• Title/Summary/Keyword: elemental technology

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Ionic-additive Crosslinked Polymeric Sulfur Composites as Cathode Materials for Lithium-Sulfur Batteries

  • Seong, Min Ji;Manivannan, Shanmugam;Kim, Kyuwon;Yim, Taeeun
    • Journal of Electrochemical Science and Technology
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    • v.12 no.4
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    • pp.453-457
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    • 2021
  • Lithium-sulfur (Li-S) batteries are one of attractive energy conversion and storage system based on high theoretical specific capacity and energy density with low costs. However, volatile nature of elemental sulfur is one of critical problem for their practical acceptance in industry because it considerably affects electrode uniformity during electrode manufacturing. In this work, polymeric sulfur composite consisting of ionic liquid (IL) are suggested to reduce volatility nature of elemental sulfur, resulting in better processibility of the Li-S cell. According to systematic spectroscopic analysis, it is found that polymeric sulfur is consisting of repeating units combining with elemental sulfur and volatility of them is negligible even at high temperature. In addition, the IL-embedded polymeric sulfur shows moderate cycle performance compared to the cell with elemental sulfur. From these results, it is found that the IL-embedded polymeric sulfur composite is applicable cathode candidate for the Li-S cell based on their excellent non-volatility as well as their superior electrochemical performance.

A STUDY ON KOREAN ANTHRACITE BY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS

  • Kim, N.B.;Woo, H.J.;Lee, K.Y.;Hong, W.;Chun, S.K.;Park, K.S.
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.477-482
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    • 1994
  • By the instrumental neutron activation analysis using two comparators of gold and cobalt, 31 elements have been anlalyzed in anthracites collected from two main coal-fields in Korea. The average concentrations and ranges of the elements were obtained with the elemental difference between two coal-fields. The trends of rare-earth elemental distribution and vertical elemental distribution are also given.

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A high-stability neutron generator for industrial online elemental analysis

  • Xiang-quan Chen;Lei Xiong;Hui Xie;Jing-fu Guo;Xue-ming Zhang;Yong-jun Dong
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1441-1453
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    • 2024
  • The yield stability of the neutron generator directly affects the accuracy of elemental analysis. This paper presents an industrial fully automatic neutron generator with a 48 mm neutron tube based on PLC to improve the stability and reliability of the neutron generator in industrial applications. By integrating a Kalman Filter with the PID algorithm in a PLC, the neutron yield of the generator is remarkably stabilized, achieving 1 × 108n/s. The neutron generator has been employed for industrial online elemental analysis. The results demonstrate that only a slight fluctuation of ±0.82 % exists in the neutron yield, and the reproducibility of the generator holds at a significant level of 0.05. This improved neutron generator can be applied to the online bulk analysis of carbon in coal-fired power stations and absolute measurement of neutron source emission rate.

Removal of Gaseous Elemental Mercury Using Reactive Species Produced by Dielectric Barrier Discharge (저온 플라즈마 반응에 의해 생성된 반응활성종을 이용한 원소상 수은의 제거)

  • Jeong, Ju-Young;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.15 no.5
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    • pp.479-484
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    • 2006
  • Removal of elemental mercury $(Hg^0)$ with the reactive species produced from dielectric barrier discharge (DBD) was studied. We investigated the effect of operating parameters such as the applied voltage, residence time, initial concentration and co-existence of other pollutants. The removal of $(Hg^0)$ was significantly promoted by an increase in the applied voltage of the DBD reactor system. It is important to note that at the same input power, the removal efficiency of $(Hg^0)$ was much higher than that of NO gas. These results imply that if the DBD system is used as a NOx treatment facility, it is capable of removing $(Hg^0)$ simultaneously with NOx.

A Study on Elemental Technology Identification of Sound Data for Audio Forensics (오디오 포렌식을 위한 소리 데이터의 요소 기술 식별 연구)

  • Hyejin Ryu;Ah-hyun Park;Sungkyun Jung;Doowon Jeong
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.34 no.1
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    • pp.115-127
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    • 2024
  • The recent increase in digital audio media has greatly expanded the size and diversity of sound data, which has increased the importance of sound data analysis in the digital forensics process. However, the lack of standardized procedures and guidelines for sound data analysis has caused problems with the consistency and reliability of analysis results. The digital environment includes a wide variety of audio formats and recording conditions, but current audio forensic methodologies do not adequately reflect this diversity. Therefore, this study identifies Life-Cycle-based sound data elemental technologies and provides overall guidelines for sound data analysis so that effective analysis can be performed in all situations. Furthermore, the identified elemental technologies were analyzed for use in the development of digital forensic techniques for sound data. To demonstrate the effectiveness of the life-cycle-based sound data elemental technology identification system presented in this study, a case study on the process of developing an emergency retrieval technology based on sound data is presented. Through this case study, we confirmed that the elemental technologies identified based on the Life-Cycle in the process of developing digital forensic technology for sound data ensure the quality and consistency of data analysis and enable efficient sound data analysis.

Reaction Characteristics of Elemental and Oxidized Mercury with Fly Ash Components (비산재 성분과 원소 및 산화수은의 반응특성)

  • Lee, Sang-Sup;Kim, Kwang-Yul;Oh, Kwang-Joong;Jeon, Jun-Min;Kang, Dong-Chang
    • Clean Technology
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    • v.19 no.4
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    • pp.453-458
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    • 2013
  • Fly ash has capacity to oxidize or adsorb mercury in a flue gas. Mercury oxidation and adsorption efficiencies of fly ash vary depending on the properties of fly ash. This study was designed to understand reaction characteristics of mercury with fly ash components. The fly ash components were tested to determine their oxidation and adsorption capabilities for elemental mercury and oxidized mercury. A sample was synthesized with fly ash components and tested. The test results were compared with those of the fly ash sample obtained from a coal-fired power plant. $Fe_2O_3$, CuO and carbon black showed higher oxidation or adsorption efficiency for elemental mercury while CaO, MgO, CuO and carbon black showed higher adsorption efficiency for mercury chloride. In addition, the synthesized sample showed comparable mercury oxidation and adsorption efficiencies to the fly ash sample.

