• Title/Summary/Keyword: energetic crystals

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Birefringence effect of two directionally rubbed liquid crystal cells

  • Huang, Chi Yen;Huang, Yao Sheng;Tian, Jing Rui
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.446-449
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    • 2005
  • The alignment property of liquid crystals on the two-easy axes substrate is investigated. The two-easy axes substrate frustrates the orientation of the LCs next to the substrate, and hence influences the birefringence of the LC cell. Experimental findings reveal that the ratio of the rubbing strengths in the different rubbing directions and the cell thickness substantially influence the birefringence of the LC cell. The surface anchoring energetic competition between the different rubbing directions contributes to the observed results.

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Crystallization of Hydrazinium Nitroformate(HNF) as Eco-friendly Oxidizer (친환경 산화제 HNF 결정화 연구)

  • Kim, Jina;Kim, Min Jun;Min, Byoung Sun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.6
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    • pp.76-82
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    • 2016
  • Recently, environmental sustainability of the transitional explosives and propellants is an issue of growing importance in energetic materials. For examples, ammonium perchlorate(AP) as an solid propellants oxidizer could create a poisonous gas and atmospheric pollutions, such as HCl. Among the several oxidizers, hydrazinium nitroformate(HNF) is an effective candidate substance for eco-friendly oxidizer, which has high density, pressure index, and less smog generating property during combustion for the thrust control system. This study was controlled the size distribution and shapes through various conditions. Length and diameter ratio(L/D) of crystals has below 1 : 3, and the particle size was two types of $200{\mu}m$ and $50{\mu}m$.

Multiscale modeling of the anisotropic shock response of β-HMX molecular polycrystals

  • Zamiri, Amir R.;De, Suvranu
    • Interaction and multiscale mechanics
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    • v.4 no.2
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    • pp.139-153
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    • 2011
  • In this paper we develop a fully anisotropic pressure and temperature dependent model to investigate the effect of the microstructure on the shock response of ${\beta}$-HMX molecular single and polycrystals. This micromechanics-based model can account for crystal orientation as well as crystallographic twinning and slip during deformation and has been calibrated using existing gas gun data. We observe that due to the high degree of anisotropy of these polycrystals, certain orientations are more favorable for plastic deformation - and therefore defect and dislocation generation - than others. Loading along these directions results in highly localized deformation and temperature fields. This observation confirms that most of the temperature rise during high rates of loading is due to plastic deformation or dislocation pile up at microscale and not due to volumetric changes.

Process variables of gamma-type aluminum trihydride in wet chemical synthesis (감마형 삼수소 알루미늄 습식합성반응의 공정변수 연구)

  • Yang, Yo-Han;Kim, Woo-Ram;Gwon, Yoon-Ja;Park, Mi-Jeong;Kim, Jun-Hyung;Cho, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.1
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    • pp.214-222
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    • 2018
  • Alane(aluminum trihydride, $AlH_3$) is a candidate material involving high energetic capacity for solid propellant or explosives. In this study aluminum trihydride-etherate ($AlH_3{\cdot}(C_2H_5)_2O$) was synthesized through a wet process, and solid alane was extracted by controlled crystallization. Alane crystals were grown during the crystallization step with phase conversion of aluminum trihydride-etherate to alane using an anti-solvent. Stable crystal forms were found by a 2 hour crystallization process at $85^{\circ}C$. Finally the extracted solid aluminium trihydride consisted mainly of ${\gamma}-type$ with $50-100{\mu}m$ in size.