• 제목/요약/키워드: electrolyte leakage

검색결과 127건 처리시간 0.022초

직접 스크린 프린팅법으로 제조된 고분자 전해질 연료전지의 고성능 전극 (High Performance Electrode of Polymer Electrolyte Membrane Fuel Cells Prepared by Direct Screen Printing Process)

  • 임재욱;최대규;류호진
    • 마이크로전자및패키징학회지
    • /
    • 제11권1호
    • /
    • pp.65-69
    • /
    • 2004
  • 스크린 프린팅법은 고분자 전해질 연료전지의 전극 촉매층 제조의 편리함과 적용성의 면에서 가장 일반적인 방법 중에 하나이다. 본 논문은 기존의 방법과 비교하여 매우 낮은 백금 함침량을 가지기 때문에 경쟁적이고, 부가적인 공정 없이 swelling 문제를 간단하게 억제시켜 개선된 스크린 프린팅 법을 제안하였다. 특히, 가스켓 일체형 MEA는 고분자 전해질 연료전지의 작동 중에 가스 침투의 영향을 방지하여 고전류 영역에서 기존의 방법으로 제조된 MEA보다 높은 성능을 가지게 제작하였다. 이와 같은 방법들은 보다 간단하고 빠른 제조의 기회를 준다.

  • PDF

각형 전기이중층 커패시터의 산업 안전성 (Industry safety characteristic of Prismatic EDLCs)

  • 김경민;장인영;강안수
    • 대한안전경영과학회:학술대회논문집
    • /
    • 대한안전경영과학회 2004년도 춘계학술대회
    • /
    • pp.247-257
    • /
    • 2004
  • Electrodes were fabricated based on activated carbon powder BP-20, conducting agent such as Super P, vapor grown carbon fiber (VGCF) and acetylene black (AB), and the mixed binders of flexible poly(vinylidenefluoridehexafluoropropylene) [P(VdF-co-HFP)] and cross linking dispersion agent of polyvinylpyrrolidone (PVP) to increase mechanical strength. According to impedance measurement of the electrode with the addition of conducting agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance (AC-ESR, fast charge transfer rate at interface between electrode and electrolyte and low RC time constant. The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. We found that the 2.3V/230F grade EDLC would be applied to industrial safety usage such as uninterrupted power supply (UPS) because of the constant DC-ESR by IR drop regardless of discharge current.

  • PDF

다공성 전극의 압축률이 레독스흐름전지의 성능에 미치는 영향에 대한 수치해석적 연구 (Numerical Study About Compression Effect of Porous Electrodes on the Performance of Redox Flow Batteries)

  • 정대인;정승훈
    • 한국분무공학회지
    • /
    • 제22권2호
    • /
    • pp.69-79
    • /
    • 2017
  • When designing a redox flow battery system, compression of battery stack is required to prevent leakage of electrolyte and to reduce contact resistance between cell components. In addition, stack compression leads to deformation of the porous carbon electrode, which results in lower porosity and smaller cross-sectional area for electrolyte flow. In this paper, we investigate the effects of electrode compression on the cell performance by applying multi-dimensional, transient model of all-vanadium redox flow battery (VRFB). Simulation result reveals that large compression leads to greater pressure drop throughout the electrodes, which requires large pumping power to circulate electrolyte while lowered ohmic resistance results in better power capability of the battery. Also, cell compression results in imbalance between anolyte and catholyte and convective crossover of vanadium ions through the separator due to large pressure difference between negative and positive electrodes. Although it is predicted that the battery power is quickly improved due to the reduced ohmic resistance, the capacity decay of the battery is accelerated in the long term operation when the battery cell is compressed. Therefore, it is important to optimize the battery performance by taking trade-off between power and capacity when designing VRFB system.

