• Title/Summary/Keyword: electroluminescence(EL)

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Photoluminescent and Electroluminescent Characteristics of Thin Films of Terbium Complex with Various Ligand Prepared by Vacuum Evaporation Method (진공 증착법에 의한 다양한 Terbium Complexes 박막의 광학적 및 전기적 특성 연구)

  • 표상우;이명호;이한성;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.315-318
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    • 1998
  • Organic light-emitting diodes(OLEDs) or electroluminescent devices have attracted much attention because of their possible application as large-area light-emitting displays. Their structure was based on employing a multilayer device structure containing an emitting layer and a carrier transporting layer of suitable organic materials. In this study, several Tb complexes such as Tb(ACAC)$_3$(Phen), Tb(ACAC)$_3$(Phen-Cl) and Tb(TPB)$_3$(Phen) were synthesized and the photoluminescence(PL) and electroluminescence (EL) characteristics of their thin films were investigated by fabricating the devices having a structure of anode/HTL/terbium-oomplex/ETL/cathode, where TPD was used as an hole transporting and Alq$_3$ and TAZ-Si were used as an electron transporting materials. It was found that the photoluminescence(PL) and electroluminescence(EL) characteristics of these terbium complexes were dependent upon the ligands coordinated to terbium metal. Details on the explanation of electrical transport phenomena of the structure with I-V characteristics of the OLEDs using the trapped-charge-limited current(TCLC) model will be discussed.

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Low molecular amorphous spirobifluorene derivatives for blue electroluminescence

  • Lee, Hyo-Young;Oh, Ji-Young;Chu, Hye-Yong;Lee, Jeong-Ik;Kim, Seong-Hyun;Yang, Yong-Suk;Do, Lee-Mi;Zyung, Tae-Hyoung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2001.08a
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    • pp.209-212
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    • 2001
  • We report the synthesis and characterization of new alkoxy substituted spirobifluorene derivatives. The spiro compounds having alkoxy hydrocarbon chains were readily soluble in common organic solvents, having improved film-forming properties and had a significantly reduced tendency to crystallize, resulting in increasing their service lifetime. The results of DSC showed that it was amorphous. The optical and electroluminescent spectra were characterized. Electroluminescence (EL) properties of three-layer light emitting diodes (LED) of $ITO/TPD/spirobifluorene/Alq_3/LiF/Al$ as the active layer were characterized. Blue emission peaking of the EL spectrum of the three-layer device at 402 nm and a luminance of 3,125 $cd/m^2$ were achieved at a drive voltage 12.8 V. The luminous efficiency was obtained to be 1.7 lm/W. The color coordinate in CIE chromaticity is (0.16, 0.09), which is in a pure blue region. The external quantum efficiency was obtained to be 2.0%. The results indicate that the spirobifluorene compounds having alkoxy hydrocarbon chains are strongly potential blue emitters for LED applications.

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Experimental study on the effects of EVA(Ethylene Vinyl Acetate) for solar cell's long-term life (EVA(Ethylene Vinyl Acetate) 수지가 태양전지의 장기적인 수명에 미치는 영향에 관한 실험적 연구)

  • Kim, Seon Yong
    • Journal of the Korea Safety Management & Science
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    • v.17 no.4
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    • pp.397-401
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    • 2015
  • In this study, analysed the characteristics of power drop and surface damage in solar cell through high temperature and humidity test in the 3 case of EVA(ethylene vinyl acetate) and 2 case ribbon thickness. The solar cells were tested during the 500hr in $85^{\circ}C$ temperature and 85% relative humidity conditions, that excerpted standard of PV Module(KS C IEC-61215). Through the EL(Electroluminescence) shots, specimen's surface have partialy damaged. Before and after high humidity and high temperature test, ribbon thickness $200{\mu}m$ EVA1 case power drop rate was 8.463%, EVA2 case was 6.667%, EVA3 case was 6.373%. In the ribbon thickness $250{\mu}m$ EVA1 case power drop rate was 6.521%, EVA2 case was 8.517%, EVA3 case was 6.019%. EVA3 case was the lowest power and FF(fill factor) drop rate at the 2 case of ribbon thickness, because EVA3 is laerger than EVA1 and EVA2 in thickness, elongation and tensile strength.

Development and Luminescent Characteristics of $CaSiN_2$ Based Phosphors ($CaSiN_2$를 모체로 하는 형광체의 개발 및 발광 특성)

  • Lee, Soon-Seok;Lim, Sung-Kyoo
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.10
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    • pp.31-36
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    • 1999
  • The $CaSiN_2:Eu$ and $CaSiN_2:Tb$ phosphors were synthesized and analyzed to develop new nitride compound phosphors. $Ca_3N_2$, $Si_3N_4$ and $EuF_3$(or $TbF_3$) powders were mixed, cold-pressed, and sintered to synthesize $CaSiN_2:Eu$ and $CaSiN_2:Tb$ phosphors. Photoluminescence(PL) and electroluminescence(EL) characteristics of the synthesized phosphors were measured and found to be similar to general emission spectra of 뗘 and Tb ion, respecticely. Threshold voltage($V_{th)$) and luminance of the $CaSiN_2:Eu$ TFEL device fabricated by sputtering were 90 V and 1.62 $cd/m^2$ at 280 V, respectively. The charge-voltage(Q-V) and transferred charge-phosphor field($Q_t-F_p$) characteristics of the TFEL devices were also measured.

