• 제목/요약/키워드: electrolytic material

검색결과 137건 처리시간 0.024초

Morphology of Bone-like Apatite Formation on Sr and Si-doped Hydroxyapatite Surface of Ti-6Al-4V Alloy after Plasma Electrolytic Oxidation

  • Yu, Ji-Min;Choe, Han-Cheol
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2017년도 춘계학술대회 논문집
    • /
    • pp.79-79
    • /
    • 2017
  • Metallic biomaterials have been mainly used for the fabrication of medical devices for the replacement of hard tissue such as artificial hip joints, bone plates, and dental implants. Because they are very reliable on the viewpoint of mechanical performance. This trend is expected to continue. Especially, Ti and Ti alloys are bioinert. So, they do not chemically bond to the bone, whereas they physically bond with bone tissue. For their poor surface biocompatibility, the surface of Ti alloys has to be modified to improve the surface osteoinductivity. Recently, ceramic-like coatings on titanium, produced by plasma electrolytic oxidation (PEO), have been developed with calciumand phosphorus-enriched surfaces. A lso included the influences of coatings, which can accelerate healing and cell integration, as well as improve tribological properties. However, the adhesions of these coatings to the Ti surface need to be improved for clinical use. Particularly Silicon (Si) has been found to be essential for normal bone, cartilage growth and development. This hydroxyapatite, modified with the inclusion of small concentrations of silicon has been demonstrating to improve the osteoblast proliferation and the bone extracellular matrix production. Strontium-containing hydroxyapatite (Sr-HA) was designed as a filling material to improve the biocompatibility of bone cement. In vitro, the presence of strontium in the coating enhances osteoblast activity and differentiation, whereas it inhibits osteoclast production and proliferation. The objective of this work was to study Morphology of bone-like apatite formation on Sr and Si-doped hydroxyapatite surface of Ti-6Al-4V alloy after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages with various concentrations of Si and Sr ions. Bone-like apatite formation was carried out in SBF solution. The morphology of PEO, phase and composition of oxide surface of Ti-6Al-4V alloys were examined by FE-SEM, EDS, and XRD.

  • PDF

Chemical Stability of Conductive Ceramic Anodes in LiCl-Li2O Molten Salt for Electrolytic Reduction in Pyroprocessing

  • Kim, Sung-Wook;Kang, Hyun Woo;Jeon, Min Ku;Lee, Sang-Kwon;Choi, Eun-Young;Park, Wooshin;Hong, Sun-Seok;Oh, Seung-Chul;Hur, Jin-Mok
    • Nuclear Engineering and Technology
    • /
    • 제48권4호
    • /
    • pp.997-1001
    • /
    • 2016
  • Conductive ceramics are being developed to replace current Pt anodes in the electrolytic reduction of spent oxide fuels in pyroprocessing. While several conductive ceramics have shown promising electrochemical properties in small-scale experiments, their long-term stabilities have not yet been investigated. In this study, the chemical stability of conductive $La_{0.33}Sr_{0.67}MnO_3$ in $LiCl-Li_2O$ molten salt at $650^{\circ}C$ was investigated to examine its feasibility as an anode material. Dissolution of Sr at the anode surface led to structural collapse, thereby indicating that the lifetime of the $La_{0.33}Sr_{0.67}MnO_3$ anode is limited. The dissolution rate of Sr is likely to be influenced by the local environment around Sr in the perovskite framework.

PEO 전류밀도 조건에 따른 알루미늄도금 강재상 산화코팅막의 특성 (Characteristics of Coating Films on Hot-Dipped Aluminized Steel Formed by Plasma Electrolytic Oxidation Process at Different Current Densities)

  • 최인혜;이훈성;이명훈
    • 한국표면공학회지
    • /
    • 제50권5호
    • /
    • pp.366-372
    • /
    • 2017
  • Plasma electrolytic oxidation(PEO) has attracted attention as a surface treatment which has high wear resistance and corrosion resistance. PEO is generally considered as cost-effective, environmentally friendly and superior in terms of coating performance. Most of studies about the PEO processes have been applied to light metals such as Al and Mg. Because the strength of Al and Mg is weaker than that of steel, there is a limit to the application. In this study, PEO process was used to form oxide coatings on Hot dipped aluminized(HDA) steel and the characteristics of the coating film according to the PEO current density were studied. The morphology was observed by SEM and component was analyzed by using EDS. The corrosion behaviors of PEO coating films were estimated by exposing salt spray test at 5 wt.% NaCl solution and measuring polarization curves in deaerated 3 wt.% NaCl solution. With the increase of PEO process current density, the pore size of the coating surface and the thickness of coating increased. It was confirmed that no Fe component was present on the coating surface. PEO coating films obviously showed good corrosion resistance compared with HDA. It is considered that the PEO coating acts as a barrier to protect the base material from external factors causing corrosion.