Au 전극의 DDT 보호막 처리 및 그 전기적 효과와 응용 (Electrical Property and Application of Au Electrodes Passivated with DDT Molecules)

  • 최민수;이동진;김태근;황성우
    • 전기학회논문지
    • /
    • 제59권1호
    • /
    • pp.127-129
    • /
    • 2010
  • We report the passivation characteristics of dodecanethiol (DDT) molecules on gold electrodes of field effect transistor bio-sensors. The leakage current between the electrolyte and the electrode can be as small as 3pA when 7 mM of DDT passivation is performed. The DDT layer is also shown to resist the attack of acid up to 120 mins.

일체화된 Aperture 구조의 한계전류형 산소센서의 제작 및 특성 (Fabrication and characteristics of limit-current type oxygen sensor with monolith aperture structure)

  • 오영제;이득용
    • 센서학회지
    • /
    • 제17권4호
    • /
    • pp.273-280
    • /
    • 2008
  • Monolith aperture-type oxygen sensors with simple structure of YSZ(pin-hole)/Pt/ YSZ(solid electrolyte)/Pt were fabricated by co-firing technique. To enhance the yield of productivity, a couple of YSZ green sheets for diffused barrier and solid electrolyte were prepared by tape-casting and co-firing method. The limit current characteristics of the oxygen sensors were measured between 500 and $650^{\circ}C$ The heating temperature of $600^{\circ}C$ was optimum as a portable oxygen sensor in the range of oxygen concentration from 0 to 75 vol%. Linear proficiency of limit current behavior as a function of oxygen concentration was controlled by the variation of aperture dimension. The fabricated oxygen sensors showed the stable sensing output for 30 days. Gas leakage in bonding area due to warping, cracking and thermal cycling was not found in the period.

고출력용 산업안전 보조전원의 Supercapacitor (Supercapacitor of Auxiliary Electric Power Source in Industrial Safety for High Output)

  • 허진우;강안수
    • 대한안전경영과학회:학술대회논문집
    • /
    • 대한안전경영과학회 2003년도 추계학술대회
    • /
    • pp.335-343
    • /
    • 2003
  • In the electrode fabrication of unit cell, it was ascertained that electrochemical characteristics were greatly increased with 90 wt.% of BP-20, 5 wt.% of Super P and 5 wt.% of mixed binder [P(VdF-co-HFP) : PVP =7 : 3] The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. The electrochemical characteristics of 2.3 V/3,000 F grade EDLC were as follows: 0.35 m of DC-ESR (100 A discharge), 0.14 mof AC-ESR (AC amplitude 100 mV), 2.80 Wh/kg (3.73 Wh/L) of energy density and 4.64 kW /kg (6.19 kW/L) of power density. Power output was compatible with electric vehicle applications, uninterrupted power supply and engine starter, in due consideration of Ragone relations.

  • PDF

도시철도 전식방지 조사보고 현황 (Investigation for the Report of DC Traction Stray Current Protection)

  • 이현구;하태현;정호성;한문섭;배정효
    • 한국철도학회:학술대회논문집
    • /
    • 한국철도학회 2008년도 추계학술대회 논문집
    • /
    • pp.281-285
    • /
    • 2008
  • Corrosion of metallic structures arises when an electric current flows from the metal into the electrolyte such as soil and water. The potential difference across the metal-electrolyte interface, the driving force for the corrosion current, can emerge due to a variety of temperature, pH, humidity and resistivity etc.. With respect to a given structure, a stray current is to be defined as a current flowing on a structure that is not part of the intended electrical circuit. Stray currents are caused by other cathodic protection installations, grounding systems and welding posts, referred to as steady state stray currents. But most often traction systems like railroads and tramlines are responsible for large dynamic stray currents. This type of stray current is generally results from the leakage of return currents from large DC traction systems that are grounded or have a bad earth-insulated return path. This paper investigates the reports, which is made for protecting the electrical corrosion by the DC traction stray current before the construction period.

