• Title/Summary/Keyword: elemental analysis

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Studies on the Polarographic Behavior of Elemental Sulfur (원소 유황의 Polarograph 거동에 관한 연구)

  • 김준용;장순자
    • YAKHAK HOEJI
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    • v.22 no.4
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    • pp.201-206
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    • 1978
  • The analysis of elemental sulfur by polarography has already been reported in the literature. Only a discussion of the more important factors influencing the analysis is here presented. (1) The effects of pH on the reduction of elemental sulfur are pronounced and the use of buffered solutions for the analysis of elemental sulfur is necessary. The authors found that a pH of 4-6 was found to be reproducible polarograms by use of D.C. polarograph. However, in alkali solvents the plateau of elemental sulfur has a pronounced dip if the concentration of sulfur is as much as 30ppm. (2) A.C. polarographic method shows a very high sensitivity in the case of sulfur reduction, so that the very low concentration of sulfur can easily be determined (about 1ppm). (3) The characteristics of sulfur wave can be formulated according to Stackelberg-Hauck-Hans equation. It was found that the curve of the peak potential of elemental sulfur in A.C. polarography versus logarithm of sulfur concentration was obtained to be straight line with the slope of 29.6 millivolts. This result was well agreed with theoretical consideration. (4) It was assumed that this polarographical methods were applicable to micro-analysis of elemental sulfur in crude oil and its petrochemical products, precipitated sulfur, and sulfur ointments with accuracy and rapidity.

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Elemental image resizing and the analysis of the reconstructed three dimensional image in the integral imaging system (집적결상법에서 기본영상의 크기 변환에 따른 3차원 재생영상의 특성 분석)

  • Ser, Jang-Il;Shin, Seung-Ho
    • Korean Journal of Optics and Photonics
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    • v.16 no.3
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    • pp.225-234
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    • 2005
  • In the integral imaging system for 3D display, the elemental image size is closely related to the several variables, such as the size of elemental lens, the distance between elemental lens and elemental image, etc., on the pick up system. We have analyzed the geometric relation between the variables. In addition, we have investigated the integrated image variation for the individual and whole conversion of the size of the elemental images, different from in pick up process, and presented experimental results.

Transformations and Their Analysis from a RGBD Image to Elemental Image Array for 3D Integral Imaging and Coding

  • Yoo, Hoon
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.12 no.5
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    • pp.2273-2286
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    • 2018
  • This paper describes transformations between elemental image arrays and a RGBD image for three-dimensional integral imaging and transmitting systems. Two transformations are introduced and analyzed in the proposed method. Normally, a RGBD image is utilized in efficient 3D data transmission although 3D imaging and display is restricted. Thus, a pixel-to-pixel mapping is required to obtain an elemental image array from a RGBD image. However, transformations and their analysis have little attention in computational integral imaging and transmission. Thus, in this paper, we introduce two different mapping methods that are called as the forward and backward mapping methods. Also, two mappings are analyzed and compared in terms of complexity and visual quality. In addition, a special condition, named as the hole-free condition in this paper, is proposed to understand the methods analytically. To verify our analysis, we carry out experiments for test images and the results indicate that the proposed methods and their analysis work in terms of the computational cost and visual quality.

The Study on the Analysis of Elemental Maintenance Costs for Educational Facilities

  • Hyun-Wook Kang;Seung-Wook Lee;Sung- Ryul Bae;Byoung-Jun Min;Moon-Sun Park;Yong-Su Kim
    • International conference on construction engineering and project management
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    • 2009.05a
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    • pp.1254-1259
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    • 2009
  • The purpose of this study is to analyze elemental maintenance costs for educational buildings. The adapted research method selected three school buildings in Seoul as BTL projects. On the basis of the selected case, the study suggested a model to establish a system for each parts and to estimate analyzed maintenance costs through that system. According to the analysis, the study proposed a partial maintenance costs standard and analyzed proper maintenance costs. The results of this study are as follows 1) The system is divided into 8 large-groups and 24 small-groups for the analysis elemental maintenance costs. 2) The average rations followed by analysis of partial maintenance costs of the three school buildings are as followings, the total maintenance costs are analyzed 3,992 million won and each part of average rations is exterior of building 10.9%, interior of building 41.58%, electricity & fire fighting facility 14.22%, water supply & healthy facility 11.39%, heating & water supply facility 12.93%, landscape 6.3%, civil engineering works 2.69%.

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Investigation of Elemental Mercury Oxidation on Commercial SCR Catalysts in Flue Gas of Fossil Fired Power Plant (상용 SCR 촉매상에서 화력발전소 배기가스 중 원소수은의 산화반응연구)

  • Lee, Seung-Min;Lee, Jung-Bin
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.3
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    • pp.245-252
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    • 2010
  • For the purpose of evaluating to remove elemental mercury using SCR (Selective Catalytic Reduction) catalysts, the result of the concentration variation of elemental mercury in lab experiment and field measurement was compared. The effect of the elemental mercury oxidation on commercial catalysts was studied in simulated gas. Three species of SCR catalyst, $V_2O_5-TiO_2$ type, were selected. The elemental mercury reduced 30% without HCl gas in SCR operating condition. But the width of reduction increased 60% at 20 ppm HCl gas. According to the result of field measurement, reduction rate of elemental mercury at SCR outlet showed 60%. The total mercury concentration decreased about 20%. The results were similar to the lab test. The results of chemical analysis of test sample showed increase of mercury concentration but surface change was not observed.

