• Title/Summary/Keyword: electrolytic material

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Etch Pit Growth on Aluminum of Cathode Film for Aluminum Electrolytic Capacitor (알루미늄 전해 커패시터용 음극박의 에칭 피트 성장)

  • Kim, Hong-Il;Choi, Ho-Gil;Kim, Sung-Han;Kim, Young-Sam;Shin, Jin-Sik;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.407-408
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    • 2005
  • High surface area electrodes for aluminum electrolytic capacitors are produced by AC electrochemical processes. Optimization of crystallographic etch pit growth on aluminium during AC etching of cathode film for aluminium as electrolytic capacitor has been established. In this work, we present the observations of pit distributions by galvanostatic measurements. The effects of electrolyte concentration, current density, frequency, various pre-treatments and etching time have been studied. The specimen was pretreated in 0.5M NaOH and 1M HCl at $40\sim60^{\circ}C$, and transferred into a cell containing 1M HCl, then various mol $H_2SO_4$ etchant was added. Pit size distributions were determined with scanning electron microscopy (SEM).

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Variables of Electrolytic Nickel Plating for RPV Cladding Repair (압력용기 클래드 보수용 전해니켈도금 인자 관계 연구)

  • Kim, Min-Su;Hwang, Seong-Sik;Kim, Dong-Jin;Lee, Dong-Bok
    • Corrosion Science and Technology
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    • v.18 no.4
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    • pp.148-153
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    • 2019
  • Pure nickel with a thickness of 1 mm was plated on type 304 stainless steels and low alloy steels (JIS G3131 SPHC) by electrolytic plating method in a circulating plating bath. Plating performance, mechanical properties, and surface characteristics were evaluated in terms of pretreatment process, anode material, pH, current density, and flow rate of the plating solution. Addition of hydrochloric acid during pre-treatment process improved the adhesion performance of plating. To improve plating efficiency, it is desirable to use S-nickel rather than electrolytic nickel. The use of S-nickel was also confirmed to be desirable for maintaining the pH and concentration of the plated solution. The defect of the plating using S-nickel anode produced pit on the surface. However, it is believed that proper control can be obtained by increasing the flow rate. Internal stress and hardness values of electrolytic nickel plating according to current density need to be carried out with further studies.

A Study on the Mirror Surface Grinding of Optical Glass Utilizing Electrolytic In-Process Dressing (전해 인프로세스 드레싱을 이용한 Optical glass계의 경면연삭에 관한 연구)

  • 조주현;원종호;박원규;이진오;김민수;김성수
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.04a
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    • pp.410-415
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    • 2003
  • Electrolytic In-process Dressing (ELID) technique for metal bonded diamond grinding wheel has been developed for mirror surface grinding of hard and brittle materials. This study process optical glass in using Electrolytic In-process Dressing. In using to main variable wheel speed (400rpm~2000rpm),feed rate (5$\mu\textrm{m}$/min~25$\mu\textrm{m}$/min),depth of cut (3$\mu\textrm{m}$~5$\mu\textrm{m}$),dressing and spray. We measured surface roughness in representative brittle materials

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Effect of Al Alloy Composition on Physical and Crystallographical Properties of Plasma Electrolytic Oxidized Coatings I. Physical Properties of PEO Layer (플라즈마 전해 산화 코팅에 있어서 알루미늄 합금 모재 성분의 물리적, 결정학적 영향 I. PEO 층의 물성)

  • Kim, Bae-Yeon;Lee, Deuk-Yong;Kim, Yong-Nam;Jeon, Min-Seok;Song, Jun-Kwang;Kim, Sung-Youp;Kim, Kwang-Youp
    • Journal of the Korean Ceramic Society
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    • v.47 no.3
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    • pp.256-261
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    • 2010
  • Physical properties of Plasma electrolytic oxidized 8 different types of Al alloys, A-1100, A-2024, A-5052, A-6061, A-6063, A-7075, ACD-7B and ACD-12 were investigated. The electrolyte for PEO was $Na_2SiO_3$ solutions with NaOH and some alkali earthen metal salts. Porous layer near the surface of PEO coating was not found, and surface roughness Ra50 was below 2.5 ${\mu}m$. Surface roughness was affected by growth rate of plasma electrolytic oxidized layer, not by Si content in Al alloy.

A Study on Cathode active material of Li/MnO$_2$ Battery for performance improvement (성능향상을 위한 리튬전지의 Cathode active material에 관한 연구)

  • 김학주;송수정
    • Proceedings of the KAIS Fall Conference
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    • 2001.11a
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    • pp.79-84
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    • 2001
  • 본 논문에서는 리튬전지의 Cathode active material로 CMD(chemical manganese dioxide)를 사용하여 현재 사용중인 EMD(electrolytic manganese dioxide)와 공정 수율 및 특성과 방전 성능을 비교함으로써 새로운 cathode active material.로의 적용 가능성을 확인하기 위함이다.