  • PDF

저관리·경량형 옥상녹화를 위한 세덤류의 내서성 평가 (Hot Tolerance Assessment of Sedum spp. for Extensive Green Roof System)

  • 조홍하;손희준;강태호
    • 한국조경학회지
    • /
    • 제40권6호
    • /
    • pp.180-189
    • /
    • 2012
  • 이 연구는 저관리 경량형 옥상녹화시스템을 위한 내서성 식물 선발을 목적으로 6종 세덤식물을 대상으로 처리 시간과 온도에 따라 전해질 용출, 엽록소 함량 변화 및 재생 실험을 실시하였으며, 토양수분과 고온스트레스와의 관계를 연구하였다. Logistic비선형 회귀분석을 이용하여 6시간의 고온 처리 후 5%의 토양 함수량의 치사 온도는 $45.1{\sim}48.0^{\circ}C$, 토양 함수량 10%, 15%의 경우 각각 $47.5{\sim}49.3^{\circ}C$, $48.6{\sim}52.8^{\circ}C$의 범위로 측정되었다. 고온스트레스는 처리 시 토양 수분이 높을수록 세덤류의 내서성이 높아졌다. 엽록소 함량은 처리 온도가 높을수록 함량이 낮아졌고, 토양 수분 함량이 낮을수록 분해 속도가 높아졌다. 토양 함수량 5% 시 고온에 대한 저항성은 S. reflexum>S. takevimense>S. middendorffianum>S. album>S. sieboldii>S. spurium의 순으로 나타났으며, 토양 함수량이 15%의 경우는S. album>S. reflexum>S. spurium>S. takevimense>S. middendorffianum>S. sieboldii의 순으로 나타났다. 토양의 수분 함량이 높을수록 S. album, S. reflexum, S. spurium의 내서성이 높아졌다. 이러한 결과는 재생 검사의 결과와 전해질 용출 평가에 일관성이 있는 것으로 증명되었다.

Relationships between Structural Features and Biological Activities of HC-toxin

  • Kim, Shin-Duk
    • BMB Reports
    • /
    • 제28권3호
    • /
    • pp.227-231
    • /
    • 1995
  • In order to figure out the relationships between structural features and biological activity of the host-specific HC-toxin in maize, structurally related cyclic tetrapeptides, chlamydocin and CYL-2 were isolated, and their biological activities in maize were examined. Biological activities of preparations were determined by root growth inhibition and electrolyte leakage bioassays. Chlamydocin and CYL-2 showed toxicities to maize. However, the toxicities of these compounds were non-specific. Thus, the precise peptide ring structure of HC-toxin apparently does not play an important role in toxicity, while resistance of maize to HC-toxin is based on a precise ring conformation.

  • PDF

Effect of Seed Priming on Quality Improvement of Maize Seeds in Different Genotypes

  • Seo Jung Moon;Lee Suk Soon
    • 한국작물학회지
    • /
    • 제49권5호
    • /
    • pp.381-388
    • /
    • 2004
  • In Korea, production of super sweet corn has been economically feasible and is substituting for traditional sweet corn due to better flavor in recent years. Major limiting factors for super sweet corn production are low field emergence and low seedling vigor. The optimum water potential (WP) for the priming of normal and aged seeds of dent, sweet (su) and super sweet (sh2) corns was studied to improve low seed quality. Seeds were primed at 0, -0.3, -0.6, -0.9, and -1.2 MPa of polyethylene glycol (PEG) 8000 solution at $15^{\circ}C$ for 2 days. Priming effects differed depending on the type of corn, seed quality, and WP of PEG solution. Although WP of priming solution did not influence the emergence rate of extremely high quality normal dent corn seeds, it reduced time to $50\%$ emergence (T50) and increased plumule weight. In contrast, the emergence rate of aged field corn was improved by seed priming at 0 MPa and plumule weight and $\alpha-amylase$ activity was enhanced. The optimum WP for both normal and aged sweet and super sweet corn seeds was between -0.3 and -0.6 Mpa. At the optimum WP emergence rate, $\alpha-amylase$ activity, and content of DNA and soluble protein increased, while T50 and leakage of total sugars and electrolytes reduced.