• Title/Summary/Keyword: element chlorine free

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Effect of Sugarcane Bagasse Soda-AQ Pulp Bleaching Properties by Type of Chelate Compounds and Simultaneous Process of (DQ) Stage (이산화염소 표백단계와 킬레이트 처리단계 동시 진행 시 킬레이트 종류가 사탕수수 Soda-AQ 펄프 표백에 미치는 영향)

  • Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.1
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    • pp.147-155
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    • 2016
  • Pulp made from sugarcane bagasse (SCB) was bleached in element chlorine free (ECF) sequence. The peroxide bleaching process for the final bleaching process has been introduced in order to reduce the use of chlorine dioxide. Prior to peroxide bleaching, different chelating chemicals were applied. When 4.5% of the total chlorine dioxide was used, bleached SCB pulp using additional DTPA chelate stage (DEDQP) resulted in 87.0% of the ISO brightness. However, bleached pulp using simultaneous stage of DTPA chelate and chlorine dioxide (DE(DQ)P) was reached at 83.9% of the ISO brightness. The viscosity of DEDQP bleached pulp was 25.6 cPs, and the one of DE(DQ)P bleached pulp was 21.9 cPs. Decreasing of chelate effect by chlorine dioxide led to a decrease in the final brightness and a lower viscosity. But simultaneous stage of EDTA chelate and chlorine dioxide (DE(DQ)P) led to higher final brightness (87.0% ISO) and higher viscosity (25.8 cPs) than those of the $DEDQ_{EDTA}P$ bleached pulp (86.4% ISO, 25.2 cPs).

Chlorine Dioxide Bleaching Properties of Sugarcane Bagasse Pulp and Oil Palm Trunk Pulp (사탕수수 부산물 펄프와 오일팜 줄기 펄프의 이산화염소 표백 특성)

  • Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.13-20
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    • 2015
  • Soda-AQ pulp made from sugarcane bagasse (SCB) and oil palm trunk (OPT) were bleached in element chlorine free (ECF) sequence. Bleached SCB and OPT pulp was achieve higher brightness than 85.0% ISO. Viscosity of SCB bleached pulp and OPT bleached pulp were achieved 18-27 cPs and 18-26 cPs. In 7.8% active chlorine dioxide addition, bleached SCB pulp was shown 88.7% ISO brightness and 20.4 cPs viscosity. And bleached OPT pulp was shown 88.5% ISO brightness and 18.8 cPs viscosity with 7.8% active chlorine dioxide addition.

Effect on Bleaching Efficiency by Chelating Treatment in Sugarcane Bagasse DEDP Bleaching Process (사탕수수 부산물 펄프의 DEDP 표백 시 킬레이트 전처리가 표백 효율에 미치는 영향)

  • Lee, Jai-Sung;Song, Woo-Yong;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.81-87
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    • 2015
  • Soda-AQ pulp made from sugarcane bagasse (SCB) were bleached in element chlorine free (ECF) sequence. To reduce chlorine dioxide use, final peroxide bleaching was introduced. Prior to peroxide bleaching, different chelating chemicals were applied for comparative analysis in ISO brightness and viscosity. When using equal total chlorine dioxide usage (4.5%), bleached SCB pulp using chelate and hydrogen peroxide (DEDQP) was reached 86.8% (DTPA), 86.4% (EDTA) ISO brightness, whereas bleached pulp using only hydrogen peroxide (DEDP) reached at 81.2% ISO brightness. Viscosity of DEDQP bleached pulp was 25.6 cPs (DTPA), 25.2 cPs (EDTA), And DEDP bleached pulp was shown 18.0 cPs viscosity. Decreasing of transition metal by chelate process led to improvements in final brightness along with higher viscosity. Due to EDTA is 5-7 times cheaper than DTPA, EDTA is recommended as chelating chemical prior to peroxide bleaching.