Application of Semi-continuous Ambient Aerosol Collection System for Elemental Analysis (대기입자의 원소성분 배출특성연구를 위한 반-연속식 입자채취시스템 적용)

  • Park, Seung-Shik;Ko, Jae-Min;Lee, Dong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.1
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    • pp.39-51
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    • 2012
  • Aerosol slurry samples were collected in 60-min interval using Korean Semi-continuous Elements in Aerosol Sampler (KSEAS) between May 19 and June 6, 2010 at an urban site of Gwangju. The $PM_{2.5}$ samples were collected with a flow rate of 16.7 L/min and particles are grown by condensation of water vapor in a condenser maintained at ${\sim}5^{\circ}C$ after saturation by direct injection of steam. The resulting droplets are collected in a liquid slurry with a airdroplet separator. Concentrations of 16 elements (Al, Fe, Mn, Ca, K, Cu, Zn, Pb, Cd, Cr, Ti, V, Ni, Co, As, Se) in the collected slurry samples were determined off-line by ICP-MS. KSEAS sample analysis encompassed the sampling periods for which 24-hr average elemental species concentrations were calculated for comparison with those derived from 24-hr integrated filter samples. Relationship between elemental species measured by two methods indicated high correlation coefficients (r), mostly greater than r of 0.80. However, we note that concentrations of Al, K, Ca, Mn, and Fe, which are often associated with crustal elemental particles, in the KSEAS samples, were substantially lower (1.4~11 times) than those found in the typical filter-based samples. This discrepancy is probably due to difficulties in transferring insoluble dust particles to the collection vials in the KSEAS. Temporal profiles of elemental concentrations indicate that some transient events in their concentrations are observed over the sampling periods. For the elemental species studied, atmospheric concentrations during the transient events increased by factors of 4 in Mn~80 in Zn, compared to their background levels. Principle component analyses were applied to the hourly KSEAS data sets to identify sources affecting the concentrations of the metal constituents observed. In this study, we conclude that hourly measurements for particle-bound elemental constituents were extremely useful for revealing the short-term variability in their concentrations and developing insights into their sources.

Role of Electron Acceptor-donor on Elemental Mercury Removal Using Nano-silver-plated Activated Carbons Complexes

  • Lee, Hyo In;Yim, Yoon-Ji;Bae, Kyong-Min;Park, Soo-Jin
    • Composites Research
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    • v.31 no.2
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    • pp.76-81
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    • 2018
  • In this study, the elemental mercury removal behaviors of silver-plated porous carbons materials were investigated. The pore structures and total pore volumes of the hybrid materials were analyzed by $N_2$ adsorption/desorption analysis at 77 K. The pore structures and surface morphologies of the hybrid materials were characterized by XRD and SEM, respectively. The elemental mercury adsorption capacities of all silver-plated porous carbons hybrid materials were higher than those of the as-received samples, despite the fact that the specific surface areas and total pore volumes decreased with increasing metal loading time. It was found that silver nanoparticles showed excellent elemental mercury removal behaviors in carbonaceous hybrid materials.

A study on the knowledge representation of industrial mechanical elemental parts for boundary representation (산업용 기계요소 부품의 경계표현을 위한 지식표현에 관한 연구)

  • Jeon, Chan-Gu;Ko, Myoung-Sam
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.325-329
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    • 1987
  • In this paper, attempts have been made to extract elemental knowledges from contours of industrial mechanical elemental parts for efficient boundary representation ( chain coding) of their contours. These elemental knowledges could be used to know-ledge representation for representing boundaries of various industrial mechanical parts. Analysis is focused on elemental knowledges of line and circle boundaries, which compose basic elements of the contours of industrial mechanical parts.

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A high-stability neutron generator for industrial online elemental analysis

  • Xiang-quan Chen;Lei Xiong;Hui Xie;Jing-fu Guo;Xue-ming Zhang;Yong-jun Dong
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1441-1453
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    • 2024
  • The yield stability of the neutron generator directly affects the accuracy of elemental analysis. This paper presents an industrial fully automatic neutron generator with a 48 mm neutron tube based on PLC to improve the stability and reliability of the neutron generator in industrial applications. By integrating a Kalman Filter with the PID algorithm in a PLC, the neutron yield of the generator is remarkably stabilized, achieving 1 × 108n/s. The neutron generator has been employed for industrial online elemental analysis. The results demonstrate that only a slight fluctuation of ±0.82 % exists in the neutron yield, and the reproducibility of the generator holds at a significant level of 0.05. This improved neutron generator can be applied to the online bulk analysis of carbon in coal-fired power stations and absolute measurement of neutron source emission rate.

Preliminary Study on the Visualization and Quantification of Elemental Compositions in Individual Microdroplets using Solidification and Synchrotron Radiation Techniques

  • Ma, Chang-Jin;Tohno, Susumu;Kasahara, Mikio
    • Asian Journal of Atmospheric Environment
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    • v.5 no.1
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    • pp.56-63
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    • 2011
  • Quantifying the solute composition of a cloud droplet (or a whole droplet) is an important task for understanding formation processes and heating/cooling rates. In this study, a combination of droplet fixation and SR-XRF microprobe analysis was used to visualize and quantify elements in a micro-scale droplet. In this study, we report the preliminary outcome of this experiment. A spherical micro-scale droplet was successfully solidified through exposure to ${\alpha}$-cyano-acrylate vapor without affecting its size or shape. An X-ray microprobe system equipped at the beam line 37XU of Super Photon ring 8 GeV (SPring-8) was applied to visualize and quantify the elemental composition in an individual micro-scale droplet. It was possible to reconstruct 2D elemental maps for the K and Cl contained in a microdroplet that was dispensed from the 10-ppm KCl standard solution. Multi-elemental peaks corresponding to X-ray energy were also successfully resolved. Further experiments to determine quantitative measures of elemental mass in individual droplets and high-resolution X-ray microtomography (i.e., 3D elemental distribution) are planned for the future.