순수 비틀림 하중하에서 열화를 고려한 2상 스데인리스강의 저주기 피로특성 (Low Cycle Fatigue Characteristics of Duplex Stainless Steel with Degradation under Pure Torsional Load)

  • 권재도;박중철
    • 대한기계학회논문집A
    • /
    • 제26권9호
    • /
    • pp.1897-1904
    • /
    • 2002
  • Monotonic torsional and pure torsional low cycle fatigue(LCF) test with artificial degradation were performed on duplex stainless steel(CF8M). CF8M is used in pipes and valves in nuclear reactor coolant system. It was aged at 430$^{\circ}C$ for 3600hrs. Through the monotonic and LCF test, it is found that mechanical properties(i.e., yield strength, strain hardening exponent, strength coefficient etc.) increase and fatigue life(N$\sub$f/) decreases with degradation of material. The relationship between shear strain amplitude(${\gamma}$$\sub$a/)and N$\sub$f/ was proposed.

자기장이 전해복합연마공정에 미치는 영향 (Effects of Magnitic Field on Electrochemical Polishing Process)

  • 김정두;최민석;김동섭
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 1994년도 추계학술대회 논문집
    • /
    • pp.108-112
    • /
    • 1994
  • The paper describes the effects of magnetic field on the electrochemical polishing process in the view of ionic in the electrolyte. Theoretical background was suggested how magnetic field increases the material removal efficiency and surface finishing ability Magnetic field changes the jonic movement in the electrolyte from linear motion to curved or complex oscillating one, thus increases the electrolytic current density and, as the results, the finishing efficiency.

  • PDF

접지선 굵기에 관한 연구 (The study on the ground wire size)

  • 최홍규;최병숙;송영주
    • 한국조명전기설비학회:학술대회논문집
    • /
    • 한국조명전기설비학회 2003년도 학술대회논문집
    • /
    • pp.97-102
    • /
    • 2003
  • Ground in must choose enough sectional area of conductor endurably in maximum fault current, fault duration time, maximum allowable temperature and have strong durability and life-time can bear enough from spontaneous corrosion or electrolytic corrosion and must choose material that problem does not exist electrically and mechanically when connection or junction. In this paper, modeled new ground wire size numerical formula, and examine and compare of modeled numerical formula and abroad regulation, and proved and analyzed validity of the new ground wire size computation method because do simulation to computer program.

  • PDF

폭염 시 육계 출하 전 전해질 급여가 닭고기 도체 및 혈액에 미치는 영향 (Effect of Electrolytic Material Feeding on Blood and Carcass Traits of Broiler under Intense Heat Condition in Summer)

  • 채현석;최희철;나재천;김민지;강환구;김동욱;김지혁;조수현;이종언;김남영;최양호;박병성
    • 한국가금학회지
    • /
    • 제39권3호
    • /
    • pp.183-193
    • /
    • 2012
  • 본 연구는 육계 출하 2일 전부터 전해물질을 급여한 후 출하 직전에 혈액을 채취하고, 출하 시 고온 수송 스트레스를 받게 한 후 닭의 혈액을 채취하였으며, 도계 후 닭고기 도체 특성을 조사하여 전해질 종류($NaHCO_3$, KCl, NaCl) 및 급여수준에 따라 혈액 및 도체 특성을 구명하기 위하여 실시하였다. 음수량의 변화에서는 고온 하에서 육계를 출하시 대조구에 비하여 처리 2구를 제외하고 전해물질을 급여한 모든 처리구에서 약간씩 증가하는 경향을 나타내었으며, 특히 처리 4구에서 음수량이 가장 높았다. 계분의 수분 함량은 처리 5구에서 87.13%로 가장 높은 수분량을 나타내었고 대조구에서 수분 함량이 가장 낮았다. 조지방과 조단백질은 대조구에서 가장 높은 함량을 나타내었다. 닭고기 도체의 pH 변화는 대조구에 비하여 전해질을 급여한 모든 처리구에서 증가하였고, 특히 처리 3구에서 가장 높은 pH 값을 나타내었다. 닭고기 $1^+$ 등급 출현율은 대조구가 33.3%인 반면에 처리 3, 4구는 60%, 처리5구는 83.3%으로 고온 스트레스 하에서 전해질 물질을 충분히 급여함에 따라 닭고기 $1^+$ 등급 출현율을 증가시켰다. 닭고기의 PSE 발생율도 대조구는 50%를 나타내었으나, 처리 5구는 13.3%를 나타내어 매우 낮은 수준을 나타내었다. 육계를 출하 시 고온스트레스에 대한 육계의 혈액 중 corticosterone의 변화는 출하 전보다 출하 후 측정값이 상승하였으나, 처리 3구를 제외하고 대조구에 비하여 출하 전과 출하 후의 차이가 적은 것으로 나타났다. ACTH에 대한 변화에서도 출하 전보다 출하 후에 모든 처리구에서 상승하였으며, 출하 후에 처리 5구에서 가장 낮은 ACTH의 함량을 나타내었고, 출하 전 후 차이값도 가장 낮게 나타났다. 혈액의 $pCO_2$ 분압은 출하 전보다 고온 스트레스를 받은 후 전체적으로 낮아졌으며, 출하 전 후의 차이 값은 대조구에서 가장 높았고, 처리 4, 5구에서 대체적으로 낮은 차이 값을 나타내었다. 혈액의 $pO_2$ 분압은 출하 전 후에서 처리별로 일정한 경향을 나타내지 않았다. 이상의 결과로 고온에서 육계 출하 시 수송 스트레스를 저하시키고 닭고기의 품질을 높이기 위하여 전해 물질($NaHCO_3$, NaCl, KCl)을 고루 혼합한 처리 4, 5구가 비교적 우수한 것으로 나타났다.