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Efficient orange-red OLED using a new DCM derivative as a doping molecule

  • Hwang, Do-Hoon;Lee, Jong-Don;Lee, Moon-Jae;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.579-581
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    • 2004
  • A new DCM derivative containing the phenoxazine moiety (DCPXZ) has been synthesized for use as a red fluorescent dye molecule in organic light-emitting diodes (OLEDs). The photoluminescence and electroluminescence properties of DCPXZ were examined. The maximum photoluminescence of DCPXZ in chloroform solution ($10^{-5}$ mol) was observed at 616 nm. EL devices were fabricated with the structure ITO/PEDOT-PSS/Cu-PC(15nm)/${\alpha}$-NPD(45nm)/$Alq_3$:DCPXZ(30nm)/$Alq_3$(30nm)/LiF(0.5nm)/Al. The maximum EL emission for the 2.0% DCPXZ-doped device was at 608 nm with CIE coordinates (0.57, 0.42). The EL device exhibited a maximum brightness of 15,000 cd/$m^2$ at 19.4 V and a power efficiency of 1.04 lm/W at a luminance of 100 cd/$m^2$.

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Growth and Characterization of SrS:Ce Thin Films for Blue EL Devices (청색발광 EL소자용 SrS:Ce박막의 제작과 기초적 물성)

  • 이상태
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.6
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    • pp.1272-1280
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    • 2001
  • SrS:Ce thin films for blue EL devices were prepared by Hot Wall Method and their crystallographic and optical characteristics were investigated by various methods. Deposition rates were increased with SrS cell temperature, but the rates were independent on substrate temperature and sulfur pressure. The optical and crystallographic characteristics were strongly affected by deposition rates. The band gap energies obtained by optical transmission spectra and Full Width at Half Maximum of (200) plane in X-ray diffraction patterns were found at 4.5-4.6eV and $0.22~0.26^{\circ}$, respectively. The photoluminescence from SrS:Ce thin tiles showed a greenish blue omission peaked at 470 and 540nm.

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A Emission Property of Powder EL device at 60Hz (상용주파수(60Hz)에서 후막 EL소자의 발광특성)

  • 오주열;정병선;이종찬;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.303-306
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    • 1998
  • Electroluminescence is occurred when phosphor is located in electric field. Object of this research show powder electroluminescent device (PELD) for high brightness compared with conventional PELD. Single layer of PELD structured as follow (ITO/phosphor + dielectric/silver paste). To investigate optical properties of PELDS, EL spectrum, CIE coordinate system, Brightness of PELDs was measured. The suitable ratio between phosphor and dielectric in single layer of PELD was 7:3(phosphor: dielectric). At 200 V4OO Hz, high performance of PELD which had ratio of 7:3

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Microcavity Effect of Top-emission Organic Light-emitting Diodes Using Aluminum Cathode and Anode

  • Lee, Chang-Jun;Park, Young-Il;Kwon, Jang-Hyuk;Park, Jong-Wook
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1344-1346
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    • 2005
  • We report microcavity effect of top emission organic light-emitting diodes (OLEDs) by using Al cathode and anode, which are feasible for not only top emission EL and angle dependant effects but facile evaporation process without ion sputtering. The device in case of $Alq_3$ green emission showed largely shifted EL maximum wavelength as 650 nm maximum emission. It was also observed that detection angle causes different EL maximum wavelength and different CIE values in R, G, B color emission. As a result, the green device using $Alq_3$ emission showed 650 nm emission ($0^{\circ}$) to 576 nm emission ($90^{\circ}$) as detection angle changed. We believe that these phenomena can be also explained with microcavity effect which depends on the different length of light path caused by detection angle.

Synthesis and Electroluminescent Properties of Diphenyl Benzeneamine Derivatives as Dopant Material

  • Seo, H.J.;Park, H.C.;Chung, T.G.;Lee, S.E.;Park, J.W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.955-958
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    • 2003
  • We report the photo-(PL) and electroluminescence (EL) properties of new conjugated compounds based on diphenyl benzeneamine moiety, 4,4'-(1,4-phenylenedi-(1E)-2,1-ethenediyl]bis(N,N-diphenyl-benzenamine](PEDB) and 4,4'-([1,1 -biphenyl]-4,4'-diyldi-2,1-ethenediyl)bis[N,N-diphenyl-benzenamine)(BPEDB), as emitting materials and dopant materials. The ITO/m-MTDATA/NPB/DPVBi + BPEDB(1%) /Alq3/LiF/Al device shows blue EL spectrum at 458nm and high efficiency(5.3 cd/A). PEDB as dopant shows also blue EL spectrum around ${\lambda}$ max=463nm and 4.1 cd/A high efficiency in ITO/m-MTDATA/NPB/DPVBi + PEDB(1%)/Alq3/LiF/Al device.

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Synthesis and Electroluminescent Properties of Cabazolyl Vinylene Derivatives

  • Seo, H.J.;Park, H.C.;Lee, S.E.;Park, J.W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.952-954
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    • 2003
  • We report the photo-(PL) and electroluminescence (EL) properties of new conjugated compounds based on carbazolyl vinylene moiety, 3,3'-(1,4-phenylene di-2,1-ethenediyl) bis[9-ethyl-(E,E)-9H-carbazole](PEEC) and 3,3'-([1,1'-biphenyl]-4,4'-diyldi-2,1-ethenediyl)bis[9-ethyl-9H-carbazole](BPEEC), as emitting materials. The ITO/m-MTDATA/NPB/BPEEC/Alq3/LiF/Al device shows bluish-green EL spectrum at 490nm and turn-on voltage at 8V. PEEC shows bluish-green EL around ${\lambda}$ max=496nm and turn-on voltage at 6V and 2.4 Cd/A efficiency in ITO/m-MTDATA/NPB/PEEC/Alq3/LiF/Al device.

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