• Title/Summary/Keyword: energy transfer mechanism

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A study on the improvement of efficiency in the light railway vehicle system using IPT (유도 급전을 이용한 경전철 시스템의 효율 개선에 대한 연구)

  • Choi, Seung-Cheol;Lee, Byung-Song;Mok, Hyung_Soo
    • Proceedings of the KIPE Conference
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    • 2010.11a
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    • pp.62-63
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    • 2010
  • This paper presents a potential for application of Inductive Power Transfer(IPT) to the light railway vehicle system. IPT system allows for a vehicle fitted with existing or new generation batteries to park over a small charging unit and commence charging immediately. Regular charging will allow for smaller batteries to be used in vehicles. In this paper, IPT system uses a full-bridge LLC resonant converter and is possible for the regenerative braking which is an energy recovery mechanism.

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Evolution of iodine from $NaI-Na_2 O_2$ System

  • Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.4 no.2
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    • pp.109-115
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    • 1972
  • The evolution of radioiodine 131I from a sodium peroxide system as a function of time, temperature, and carrier gas (nitrogen) flow rate was studied. Virtually no iodine was volatilized at 25$0^{\circ}C$ and a very small amount, of the order of 10$^{-3}$ % per flour, at 63$0^{\circ}C$. Substantially greater amounts of iodine were volatilized at 7$25^{\circ}C$ and 83$0^{\circ}C$. The data are consistent with the hypothesis that the mechanism of transfer is distillation of sodium iodide, and that elemental iodine is not produced in this system.

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Effects of chlorhexidine digluconate on thickness of outer membranes isolated from Cultured Porphyromonas gingivalis

  • Jang, Hye-Ock;Ahn, Ki-Weon;Shin, Sang-Hun;Chung, In-Kyo;Yun, Il
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.93.2-93.2
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    • 2003
  • To get a better insight into the biophysical mechanism of action of chlorhexidine digluconate, we examined the effect of chlorhexidine digluconate on the thickness of outer membranes isolated from cultured Porphyromonas gingivalis using energy transfer between the membrane surface fluorescent probe (l-anilinonaphthalene-8-sulfonic acid) and the hydrophobic fluorescent probe [1,3-di(l-pyrenyl)propane]. 1-Anilinonaphthalene-8-sulfonic acid quenches the monomer fluorescence of 1,3-di(1-pyrenyl)propane. (omitted)

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Spectroscopic Studies on the Interaction of N-alkyl Phenothiazines with Bovine Serum Albumin

  • Seetharamappa, J.;Shaikh, S.M.T;Kamat, B.P.
    • Journal of Photoscience
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    • v.12 no.1
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    • pp.25-32
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    • 2005
  • Binding of N-Alkyl phenothiazines (NAP) to bovine serum albumin (BSA) was studied by spectroscopic methods.It was found that the phenothiazine ring common to all drugs makes major contribution to interaction. However, the nature of alkylamino group at position 10 influences the protein binding significantly. Stern-Volmer plots indicated the presence of static component in the quenching mechanism. The high magnitude of rate constant of quenching indicated that the process of energy transfer occurs by intermolecular interaction and thus the drug-binding site is in close proximity to tryptophan residues of BSA. Binding studies in presence of hydrophobic probe, 8-anilino-1-naphthalein-sulphonic acid showed that there is hydrophobic interaction between drug and the probe and they do not share common sites in BSA. Thermodynamic parameters obtained from data at different temperatures showed that the binding of NAP to BSA predominantly involve hydrophobic forces. The effects of some cations and anions common ions were investigated on NAP-BSA interactions. The CD spectrum of BSA in presence of drug showedthat binding of drug leads to change in the helicity of the protein.