Vibroacoustic response of thin power law indexed functionally graded plates

  • Baij Nath Singh;Vinayak Ranjan;R.N. Hota
    • Steel and Composite Structures
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    • v.50 no.3
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    • pp.299-318
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    • 2024
  • The main objective of this paper is to compute the far-field acoustic radiation (sound radiation) of functionally graded plates (FGM) loaded by sinusoidally varying point load subjected to the arbitrary boundary condition is carried out. The governing differential equations for thin functionally graded plates (FGM) are derived using classical plate theory (CPT) and Rayleigh integral using the elemental radiator approach. Four cases, segregated on power-law index k=0,1,5,10, are studied. A novel approach is illustrated to compute sound fields of vibrating FGM plates using the physical neutral surface with an elemental radiator approach. The material properties of the FGM plate for all cases are calculated considering the power law indexes. An in-house MATLAB code is written to compute the natural frequencies, normal surface velocities, and sound radiation fields are analytically calculated using semi-analytical formulation. Ansys is used to validate the computed sound power level. The parametric effects of the power law index, modulus ratios, different constituent of FGM plates, boundary conditions, damping loss factor on the sound power level, and radiation efficiency is illustrated. This work is the benchmark approach that clearly explains how to calculate acoustic fields using a solid layered FGM model in ANSYS ACT. It shows that it is possible to asymptotically stabilize the structure by controlling the intermittent layers' stiffness. It is found that sound fields radiated by the elemental radiators approach in MATLAB, ANSYS and literatures are in good agreement. The main novelty of this research is that the FGM plate is analyzed in the low-frequency range, where the stiffness-controlled region governs the whole analysis. It is concluded that a clamped mono-ceramic FGM plate radiates a lesser sound power level and higher radiation efficiency than a mono-metallic or metal-rich FGM plate due to higher stiffness. It is found that change in damping loss factor does not affect the same constituents of FGM plates but has significant effects on the different constituents of FGM plates.

Adsorption Characteristics of Elemental Iodine and Methyl Iodide on Base and TEDA Impregnated Carbon (활성탄을 이용한 원소요오드 및 유기요오드 흡착특성)

  • Lee, Hoo-Kun;Park, Geun-Il
    • Nuclear Engineering and Technology
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    • v.28 no.1
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    • pp.44-55
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    • 1996
  • For the purpose of controlling the release of radioiodine to the environment in nuclear power plants, adsorption characteristics of elemental iodine and methyl iodide on the base carbon and 2%, 5% TEDA impregnated carbons were studied. The amounts of adsorption of elemental iodine and methyl iodide on the carbons were compared with Langmuir, Freundlich, Sips and Dubinin-Astakhov(DA) isotherm equations. Adsorption data were well correlated by the DA equation based on the potential theory. Adsorption energy distributions were obtained from the parameters of the DA equation derived from the condensation approach method. For the adsorption of methyl iodide and elemental iodine-carbon system, the DA equation can be well expressed by the degree of heterogeneity of the micropore system because the surface is nonuniform when its potential energy is unequal. The adsorption energy distribution wes investigated to find a surface heterogeneity on the carbon. The surface heterogeneity for iodine-carbon system is highly affected by the adsorbate-adsorbent interaction as well as the pore structure. The surface heterogeneity increases as a content of TEDA impregnated increases. The adsorption nature of methyl iodide on carbon turned out to be more heterogeneous than that of elemental iodine.

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Preliminary Proteomic Analysis of Thiobacillus ferrooxidans Growing on Elemental Sulphur and Fe2+ Separately

  • He, Zhi-guo;Hu, Yue-Hua;Zhong, Hui;Hu, Wei-Xin;Xu, Jin
    • BMB Reports
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    • v.38 no.3
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    • pp.307-313
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    • 2005
  • Thiobacillus ferrooxidans is one of the most important bacterium used in bioleaching, and can utilize $Fe^{2+}$ or sulphide as energy source. Growth curves for Thiobacillus ferrooxidans have been tested, which show lag, logarithmic, stationary and aging phases as seen in other bacteria. The logarithmic phases were from 10 to 32 hours for Thiobacillus ferrooxidans cultivated with $Fe^{2+}$ and from 4 to 12 days for Thiobacillus ferrooxidans cultivated with elemental sulphur. Differences of protein patterns of Thiobacillus ferrooxidans growing on elemental sulphur and $Fe^{2+}$ separately were investigated after cultivation at $30^{\circ}C$ by the analysis of two-dimensional gel electrophoresis (2-DE), matrix-assisted laser desorption/ ionization (MALDI)-Mass spectrometry and ESI-MS/MS. From the 7 identified protein spots, 11 spots were found more abundant when growing on elemental sulphur. By contrast 6 protein spots were found decreased at elemental cultivation condition. Among the proteins identified, cytochrome C have been previously identified as necessary elements of electron-transfering pathway for Thiobacillus ferrooxidans to oxidize $Fe^{2+}$; ATP synthase alpha chain and beta are expressed increased when Thiobacillus ferrooxidans cultivated with $Fe^{2+}$ as energy source. ATP synthase Beta chain is the catalytic subunit, and ATP synthase alpha chain is a regulatory subunit. The function of ATPase produces ATP from ADP in the presence of a proton gradient across the membrane.