• Title/Summary/Keyword: electron accepting conditions

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Fluorescent Blue Materials for Efficient Organic Light-Emitting Diode with High Color Purity

  • Choi, Kyung-Sun;Lee, Chan-Hyo;Lee, Kwan-Hee;Park, Su-Jin;Son, Seung-Uk;Chung, Young-Keun;Hong, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1549-1552
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    • 2006
  • We report a new series of blue dopants composed of both electron donating and electron accepting moieties in one molecule, based on nalidixic acid. The EL device derived from the dopant exhibits pure blue light emission (0.15, 0.14) The current efficiency is estimated to be 3.88 cd/A at 100 $cd/m^2$, which shows remarkable enhancement, compared to that of the host itself (2.5 cd/A at 100 $cd/m^2$) under the same conditions. These results demonstrate that the incorporation of a proper guest into the host in a guest-host doped system improves not only the purity of the fluorescent blue emission but also elevates its quantum efficiency, thus improving the OLED performance.

Anaerobic Degradation of cis-1,2-Dichloroethylene by Cultures Enriched from a Landfill Leachate Sediment

  • Chang, Young-Cheol;Jung, KwEon;Yoo, Young-Sik
    • Journal of Microbiology and Biotechnology
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    • v.13 no.3
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    • pp.366-372
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    • 2003
  • The production of microbiologically enriched cultures that degrade cis- 1,2-dichloroethylene(DCE) under anaerobic conditions was investigated. Among 80 environmental samples, 19 displayed significant degradation of $10{\mu}M$ cis-DCE during 1 month of anaerobic incubation, and one sediment sample collected at a landfill area (Nanji-do, Seoul, Korea) showed the greatest degradation ($94\%$). When this sediment culture was subcultured repeatedly, the ability to degrade cis-DCE gradually decreased. However, under Fe(III)-reducing conditions, cis-DCE degradation by the subculture was found to be maintained effectively. In the Fe(III)-reducing subculture, vinyl chloride (VC) was also degraded at the same extent as cis-DCE No accumulation of VC during the cis-DCE degradation was observed. Thus, Fe(III)-reducing microbes might be involved in the anaerobic degradation of the chlorinated ethenes. However, the subcultures established with Fe(III) could function even in the absence of Fe(III), showing that the degradation of cis-DCE and VC was not directly coupled with the Fe(III) reduction. Consequently, the two series of enrichment cultures could not be obtained that degrade both cis-DCE and VC in the presence or absence of Fe(III). Considering the lack of VC accumulation, both cultures reported herein may involve interesting mechanism(s) for the microbial remediation of environments contaminated with chlorinated ethenes. A number of fermentative reducers (microbes) which are known to reduce Fe(III) during their anaerobic growth are potential candidates involved in cir-DCE degradation in the presence and absence of Fe(III).