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Design and Implementation of Energy Efficient File Transfer Mechanism Using CRC64 (CRC64해시를 이용한 에너지 효율적인 파일 전송 기법 설계 및 구현)

  • Jung, Ho-Min;Kang, Sung-Woon;Lee, Jeong-Gun;Ko, Young-Woong
    • Proceedings of the Korea Information Processing Society Conference
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    • 2011.04a
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    • pp.149-151
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    • 2011
  • 모바일 단말에서 소프트웨어의 기능을 구현할 때, 배터리 소모를 최소화 시키는 것이 매우 중요하다. 본 연구에서는 모바일 단말에서 파일 전송을 수행함에 있어서 에너지 효율적으로 처리하는 기법을 제안한다. 주요 아이디어는 클라이언트 부분에서 전송하려는 파일을 128Kbyte 크기의 블록으로 나누고 CRC64를 사용하여 블록의 해시를 서버로 보내 블록을 전송할 지 결정한다. 보내고자 하는 블록이 서버에 있는 크기만큼 대역폭을 줄이면서 모바일 단말의 에너지 소모를 줄이는 것이다. 실험 결과 5% 이상의 중복율을 가지는 파일에 대해서 제안하는 기법이 배터리 소모를 크게 줄일 수 있음을 보였다.

Kinetics and Mechanism of the Pyridinolysis of Aryl Ethyl Chlorothiophosphates in Acetonitrile

  • Adhikary, Keshab Kumar;Lee, Hai-Whang
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.3947-3951
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    • 2011
  • The nucleophilic substitution reactions of Y-aryl ethyl chlorothiophosphates with X-pyridines are studied kinetically in acetonitrile at $55.0^{\circ}C$. The Hammett and Bronsted plots for substituent X variations in the nucleophiles exhibit biphasic concave upwards with a break point at X = 3-Me. The substituents of X = 4-CN and 4-Ac show great positive deviations from both the Hammett and Bronsted plots. The Hammett plots for substituent Y variations in the substrates exhibit biphasic concave upwards with a minimum point at Y = H. The obtained values of the cross-interaction constants (${\rho}_{XY}$) are all in spite of the biphasic free energy correlations for both substituent X and Y variations, since the ${\rho}_X$values with both the strongly and weakly basic pyridines are almost constant. A stepwise mechanism with a rate-limiting leaving group departure from the intermediate is proposed where the distance between X and Y does not vary from the intermediate to the second transition state. A frontside attack is proposed with the strongly basic pyridines based on the considerably great magnitudes of ${\rho}_X$ and ${\beta}_X$ values and a backside attack is proposed with the weakly basic pyridines based on the relatively small magnitudes of ${\rho}_X$ and ${\beta}_X$. The positive deviations of the two strong ${\pi}$-acceptor parasubstituents, X = 4-Ac and 4-CN, from both the Hammett and Bronsted plots are rationalized by the great extents of bond formation and breaking.

A Numerical Study of a Vehicle Windshield Defrosting Mechanism (자동차 전면유리 제상 메커니즘의 수치해석 연구)

  • Kang, Seung-Jae;Jun, Yong-Du;Lee, Kum-Bae
    • Journal of Energy Engineering
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    • v.19 no.3
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    • pp.151-155
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    • 2010
  • Adequate visibility through a vehicle windshield and frost melting period are critical aspects of major design parameters. To make progress in this area, a good understanding of the flow behavior and heat transfer characteristics produced by the HVAC module is required. The computational study was used to perform the parametric investigation into the defroster nozzle's performance with a full-scale model. The study highlights the drawbacks of current designs and points the way to improve passive defrosting mechanism. The results show that the current design of the defroster nozzles deliver the maximum airflow in the vicinity of the lower part of the windshield, which yields unsatisfactory visibility. Defrosting performance was excellent when the injection angle of the defrost nozzle was 45 degree. The numerical analysis satisfies the criteria provided by NHTSA.

