• Title/Summary/Keyword: energy degradation

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Enhancement of Electrolyte Properties for High Energy Density Supercapacitors by using Additive Materials

  • Kim, Cheong;Habazaki, Hiroki;Park, Soo Gil
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.214-217
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    • 2016
  • In this study, we studied the enhancement of the energy densities of electrochemical capacitors by improving the working voltage range of the electrolyte. To prevent the decomposition of the electrolyte, stable SEI layers were formed by reductive degradation of additive materials such as fluoro-ethylene carbonate (FEC) and vinyl ethylene carbonate (VEC) before degradation of the base electrolyte. As a result, the solution resistance (Rs) of EC:DMC + SL 20 % + VEC 1 % electrolytes observed 1.47 Ω and the charge transfer resistance (Rct) was 2.64 Ω at the open circuit voltage. Additionally, a cycle retention of 94 % was observed for EC:DMC + SL 20 % + VEC 1 % after 500 cycles at 3.5 V.

Characteristics of Hydrogen Storage Alloy powder Compacts Using Polymer Binders (고분자 결합제를 이용한 수소저장합금 분말 성형체의 특성)

  • Kim, Chan-Jung;Kim, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.2
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    • pp.81-89
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    • 1999
  • Various characteristics - mechanical propertis, thermal cyclic hydriding characteristics and resistance to degradation by $H_2O$, CO in hydrogen - of hydrogen storage alloy powder compacts using PTFE and silicon sealant as a polymer binder were studied. Diametral tensile strength of 10wt% PTFE and 5wt% silicon sealant added compacts showed relatively high value of $4kg/cm^2$ and $10kg/cm^2$, respectively. Compacts show a good resistance to degradation by $H_2O$ in hydrogen. But hydrogen absorption rate and capacity of compacts were decreased by CO in hydrogen with the number of cycles. Cu coated and PTFE bonded compacts showed very small decrease of capacity and a good strength even after 1000 cycles of thermal hydriding and dehydriding.

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Degradation of Gate Induced Drain Leakage(GIDL) Current of p-MOSFET along to Analysis Condition (분석 조건에 따른 p-MOSFET의 게이트에 유기된 드레인 누설전류의 열화)

  • 배지철;이용재
    • Electrical & Electronic Materials
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    • v.10 no.1
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    • pp.26-32
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    • 1997
  • The gate induced drain leakage(GIDL) current under the stress of worse case in -MOSFET's with ultrathin gate oxides has been measured and characterized. The GIDL current was shown that P-MOSFET's of the thicker gate oxide is smaller than that of the thinner gate oxide. It was the results that the this cur-rent is decreased with the increamental stress time at the same devices.It is analyzed that the formation components of GIDL current are both energy band to band tunneling at high gate-drain voltage and energy band to defect tunneling at low drain-gate voltage. The degradations of GIDL current was analyzed the mechanism of major role in the hot carriers trapping in gate oxide by on-state stress.

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A Study of Upgrading Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste with Film Type - The Influence of Catalyst Amount and Reaction Temperature (필름형 혼합폐플라스틱의 열분해로부터 얻은 왁스오일의 고급화연구 - 촉매 양과 반응온도의 영향 -)

  • Lee, Kyong-Hwan;Song, Kwang-Sup;Nam, Ki-Yun
    • New & Renewable Energy
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    • v.5 no.4
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    • pp.52-58
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    • 2009
  • Upgrading of pyrolysis wax oil using HZSM-5 catalyst has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation was studied with a function of catalyst amount and reaction temperature. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The catalytic degradation using HZSM-5 catalyst shows the high conversion of pyrolysis wax oil to light hydrocarbons. The liquid product obtained shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Here, the experimental variable such as catalyst amount and reaction temperature was influenced on the product distribution.

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Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Plasma-Enhanced Atomic Layer-Deposited Ultra-Thin Electrolyte (플라즈마 원자층증착 초박막전해질 수소 세라믹연료전지의 초기성능 저하)

  • JI, SANGHOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.340-346
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte fabricated by plasma-enhanced atomic layer deposition method was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~52% for 30 min, which continually decreased as time increased but degradation rate gradually decreased. The open circuit voltage ratio decreased with respect time; however, its behavior was evidently different from the reduction behavior of the peak power density. The activation resistance ratio increased as ~127% for 30 min, which was almost similar with the reduction behavior of the peak power density ratio.

Comparison of Acetaminophen Degradation Performance using Advanced Oxidation Process (고급산화공정을 이용한 아세트아미노펜 분해 성능 비교)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.31 no.4
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    • pp.319-328
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    • 2022
  • This study investigated the treatment of acetaminophen in municipal wastewater by conventional ozonation, ozone-based advanced oxidation, ozone/UV, and the electro-peroxone process. The ozone/UV process and electro-peroxone process of electric power consumption increased 1.25 and 2.04 times, respectively, compared to the ozone process. The pseudo-steady OH radical concentration was the greatest in the electro-peroxone process and lowest in the ozone process. The specific energy consumption for TOC decomposition of the ozone/UV process and electro-peroxone process were 22.8% and 15.5% of the ozone process, respectively. Results suggest that it is advantageous in terms of degradation performance and energy consumption to use a combination of processes in municipal wastewater treatment, rather than an ozone process alone. In combination with the ozone process, the electrolysis process was found to be more advantageous than the UV process.

