• Journal of Welding and Joining
• /
• 제15권4호
• /
• pp.116-125
• /
• 1997

Electron beam weldability of 9%Ni steels has been investigated to apply EBW to the construction of LNG storage tank. While mechanical properties of welded joints were satisfied by ASTM specification, impact energy of weld metal was as low as 27 - 55J at $-196^{\circ}C$. As the result of Ni wires inserted at the joint to be welded, Ni content of weld metal was increased to about 10%, resulting on the improvement of impact toughness to 110 ~ 120J at $-196^{\circ}C$. This improvement of impact toughness in weld metal was due to the formation of tempered martensite and retained austenite. Above results indicate that, if Ni content of weld metal was increased about 10% by Ni wires addition, electron beam welded 9%Ni steels weld metal had sufficient impact energy necessary for a LNG storage tank.

• 한국수소및신에너지학회논문집
• /
• 제5권1호
• /
• pp.33-39
• /
• 1994

The changes of hydrogenation properties of $LaNi_5$ by hydrogen charging condition were investigated using the P-C-isotherm curves, DSC(Differential Scanning Calorimetry), GC(Gas Chromatograph), X-ray diffractometer. As a results of static hydrogen charging, the hydrogen storage capacity gradually decreased and the plateau region severly slopped. Most of the degraded properties could be restored by the annealing treatment. The degradation of hydrogen storage capacity was related with the formation of stable hydride, which was not dehydrided at room temperature.

• 한국수소및신에너지학회논문집
• /
• 제15권2호
• /
• pp.144-151
• /
• 2004

The effect of the cobalt content on the thermodynamic and, heat and mass transfer properties of the $MmNi_{5-y}B_{y-z}C_z(y=0.5{\sim}1.5,\;z=0.5)$hydrogen storage alloys has been studied systematically. The P-C isotherms curves show that with increasing cobalt content in the alloys, the plateau pressure of the hydrogen absorption and desorption and enthalpy(${\Delta}H$) increases steeply and the plateau region becomes flat, while entropy(${\Delta}S$) decreases. Also at the constant cobalt content the hydrogen transfer rate decreases with the reaction temperature, while the initial reaction kinetics increases. But the initial reaction with hydrogen completes within 1min, although the reaction proceeds about 30minutes thereafter.

• 한국수소및신에너지학회논문집
• /
• 제29권4호
• /
• pp.331-338
• /
• 2018

In this study, sulfonated PAES block copolymers have been synthesized via nucleophilic substitution reaction. Hydrophobic oligomer was prepared using 2,6-dihydroxynaphthalene and bis(4-chlorophenyl) sulfone, whereas hydrophilic oligomer was prepared using sulfonated bis(4-chlorophenyl) sulfone and bis(4-hydroxyphenyl) sulfone. The chemical structure of polymers was analyzed by $^1H$ NMR, FT-IR and GPC. The thermal properties of polymers were measured by TGA and DSC. The oxidative stability of membranes was investigated by Fenton's test. Furthermore, the proton conductivity of membrane was found to be 26 mS/cm at $90^{\circ}C$. All physiochemical properties suggest that fabricated membrane have a great potential for applications in PEMFC.

• EDISON SW 활용 경진대회 논문집
• /
• 제2회(2013년)
• /
• pp.294-298
• /
• 2013

A FeRh alloy is a well-known efficient magnetocaloric material and some experimental and theoretical studies of bulk FeRh have been reported already by several groups. In this study we report first-principles calculations on magnetic properties of different thickness FeRh thin films in order to investigate the possibility to enhance further the magnetocaloric efficiency. We used two methods of a Vienna Ab-initio Simulation Package (VASP) code and SIESTA package. We found that the FeRh thin films have quite different magnetic properties from the bulk when the thickness is thinner than 6-atomic-layers. While bulk FeRh has a G-type antiferromagnetic(AFM) state, thin films which are thinner than 6-atomic-layers have an A-type AFM state or a ferromagnetic (FM) state. We will discuss possibility of magnetic phase transitions of the FeRh thin films in the view point of a magnetocaloric effect. And we found 4-, 5-, 6-layers films with Fe surface and 7-layers film with Rh surface are FM and they have relatively small magnetocrystalline anisotropy (MCA) energy about less than 70 meV. The small MCA energy leads to reduction of the strength of magnetic field in operating a magnetic refrigerator.

• 멤브레인
• /
• 제33권6호
• /
• pp.344-351
• /
• 2023

본 연구에서는 중공사형 이산화탄소 분리막 모듈을 사용하여 수소개질기 배가스로부터 이산화탄소 포집을 목적으로 한 분리막 공정 최적화 연구를 진행하였다. 랩스케일의 소형 분리막 모듈을 사용하여 혼합기체를 대상으로 이산화탄소 순도 90% 및 회수율 90%을 달성하는 2단 공정 조건을 도출하였다. 막 면적이 정해진 모듈의 분리막 공정에서는 스테이지-컷, 주입부 및 투과부 압력에 따라서 포집 순도 및 회수율이 모두 다르게 나타나기 때문에 운전 조건에 대한 최적화가 필수적이다. 본 연구에서는 다양한 운전 조건에서 1단 분리막에서 보이는 공정 포집 효율의 한계를 확인하고, 높은 순도와 회수율을 동시에 달성하기 위한 2단 회수 공정을 최적화하였다.

• KEPCO Journal on Electric Power and Energy
• /
• 제2권1호
• /
• pp.115-119
• /
• 2016

For many past years, research in the operation of stand-alone Microgrid, which provides electric power generated from renewable energy sources and energy storage system instead of diesel generators, has been a major issue in order to prepare the exhaustion of fossil fuel and to protect environment, in island grids. Samso Island, known as the world's first stand-alone Microgrid in Denmark, is connected to the mainland grid through AC system, which has different technical conditions with Korea's isolated power system. Korea's first stand-alone Microgrid has been built in Ga-sa island, Chun-la-nam-do, based on Energy Management System (EMS) operation, and other islands are under construction to follow the next step. These stand-alone Microgrid's has large capacity of Battery Energy Storage System (BESS) and the proportion of the renewable energy sources are large, which makes it necessary to use a Microgrid-Energy Management System (MG-EMS) to operate the grid effectively and economically. However, since the main subject of MG-EMS is different from EMS, specific characteristics and functions must be different as well. In this paper, the necessary characteristics and functions are explained for a general MG-EMS compared to a large power system EMS.

• 한국광과학회:학술대회논문집
• /
• 한국광과학회 1999년도 학술대회지
• /
• pp.20-21
• /
• 1999

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2010년도 춘계학술대회 논문집
• /
• pp.1101-1102
• /
• 2010

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2009년도 춘계학술대회 논문집
• /
• pp.791-792
• /
• 2009