Kinetics and Mechanism of the Anilinolysis of Ethylene Phosphorochloridate in Acetonitrile

  • Barai, Hasi Rani;Lee, Hai-Whang
    • Bulletin of the Korean Chemical Society
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    • v.32 no.12
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    • pp.4185-4190
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    • 2011
  • The nucleophilic substitution reactions of ethylene phosphorochloridate (1c) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at $5.0^{\circ}C$. The anilinolysis rate of 1c involving a cyclic five-membered ring is four thousand times faster than its acyclic counterpart (1a: diethyl chlorophosphate) because of great positive value of the entropy of activation of 1c (${\Delta}S^{\neq}=+30\;cal\;mol^{-1}K^{-1}$ compared to negative value of 1a (${\Delta}S^{\neq}=-45\;cal\;mol^{-1}K^{-1}$) over considerably unfavorable enthalpy of activation of 1c (${\Delta}H^{\neq}=27.7\;kcal\;mol^{-1}$) compared to 1a (${\Delta}H^{\neq}=8.3\;kcal\;mol^{-1}$). Great enthalpy and positive entropy of activation are ascribed to sterically congested transition state (TS) and solvent structure breaking in the TS. The free energy correlations exhibit biphasic concave upwards for substituent X variations in the X-anilines with a break point at X = 3-Me. The deuterium kinetic isotope effects are secondary inverse ($k_H/k_D$ < 1) with the strongly basic anilines and primary normal ($k_H/k_D$ > 1) with the weakly basic anilines and rationalized by the TS variation from a dominant backside attack to a dominant frontside attack, respectively. A concerted $S_N2$ mechanism is proposed and the primary normal deuterium kinetic isotope effects are substantiated by a hydrogen bonded, four-center-type TS.

Study on the Cooling Mechanism in a Cryogenic Cooling System (극저온 냉각 챔버 내 냉각 메커니즘 연구)

  • SEONGWOO LEE;YOUNGSANG NA;YOUNGKYUN KIM;SEUNGMIN JEON;JUNHO LEE;SUNGWOONG CHOI
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.146-151
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    • 2024
  • The demand for research on materials with excellent cryogenic strength and ductility has been increasing, particularly for applications such as liquid hydrogen (20 K) storage tanks. To effectively utilize liquid hydrogen, a system capable of maintaining and operating at 20 K is essential. Therefore, preliminary research and verification of the cooling system are crucial. In this study, a heat transfer analysis was conducted on a cooling system to meet the cryogenic environment requirements for cryogenic hydrogen chamber, which are conducted at liquid helium temperatures (4 K). The cooling mechanism in a helium cooling system was examined using numerical analysis. The numerical cooling trends were compared with experimentally obtained cooling results. The good agreement between numerical and experimental results suggests that the numerical approach developed in this study is applicable over a wide range of cryogenic systems.

Computational and Experimental Study of Grain Growth in WC-Co and WC-VC-Co Cemented Carbides

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.19 no.11
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    • pp.588-595
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    • 2009
  • The knowledge of grain growth of carbide particles is very important for manufacturing micrograined cemented carbides. In the present study, continuous and discontinuous grain growth in WC-Co and WC-VC-Co cemented carbides is investigated using the Monte Carlo computer simulation technique. The Ostwald ripening process (solution/re-precipitation) and the grain boundary migration process are assumed in the simulation as the grain growth mechanism. The effects of liquid phase fraction, grain boundary energy and implanted coarse grain are examined. At higher liquid phase content, mass transfer via solid/liquid interfaces plays a major role in grain growth. Growth rate of the implanted grain was higher than that of the matrix grains through solution/re-precipitation and coalescence with neighboring grains. The results of these simulations qualitatively agree with experimental ones and suggest that distribution of liquid phase and carbide particle/carbide grain boundary energy as well as contamination by coarse grain are important factors controlling discontinuous grain growth in WC-Co and WC-VC-Co cemented carbides. The contamination by coarse grains must by avoided in the manufacturing process of fine grain cemented carbides, especially with low Co.