순환공정법(循環工程法)을 적용(適用)한 인공(人工) 사진폐액(寫眞廢液)으로부터의 전해채취(電解採取)에 의한 은(銀)의 회수(回收) (Recovery of Silver from Artificial Photographic Wastewater by Continuous Flow Electrolytic Process)

  • 정원주;김동수
    • 자원리싸이클링
    • /
    • 제16권1호
    • /
    • pp.68-72
    • /
    • 2007
  • 전기적 환원을 이용한 인공 사진폐수에서의 은 회수를 연속순환식 공정을 적용하여 환원시간 및 두 전극간의 전합 차, 농도유량에 따른 영향을 검토하였다. 은 함유 인공폐수 처리에 있어 적용(인가) 전압과 초기 농도가 증가함에 따라 제거율이 증가함을 보였다. 은 함유 인공폐수의 전해 반응 시, 음극에 환원 석출된 물질의 정성적인 분석을 위해 EPMA 및 XRD 분석 결과, 석출된 물질이 은임을 확인하였다.

자기연마를 이용한 ELID 연삭면의 나노경면연마 (Nano-level mirror finishing for ELID ground surfsce using magnetic assisted polishing)

  • 이용철;곽태수;안제 정박;대삼 정
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2005년도 춘계학술대회 논문집
    • /
    • pp.629-632
    • /
    • 2005
  • ELID(ELectrolytic In-process Dressing) grinding is an excellent technique for mirror grinding of various advanced metallic or nonmetallic materials. A polishing process is also required for elimination of scratches present on ELID grinded surfaces. MAP(Magnetic Assisted Polishing) has been used as a polishing method due to its high polishing efficiency and to its resulting in a superior surface quality. This study describes an effective fabrication method combining ELID and MAP of nano-precision mirror grinding for glass-lens molding mould, such as WC-Co, which are extensively used in precision tooling material. And for the optics glass-ceramic named Zerodure, which is extensively used in precision optics components too. The experimental results show that the combined method is very effective in reducing the time required for final polishing. The best surface roughness of the polished glass-ceramic was within 1.7nm Ra in this study.

  • PDF

플라즈마 전해 산화 코팅에 있어서 인산염 전해액과 모재 성분 변화가 Al 산화피막 물성에 미치는 영향 II. PEO 층의 결정상 분석 (Effect of Na2P2O7 Electrolyte and Al Alloy Composition on Physical and Crystallographical Properties of PEO Coating Layer : II. Crystallographic Analysis of PEO Layer)

  • 김배연;김정곤;이득용;김용남;전민석;김성엽;김광엽
    • 한국세라믹학회지
    • /
    • 제49권3호
    • /
    • pp.247-252
    • /
    • 2012
  • Crystal structure and chemical compositions of Plasma electrolytic oxidized layer of A-1100, A-2024, A-5052, A-6061, A-6063, A-7075, ACD-7B and ACD-12 were investigated. The electrolyte for plasma electrolytic oxidation was mixture of distilled water, $Na_2P_2O_7$, Cu, Cr metal salts and KOH. ${\eta}$-Alumina, as well as ${\alpha}$-alumina, was main crystal phase. Another crystals such as $(Al_{0.948}Cr_{0.052})_2O_3$ and $(Al_{0.9}Cr_{0.1})_2O_3$ were also formed in the oxide layer. It was thought that the effect of electrolyte compositions on the physical properties and crystal system of PEO layers was greater than the effect of Al alloy composition variation.