Characterization of a Commercial Black Chrome Solar Coating (상업용 Black Chrome 태양선택 흡수면의 특성)

  • Lee, K.D.;Chea, Y.H.;Auh, P.C.
    • Solar Energy
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    • v.7 no.2
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    • pp.65-73
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    • 1987
  • Microstructural basis for the thermal degradation of electrodeposited black chrome "solar-L-foil" heated in air has been investigated using scanning electron microscopy, energy dispersive x-ray analysis, X-ray diffraction techniques and UV-VIS-NIR spectre-photometer. Experimental result, the change in the shape of the particle comprising the film from their initial needle like structure to a more spherical shape with an oxide after 1hr annealing at $600^{\circ}C$ has been observed. The effect is to degrade solar absorptance of the thin film.

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Phenolic Composition, Fermentation Profile, Protozoa Population and Methane Production from Sheanut (Butryospermum Parkii) Byproducts In vitro

  • Bhatta, Raghavendra;Mani, Saravanan;Baruah, Luna;Sampath, K.T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.10
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    • pp.1389-1394
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    • 2012
  • Sheanut cake (SNC), expeller (SNE) and solvent extractions (SNSE) samples were evaluated to determine their suitability in animal feeding. The CP content was highest in SNSE (16.2%) followed by SNE (14.7%) and SNC (11.6%). However, metabolizable energy (ME, MJ/kg) was maximum in SNC (8.2) followed by SNE (7.9) and SNSE (7.0). The tannin phenol content was about 7.0 per cent and mostly in the form of hydrolyzable tannin (HT), whereas condensed tannin (CT) was less than one per cent. The in vitro gas production profiles indicated similar y max (maximum potential of gas production) among the 3 by-products. However, the rate of degradation (k) was maximum in SNC followed by SNE and SNSE. The $t^{1/2}$ (time taken for reaching half asymptote) was lowest in SNC (14.4 h) followed by SNE (18.7 h) and SNSE (21.9 h). The increment in the in vitro gas volume (ml/200 mg DM) with PEG (polyethylene glycol)-6000 (as a tannin binder) addition was 12.0 in SNC, 9.6 in SNE and 11.0 in SNSE, respectively. The highest ratio of $CH_4$ (ml) reduction per ml of the total gas, an indicator of the potential of tannin, was recorded in SNE (0.482) followed by SNC (0.301) and SNSE (0.261). There was significant (p<0.05) reduction in entodinia population and total protozoa population. Differential protozoa counts revealed that Entodinia populations increased to a greater extent than Holotricha when PEG was added. This is the first report on the antimethanogenic property of sheanut byproducts. It could be concluded that all the three forms of SN byproducts are medium source of protein and energy for ruminants. There is a great potential for SN by-products to be incorporated in ruminant feeding not only as a source of energy and protein, but also to protect the protein from rumen degradation and suppress enteric methanogenesis.

IAQ improvement effect analysis in Dynamic Breathing Building(DBB) (숨쉬는 벽체를 적용한 건물에서의 실내공기질(IAQ) 개선 효과 분석)

  • Park, Yong-Dai;Lee, Jin-Sook;Kang, Eun-Chul;Lee, Euy-Joon
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.748-753
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    • 2008
  • In modern buildings, the air-tightness and insulation for energy saving resulted in degradation of Indoor Air Quality(IAQ). It has brought out new diseases such as New Building Syndrome(NBS) and Sick Building Syndrome(SBS) to the tenants of such buildings. As a result, researches on the Dynamic Breathing Building(DBB) are being undertaken to minimize energy loss as well as to improve IAQ. DBB is a state-of-the-art technology to build channels inside the wall so that air migrates between indoor and outdoor, which improves insulation performance and IAQ. This study attempts to evaluate the improvement of DBB employed in real buildings. As analyzing tools, IAQ improvement and particle degradation while were evaluated while the required indoor ventilation rate was satisfied. DBB were installed in the twin test cells at Korea Institute of Energy Research(KIER). From the test, IAQ was compared with outdoor air base on the concentration of particle matter(PM10). As a results, the concentration of particle dust (PM10) within the breathing walls was reduced by 80% at 0.7 ACH, 67% at 2 ACH, 63% at 3 ACH respectively. As ACH is higher, Dnamic Isulation(DI) and normal wall permit more PM10 particles being infiltrated.

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Photocatalytic Properties of WO3 Thin Films Prepared by Electrodeposition Method (전기증착법으로 제조된 WO3 박막의 광촉매 특성)

  • Kang, Kwang-Mo;Jeong, Ji-Hye;Lee, Ga-In;Im, Jae-Min;Cheon, Hyun-Jeong;Kim, Deok-Hyeon;Nah, Yoon-Chae
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.40-44
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    • 2019
  • Tungsten trioxide ($WO_3$) is a promising candidate as a photocatalyst because of its outstanding electrical and optical properties. In this study, we prepare $WO_3$ thin films by electrodeposition and characterize the photocatalytic degradation of methylene blue using these films. Depending on the voltage conditions (static and pulse), compact and porous $WO_3$ films are fabricated on a transparent ITO/glass substrate. The morphology and crystal structure of electrodeposited $WO_3$ thin films are investigated by scanning electron microscopy, atomic force microscopy, and X-ray diffraction. An application of static voltage during electrodeposition yields a compact layer of $WO_3$, whereas a highly porous morphology with nanoflakes is produced by a pulse voltage process. Compared to the compact film, the porous $WO_3$ thin film shows better photocatalytic activities. Furthermore, a much higher reaction rate of degradation of methylene blue can be achieved after post-annealing of $WO_3$ thin films.