Study on Electrochemical Polishing for Stainless Steel using Micro Pulse Current (미세 펄스전원을 이용한 스테인레스강의 전기화학연마)

  • 이동활;박정우;문영훈
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.127-130
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    • 2003
  • Electrolytic polishing is the anodic dissolution process in the transpassive state. It removes non-metallic inclusions and improves mechanical and corrosion resistance of stainless steel. Electrolytic polishing is normally used to remove a very thin layer of material from the surface of a metal object. An electrolyte of phosphoric, sulfuric and distilled water has been used in this study. In the low current density region, there can be found plateau region and material removal process and leveling process occur successively. In this study, an electrochemical polishing process using pulse current is adopted as a new electrochemical polishing process. In electrochemical machining processes, it has been found that pulse electrochemical processes provide an attractive alternative to the electrochemical processes using continuous current. Hence, this study will discuss the electrochemical polishing processes in low current density region and pulse electrochemical polishing.

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Study on Electrochemical Polishing for Stainless Steel 300 Series using Micro Pulse Current (미세 펄스전원을 이용한 스테인레스강 300 계열의 전기화학연마)

  • 이동활;박정우;문영훈
    • Transactions of Materials Processing
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    • v.12 no.4
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    • pp.388-393
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    • 2003
  • Electrolytic polishing is the anodic dissolution process in the transpassive state. It removes non-metallic inclusions and improves mechanical and corrosion resistance of stainless steel. Electrolytic polishing is normally used to remove a very thin layer of material from the surface of a metal object. An electrolyte of phosphoric acid 50% in vol., sulfuric acid 20% in vol. and distilled water 30% in vol. has been used in this study. In the low current density region, there can be found plateau region and material removal process and leveling process occur successively. In this study, an electrochemical polishing process using pulse current is adopted as a new electrochemical polishing process. In electrochemical machining processes, it has been found that pulse electrochemical processes provide an attractive alternative to the electrochemical processes using continuous current. Hence, this study will discuss the electrochemical polishing processes in low current density region and pulse electrochemical polishing.

Characteristics of a Titanium-oxide Layer Prepared by Plasma Electrolytic Oxidation for Hydrogen-ion Sensing

  • Lee, Do Kyung;Hwang, Deok Rok;Sohn, Young-Soo
    • Journal of Sensor Science and Technology
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    • v.28 no.2
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    • pp.76-80
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    • 2019
  • The characteristics of a titanium oxide layer prepared using a plasma electrolytic oxidation (PEO) process were investigated, using an extended gate ion sensitive field effect transistor (EG-ISFET) to confirm the layer's capability to react with hydrogen ions. The surface morphology and element distribution of the PEO-processed titanium oxide were observed and analyzed using field-emission scanning-electron microscopy (FE-SEM) and energy-distribution spectroscopy (EDS). The titanium oxide prepared by the PEO process was utilized as a hydrogen-ion sensing membrane and an extended gate insulator. A commercially available n-channel enhancement MOS-FET (metal-oxide-semiconductor FET) played a role as a transducer. The responses of the PEO-processed titanium oxide to different pH solutions were analyzed. The output drain current was linearly related to the pH solutions in the range of pH 4 to pH 12. It was confirmed that the titanium-oxide layer prepared by the PEO process could feasibly be used as a hydrogen-ion-sensing membrane for EGFET measurements.

A Study on The Characteristics of Ultra Precision Lapping of Machinable Ceramic($Si_3N_4$) by Free & Fixed abrasive (자유지립 및 고정지립을 적용한 머신어블 세라믹($Si_3N_4$)의 초정밀 래핑 가공 특성에 관한 연구)

  • 장진용;이은상;조명우;조원승;이재형
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.537-542
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    • 2004
  • Machinble Ceramics have some excellent properties as the material for the mechanical components. It is, however, very difficult to grind ceramics with high efficiency because of their high strength, hardness and brittleness. Lapping used diamond slurry and lapping by in-process electrolytic dressing is developed to solve this problem. On this paper, a comparative study of processing ability of lapping used diamond slurry and lapping by in-process electrolytic dressing.

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The Explosion Prevention Method for Electrolytic Motor Start Capacitors using Current Characteristic (통전전류 특성을 이용한 모터 기동용 전해 커패시터 폭발 방지 방법)

  • Kim, Jae-Hyun;Park, Jin-Young;Park, Kwang-Muk;Bang, Sun-Bae;Kim, Yong-Un
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.12
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    • pp.1836-1843
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    • 2017
  • In this paper, we investigated fire cases those are believed to be caused by explosion of a electrolytic motor start capacitor. Using two types of commercially available electrolytic motor start capacitors, capacitor current and the possibility of capacitor explosion were tested. And the ignition possibility of the internal material leaked from a capacitor was also tested. In addition, experiments were conducted to see if the fire could spread when a capacitor was exposed to an external flame. From our test we observed that the current of the electrolytic motor start capacitor rose continuously to a certain level by product, if the capacitor was continuously energized with working voltage, and then the capacitor was exploded. The gas and liquid leaked from the capacitor by the explosion could ignite by an electric arc and an external flame. The capacitor current at explosion was different product by product, but each product had a certain current level at explosion. And the increase rate of the capacitor current until explosion was 24% and 31% for the products used in the experiment. We proposed the capacitor explosion prevention method that cuts off power when the capacitor current rises to a certain threshold level. The proposed method can be used if the current of the applied electrolytic motor start capacitor rises continuously and then the capacitor is exploded at a certain current level when the capacitor is energized continuously.