thermal comfort of clothing is a basic parameter of the comfort sensation which is usually represented by the cool-and-warm feeling felt by human skin. Cloo-and-warm feeling is perceived by the heat flux which transfers heat energy stored in an object to skin. We feel warm (cool) if the temperature of nerve extremity in skin ascends (descends). As cool-and-warm feeling determines the comfort sensation of clothing, it is important to develop new comfort fabrics. Although considerable works have been made on the body, clothing, and environment, there has been no research study on the structural characteristics of fabrics and their cool and warm feeling. Cool-and-warm feeling is closely related to the transient heat transfer property. This research study used the cotton fabrics manufactured in Korea as sample and measured $q_{max}$ value with thermal property measuring instrument (Thermo-Labo II type). $q_{max}$ values estimated by polynomial regression equation were compared with those observed in this study. This study also identified the structural parameters of cotton fabrics for a specific range of $q_{max}$ values. The findings of this study can be summarized as follows: 1) As the thickness, porosity and air permeability of cotton fabrics increase, $q_{max}$ value decreases. 2) As the fabric count and over factor of cotton fabrics increase, $q_{max}$ value also increases. 3) $q_{max}$ values have been estimated by simple and polynomial regression equations developed in this study. Regression curves which have been plotted by polynomial regression equations also provided with the range of structural parameters for a specific range of $q_{max}$ values of cotton fabrics. This study would be significant in that it has identified the structural Parameters for the cool-and-warm feeling of cotton fabric at $65\%$ relative humidity.

  • PDF

BLAC speed contol using precision Velocity Estimation through the Rotor Position ObservationR (관측 위치를 지령치로 하는 새로운 속도추정 알고리즘을 이용한 BLAC 속도제어)

  • Lee, Sang-Hun;Song, Hyin-Jig;Park, Chan-Kyu
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.17 no.3
    • /
    • pp.93-102
    • /
    • 2014
  • Recently the interest in permanent magnet alternating motor using for electric compressor become great. Especially the research on Interior Permanent Magnet Motor has been doing actively for its advantages in the energy density and the efficiency. In order to control the output of motor to the desired value, the current control or speed control of motor are required. The accurate detection of rotor position and speed information are necessary for the control of motor. In general, the encoder, hall sensor, and resolver are used to obtain the information of motor position and speed and the speed detection algorithm, M/T method, is applied. However, the M/T method causes the error depending on rotor speed. Therefore, this M/T speed detection method is not perfect. In this paper, it is proposed that the PI control with a 1st transfer function and the integration element between velocity and position are composed in series and this feeds back to the reference value of position angle. The proposed algorithm is a function of the integral elements 2nd term, speed element, is used as an output. Thus, it is possible to detect the correct speed by configuring like the mechanical structure similarly. The proposed algorithm is verified by using PSIM DLL and is applied to the BLAC motor drive. And also it is confirmed that this system estimates the accurate speed regardless of rotor speed changes. As a example, the experimental results and simulations shows that the proposed method is very effective.

Change in Engine Exhaust Characteristics Due to Automotive Waste Heat Recovery (엔진 배기 폐열회수로 인한 배기 특성 변화)

  • Kim, Kibum
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.8
    • /
    • pp.4723-4728
    • /
    • 2014
  • In this study, a thermoelectric module (TEM) and a diesel engine were modeled using 1-D commercial software AMESim, and the performance of the TEM was evaluated when the engine was operated under the NEDC driving cycle. The goal of TEM modeling was to investigate not only the waste heat recovery (WHR) rate and energy converting efficiency, but also the heat transfer rate by taking the materials characteristics into account. In addition, a diesel oxidation catalyst (DOC) was designed, and it was found that the waste heat recovery with TEM affects the activation of DOC and alters engine exhaust composition. The simulation indicated that the WHR using TEM is beneficial for decreasing the fuel consumption of vehicles, but the reduction in the exhaust temperature affects the activation of DOC, resulting in an approximately 14% increase in CO and HC emissions. Therefore, the effect of waste heat recovery on the automotive emission characteristics must be considered in the development of automotive engine WHR systems.

