• Atmosphere
• /
• v.25 no.2
• /
• pp.221-233
• /
• 2015

Pollen is closely related to health issues such as allergenic rhinitis and asthma as well as intensifying atopic syndrome. Information on current and future spatio-temporal distribution of allergenic pollen is needed to address such issues. In this study, the Community Multiscale Air Quality Modeling (CMAQ) was utilized as a base modeling system to forecast pollen dispersal from oak trees. Pollen emission is one of the most important parts in the dispersal modeling system. Areal emission factor was determined from gridded areal fraction of oak trees, which was produced by the analysis of the tree type maps (1:5000) obtained from the Korea Forest Service. Daily total pollen production was estimated by a robust multiple regression model of weather conditions and pollen concentration. Hourly emission factor was determined from wind speed and friction velocity. Hourly pollen emission was then calculated by multiplying areal emission factor, daily total pollen production, and hourly emission factor. Forecast data from the KMA UM LDAPS (Korea Meteorological Administration Unified Model Local Data Assimilation and Prediction System) was utilized as input. For the verification of the model, daily observed pollen concentration from 12 sites in Korea during the pollen season of 2014. Although the model showed a tendency of over-estimation in terms of the seasonal and daily mean concentrations, overall concentration was similar to the observation. Comparison at the hourly output showed distinctive delay of the peak hours by the model at the 'Pocheon' site. It was speculated that the constant release of hourly number of pollen in the modeling framework caused the delay.

• Journal of Korean Society for Atmospheric Environment
• /
• v.23 no.E2
• /
• pp.57-65
• /
• 2007

In Korea, there is a general lack of information available on air emissions from industry. The reasons for this include the lack of regulatory requirements for emission monitoring, limited information on specific industries, and difficulties in monitoring certain sources. This paper presents the first detailed air pollutant emission factors from composite wood product manufacturing in Korea. This study introduced emission factors for wood-based panels such as plywood, particle board (PB), and medium density fiberboard (MDF). The emission factors of particulate matters (PM) and hazardous air pollutants (HAPs) from MDF were higher than that from other wood products. The concentration of total volatile organic compounds (TVOCs) for hot press from wood-based panels was higher than drying or gluing processes. Emissions data from NPIP were compared to the data from the suggested emission factors in this study and the US EPA's. The data from our emission factors were closer to the observed results than the data using the US EPA's emission factor.

• Journal of Environmental Health Sciences
• /
• v.36 no.2
• /
• pp.128-135
• /
• 2010

The main purpose of this study was to develop the greenhouse gas emission factor for power plant using sub-bituminous coal. In Korea, Fired power plant are a major source of greenhouse gases within the fossil fuel combustion sectors, thus the development of emission factors is necessary to understand the characteristics of the national specific greenhouse gas emission and to develop nation specific emission factors. These emission factors were derived from the $CO_2$ concentrations measurement from stack and fuel analysis of sub-bituminous coal. Caloric value of sub-bituminous coal used in the power plants were 5,264 (as received basis), 5,936 (air-dried basis) and 6,575 kcal/kg (dry basis). The C emission factors by fuel analysis and $CO_2$ concentration measurement was estimated to be 26.7(${\pm}0.9$), 26.3(${\pm}2.8$)tC/MJ, respectively. Our estimates of C emission factors were comparable with IPCC default value.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.34 no.3
• /
• pp.999-1006
• /
• 2014

$CO_2$ emission factor for earthwork equipment was made based on fuel consumption quantity using IPCC carbon emission factor. This is presented through the carbon emission estimating guideline each facilities by the Ministry of Land, Infrastructure and Transportation in 2011. However, this method has the defect which don't apply the various condition of site. Therefor it needs the new emission factor supplemented these defects. This study will tries to estimate $CO_2$ emission with the direct measurement method using concentration flow velocity measurement (C-FVM) for earth work equipment and present the new $CO_2$ emission factor for earth work equipment after compare with emission factor of the Ministry of Land, Infrastructure and Transportation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.13 no.4
• /
• pp.326-331
• /
• 2000

We have fabricated the field emitter arrays coated with diamond-like carbon (DLC) films that improved the field emission characteristics. The nitrogen doped DLC films are prepared by the filtered cathodic vacuum are (FCVA) tehnique. The activation energy of the nitrogen doped DLC films are derived from electrical conductivity measurements. The silicon field emission arrays (FEAs) were prepared by the VLSI technique. The turn-on field was rapidly decreasing and the emission current was remarkably increasing the DLC-coated FEAs than the non-coated silicon FEAs. In the nitrogen doped FEAs, the turn-on field decreased and the emission current increased with increasing the nitrogen found out the field emission current and the work function of the DLC-coated FEAs was remarkably decreased than that of the non-coated silicon FEAs. As nitrogen doping concentrations are increased the work function of FEAs is decreased and the field emission properties are improved in nitrogen doped DLC-coated FEAs. This phenomenon in due the fact that the Fermi energy level moves to the conduction band by increasing nitrogen doping concentration.

