• Title/Summary/Keyword: energy storage properties

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A Study on electron beam veldability of 9%Ni steels (III) - Microstructures and mechanical properties of welded joints - (9%Ni 강의 전자빔 용접성에 관한 연구 (III) - 전자빔 용접부 기계적 특성과 조직 -)

  • 김숙환;강정윤
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.116-125
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    • 1997
  • Electron beam weldability of 9%Ni steels has been investigated to apply EBW to the construction of LNG storage tank. While mechanical properties of welded joints were satisfied by ASTM specification, impact energy of weld metal was as low as 27 - 55J at $-196^{\circ}C$. As the result of Ni wires inserted at the joint to be welded, Ni content of weld metal was increased to about 10%, resulting on the improvement of impact toughness to 110 ~ 120J at $-196^{\circ}C$. This improvement of impact toughness in weld metal was due to the formation of tempered martensite and retained austenite. Above results indicate that, if Ni content of weld metal was increased about 10% by Ni wires addition, electron beam welded 9%Ni steels weld metal had sufficient impact energy necessary for a LNG storage tank.

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The Changes of Hydrogenation Properties of LaNi5 alloy by Hydrogen Charging Condition (수소주입조건 변화에 따른 LaNi5합금의 특성변화)

  • Ahn, Hyo-Jun
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.33-39
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    • 1994
  • The changes of hydrogenation properties of $LaNi_5$ by hydrogen charging condition were investigated using the P-C-isotherm curves, DSC(Differential Scanning Calorimetry), GC(Gas Chromatograph), X-ray diffractometer. As a results of static hydrogen charging, the hydrogen storage capacity gradually decreased and the plateau region severly slopped. Most of the degraded properties could be restored by the annealing treatment. The degradation of hydrogen storage capacity was related with the formation of stable hydride, which was not dehydrided at room temperature.

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Heat and Mass Transfer Properties of Mm-Based Metal Hydride upon Co Content (Mm계 금속수소화물의 Co함량에 따른 열 및 물질전달특성)

  • Park, Chan-kyo
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.2
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    • pp.144-151
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    • 2004
  • The effect of the cobalt content on the thermodynamic and, heat and mass transfer properties of the $MmNi_{5-y}B_{y-z}C_z(y=0.5{\sim}1.5,\;z=0.5)$hydrogen storage alloys has been studied systematically. The P-C isotherms curves show that with increasing cobalt content in the alloys, the plateau pressure of the hydrogen absorption and desorption and enthalpy(${\Delta}H$) increases steeply and the plateau region becomes flat, while entropy(${\Delta}S$) decreases. Also at the constant cobalt content the hydrogen transfer rate decreases with the reaction temperature, while the initial reaction kinetics increases. But the initial reaction with hydrogen completes within 1min, although the reaction proceeds about 30minutes thereafter.

Synthesis and Properties of Sulfonated Poly (Arylene Ether Sulfone) Block Copolymers with Naphthalene Moiety for Polymer Electrolyte Fuel Cells (고분자 전해질형 연료전지용 나프탈렌 부분을 갖는 술폰화된 폴리(아릴렌 이써 설폰) 블록 공중합체의 합성과 특성연구)

  • HAN, DASOM;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.4
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    • pp.331-338
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    • 2018
  • In this study, sulfonated PAES block copolymers have been synthesized via nucleophilic substitution reaction. Hydrophobic oligomer was prepared using 2,6-dihydroxynaphthalene and bis(4-chlorophenyl) sulfone, whereas hydrophilic oligomer was prepared using sulfonated bis(4-chlorophenyl) sulfone and bis(4-hydroxyphenyl) sulfone. The chemical structure of polymers was analyzed by $^1H$ NMR, FT-IR and GPC. The thermal properties of polymers were measured by TGA and DSC. The oxidative stability of membranes was investigated by Fenton's test. Furthermore, the proton conductivity of membrane was found to be 26 mS/cm at $90^{\circ}C$. All physiochemical properties suggest that fabricated membrane have a great potential for applications in PEMFC.

Magnetic properties of thin films of a magnetocaloric material FeRh

  • Jekal, Soyoung;Kwon, Oryong
    • Proceeding of EDISON Challenge
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    • 2013.04a
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    • pp.294-298
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    • 2013
  • A FeRh alloy is a well-known efficient magnetocaloric material and some experimental and theoretical studies of bulk FeRh have been reported already by several groups. In this study we report first-principles calculations on magnetic properties of different thickness FeRh thin films in order to investigate the possibility to enhance further the magnetocaloric efficiency. We used two methods of a Vienna Ab-initio Simulation Package (VASP) code and SIESTA package. We found that the FeRh thin films have quite different magnetic properties from the bulk when the thickness is thinner than 6-atomic-layers. While bulk FeRh has a G-type antiferromagnetic(AFM) state, thin films which are thinner than 6-atomic-layers have an A-type AFM state or a ferromagnetic (FM) state. We will discuss possibility of magnetic phase transitions of the FeRh thin films in the view point of a magnetocaloric effect. And we found 4-, 5-, 6-layers films with Fe surface and 7-layers film with Rh surface are FM and they have relatively small magnetocrystalline anisotropy (MCA) energy about less than 70 meV. The small MCA energy leads to reduction of the strength of magnetic field in operating a magnetic refrigerator.

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Membrane-Based Carbon Dioxide Separation Process for Blue Hydrogen Production (블루수소 생산을 위한 이산화탄소 포집용 2단 분리막 공정 최적화 연구)

  • Jin Woo Park;Joonhyub Lee;Soyeon Heo;Jeong-Gu Yeo;Jaehoon Shim;Jinhyuk Yim;Chungseop Lee;Jin Kuk Kim;Jung Hyun Lee
    • Membrane Journal
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    • v.33 no.6
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    • pp.344-351
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    • 2023
  • The membrane separation process for carbon dioxide capture from hydrogen reformer exhaust gas has been developed. Using a commercial membrane module, a multi-stage process was developed to achieve 90% of carbon dioxide purity and 90% of recovery rate for ternary mixed gas. Even if a membrane module with being well-known properties such as material selectivity and permeability, the process performance of purity and recovery widely varies depending on the stage-cut, the pressure at feed and permeate side. In this study, we verify the limits of capture efficiency at single-stage membrane process under various operating conditions and optimized the two-stage recovery process to simultaneously achieve high purity and recovery rate.

Functional Properties of Stand-alone Microgrid EMS Application (에너지 자립섬 EMS 어플리케이션의 기능적 특성)

  • Lee, Ha-Lim;Chun, Yeong-Han;Chae, Wookyu;Park, Jungsung
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.1
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    • pp.115-119
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    • 2016
  • For many past years, research in the operation of stand-alone Microgrid, which provides electric power generated from renewable energy sources and energy storage system instead of diesel generators, has been a major issue in order to prepare the exhaustion of fossil fuel and to protect environment, in island grids. Samso Island, known as the world's first stand-alone Microgrid in Denmark, is connected to the mainland grid through AC system, which has different technical conditions with Korea's isolated power system. Korea's first stand-alone Microgrid has been built in Ga-sa island, Chun-la-nam-do, based on Energy Management System (EMS) operation, and other islands are under construction to follow the next step. These stand-alone Microgrid's has large capacity of Battery Energy Storage System (BESS) and the proportion of the renewable energy sources are large, which makes it necessary to use a Microgrid-Energy Management System (MG-EMS) to operate the grid effectively and economically. However, since the main subject of MG-EMS is different from EMS, specific characteristics and functions must be different as well. In this paper, the necessary characteristics and functions are explained for a general MG-EMS compared to a large power system EMS.