HEN Simulation of a Controlled Fluid Flow-Based Neural Cooling Probe Used for the Treatment of Focal and Spontaneous Epilepsy

  • Mohy-Ud-Din, Zia;Woo, Sang-Hyo;Qun, Wei;Kim, Jee-Hyum;Cho, Jin-Ho
    • Journal of Sensor Science and Technology
    • /
    • v.20 no.1
    • /
    • pp.19-24
    • /
    • 2011
  • Brain disorders such as epilepsy is a condition that affects an estimated 2.7 million Americans, 50,000,000 worldwide, approximately 200,000 new cases of epilepsy are diagnosed each year. Of the major chronic medical conditions, epilepsy is among the least understood. Scientists are conducting research to determine appropriate treatments, such as the use of drugs, vagus nerve stimulation, brain stimulation, and Peltier chip-based focal cooling. However, brain stimulation and Peltier chip-based stimulation processes cannot effectively stop seizures. This paper presents simulation of a novel heat enchanger network(HEN) technique designed to stop seizures by using a neural cooling probe to stop focal and spontaneous seizures by cooling the brain. The designed probe was composed of a U-shaped tube through which cold fluid flowed in order to reduce the temperature of the brain. The simulation results demonstrated that the neural probe could cool a 7 $mm^2$ area of the brain when the fluid was flowing atb a velocity of 0.55 m/s. It also showed that the neural cooling probe required 23 % less energy to produce cooling when compared to the Peltier chip-based cooling system.

A Magnetization Study of Prussian-blue Analogue NaxMny[Fe(CN)6]

  • Minh, Nguyen Van;Phu, Phung Kim;Thuan, Nguyen Minh;Yang, In-Sang
    • Journal of Magnetics
    • /
    • v.13 no.4
    • /
    • pp.149-152
    • /
    • 2008
  • In this report, we present the results of a study on the effects of the particle size on the properties of the Prussian blue (PB) analog $Na_xMn_y[Fe(CN){_6}]$. A novel synthesis method of the $Na_xMn_y[Fe(CN){_6}]$ nano-particles using an organic solvent, formamide, is employed. The size of the PB particles is found to be 100-150 nm for the samples prepared in the formamide solvent, which is much smaller than that of the samples prepared using water only. The broadening of the X-ray diffraction peaks of the nano-sized PB samples is attributed to the lattice disorder and a dramatic reduction in the particle size. The compositions of the samples are confirmed by an energy-dispersive X-ray analysis (EDAX), and the result proves that the samples are actually $Na_xMn_y[Fe(CN){_6}]$ Prussian blue. The UV-vis spectra show a broad intervalence charge-transfer (CT) band in the visible region between 400 and 700 nm, and the absorption decreases abruptly in the green region for the nano-sized PB sample. A divergence between the field cooled (FC) and zero field cooled (ZFC) magnetization curves is observed for the nano-sized PB sample at 11 K, indicating that nanoparticles in the sample are single domain superparamagnets with a blocking temperature of 11 K. Our results reveal that the nano-sized PB samples show significantly different optical and magnetic properties than those of the bulk PB samples.

Effect of Argon Ion Beam Incident Angle on Self-Organized Nanostructure on the Surface of Polyethylene Naphthalate Film (알곤 이온빔 입사각에 따른 Polyethylene Naphthalate 필름 표면의 자가나노구조화 분석)

  • Joe, Gyeonghwan;Yang, Junyeong;Byeon, Eun-Yeon;Park, Young-Bae;Jung, Sunghoon;Kim, Do-Geun;Lee, Seunghun
    • Journal of the Korean institute of surface engineering
    • /
    • v.53 no.3
    • /
    • pp.116-123
    • /
    • 2020
  • Ion beam irradiation induces self-organization of nanostructure on the surface of polymer film. We show that the incident angle of Ar ions on polyethylene naphthalate(PEN) film changes self-organized nanostructure. PEN film was irradiated by argon ion beams with the ion incident angle of 0°, 30°, 45°, 60°, and 80°. Nanostructure was altered from dimple to ripple structure as the angle increases. The ripple structure changed to pillar structure after 60°due to that the shallow incident angle increased the ion energy transfer per depth up to 50 eV/Å, which value could induce excessive surface heating and oligomer formation reacting as a physical mask for anisotropic etching. And quantitative analysis of the nanostructures was adapted by using ABC model and fractal dimension theory.

Routing Protocol for Wireless Sensor Network Considering Data Transmission Stability and Load Quantity (선형적 데이터 전달의 안정성과 부하량을 고려한 무선 센서 네트워크 라우팅 프로토콜)

  • Hwang, Min;Cheon, Seung-Hwan;You, Jin-Ho;Kien, Nguyen Trung;Lee, Guee-Sang
    • The Journal of the Korea Contents Association
    • /
    • v.7 no.11
    • /
    • pp.111-119
    • /
    • 2007
  • Sensor networks are needed for special purposes such as collecting or transmitting information by using sensor devices, for which various routing protocols have been proposed. Among existing protocols, the modified PEGASIS routing technique is known to be effective when applied to cases with directional transmissions of data. However it does not consider recovery from errors or guaranteeing stability in data transmission, while sensor devices performing repetitive relays and controls are prone to errors. In this paper, a double relay routing protocol for Zigbee based sensor networks where data are transfered reliably with a linear direction. The proposed protocol is effective in the sense that it secures the relaible transmission of data with minimal energy consumption based on a directional data transfer. A streetlight control system has been presented as an application of the proposed protocol.