• Journal of Surface Science and Engineering
• /
• v.50 no.4
• /
• pp.282-288
• /
• 2017

$Eu^{3+}$- or $Sm^{3+}$-doped $La_2MoO_6$ phosphors were synthesized with different concentrations of activator ions via a solid-state reaction. The X-ray diffraction patterns exhibited that crystalline structures of all the phosphors were tetragonal systems with the dominant peak occurring at (103) plane, irrespective of the concentration and the type of activator ions. The crystallites showed the pebble-like crystalline shapes and the average crystallite size increased with a tendency to agglomerate as the concentration of $Eu^{3+}$ ions increased. The excitation spectra of $Eu^{3+}$-doped $La_2MoO_6$ phosphors contained an intense charge transfer band centered at 331 nm in the range of 250-370 nm and three weak peaks at 381, 394, and 415 nm, respectively, due to the $^7F_0{\rightarrow}^5L_7$, $^7F_0{\rightarrow}^5L_6$, and $^7F_0{\rightarrow}^5D_3$ transitions of $Eu^{3+}$ ions. The emission spectra under excitation at 331 nm exhibited a strong red band centered at 620 nm and two weak bands at 593 and 704 nm. As the concentration of $Eu^{3+}$ increased from 1 to 20 mol%, the intensities of all the emission bands gradually increased. For the $Sm^{3+}$-doped $La_2MoO_6$ phosphors, the emission spectra consisted of an intense emission band at 607 nm arising from the $^4G_{5/2}{\rightarrow}^6H_{7/2}$ transition and three relatively small bands at 565, 648, and 707 nm originating from the $^4G_{5/2}{\rightarrow}^6H_{5/2}$, $^4G_{5/2}{\rightarrow}^6H_{9/2}$, and $^4G_{5/2}{\rightarrow}^6H_{11/2}$ transitions of $Sm^{3+}$, respectively. The intensities of all the emission bands approached maxima when concentration of $Sm^{3+}$ ions was 5 mol%. These results indicate that the optimum concentrations for highly-luminescent red and orange emission are 20 mol% of $Eu^{3+}$ and 5 mol% of $Sm^{3+}$ ions, respectively.

• Fire Science and Engineering
• /
• v.23 no.5
• /
• pp.24-31
• /
• 2009

Based on fallen leaves of major Korean conifer species 'Pinus densiflora' and major Korean broadleaved species 'Quercus variabilis', this study sought to identify combustion emission gas types and measure their concentration by means of FTIR (Fourier Transform Infrared) spectrometer. As a result, it was found that there were total 13 types of combustion gas detected from fallen leaves of Pinus densiflora and Quercus variabilis, such as carbon monoxide, carbon dioxide, acetic acid, butyl acetate, ethylene, methane, methanol, nitrogen dioxide, ammonia, hydrogen fluoride, sulfur dioxide and hydrogen bromide. Notably, nitrogen monoxide was additionally detected from fallen leaves of Quercus variabilis. It was found that the overall concentration of combustion gas emitted from the fallen leaves of Pinus densiflora was 4.5 times higher than that from fallen leaves of Quercus variabilis. Particularly, it was found that emission concentration of some combustion emission gas types like carbon monoxide, carbon dioxide and butyl acetate exceeded the upper limit of their time-weighted average (TWA, ppm), while the emission concentration of carbon monoxide and carbon dioxide exceeded their short-term exposure limit (STEL, ppm) for both species. Thus, it was found that carbon monoxide and carbon dioxide have higher hazard to health than other gas types, because these two gas types account for higher than 99% of overall gas emission due to combustion of surface fire starting from litter layer in forest.

• Journal of Environmental Science International
• /
• v.15 no.6
• /
• pp.601-606
• /
• 2006

The coal gasification fuel is important to replace petroleum fuel. Also they have many benefits for reducing the air pollution. Measurements on the combustion characteristics of synthetic gas from coal gasification have been conducted as compared with LPG in constant volume combustion chamber. The fuel is low caloric synthetic gas containing carbon monoxide 30%, hydrogen 20%, carbon dioxide 5%, and nitrogen 45%. To elucidate the combustion characteristics of the coal gasification fuel, the combustion pressures, combustion durations, and pollutants(NOx, $CO_2$, CO) are measured with equivalence ratios($\phi$), and initial pressures of fuel-air mixture in constant volume chamber. In the case of the coal gasification fuel, maximum combustion pressure and NOx concentration are lower rather than LPG fuel. However CO and $CO_2$ emission concentration are similar to that of LPG fuel.

• Journal of Environmental Impact Assessment
• /
• v.19 no.1
• /
• pp.59-74
• /
• 2010

The trend of the PM10 concentrations in the Seoul Metropolitan Area (SMA) is reviewed and relative contributions of major contributors (paved road emissions and long-range transport from outside the SMA) are discussed. It was shown that the PM10 concentrations in the SMA have generally decreased except Incheon between 1999 and 2005. Further, it was identified that the difference of the PM10 mass concentration between the roadside stations and urban ambient stations has decreased between 2004 and 2008. Based on the emission estimates, it was suggested that the reduction of resuspension of aerosols on the road is the major reason for that. Based on the modeling results, it was identified that outside effects be about 30% of the ambient PM10 concentration in the SMA. Further research and policy issues to identify major sources of PM10 in the SMA are discussed.

• Journal of Korean Society for Atmospheric Environment
• /
• v.13 no.3
• /
• pp.221-229
• /
• 1997

Wax is a protectant for floors that is used widely in Korea and is considered an emission source of volatile organic compounds (VOCs) in the indoor environment. This study examined the concentration change of indoor VOCs due to waxing and also due to wiping the floor with an oiled dustcloth. VOCs were identified using a cryogenic concentration/thermal desorption system with capillary GC that utilized a liquid nitrogen cryostat and induction heating. The major components emitted from the waxing were nonane, decane, undecane, $C_2$-benzene, and $C_3$-benzene. The concentrations of nonane were 1,276 $\mu\textrm{g}$/㎥ an hour after wax applications, 832 $\mu\textrm{g}$/㎥ after 3 days, and less than 10$\mu\textrm{g}$/㎥) after 15 days. Another emission source of VOCs in indoor was the oiled dustcloth used for cleaning the floor. The oiled dustcloth gave VOCs concentrations three times higher than the normal undusted floor.