• 한국정밀공학회지
• /
• 제15권7호
• /
• pp.78-84
• /
• 1998

The problem of autobody corrosion has been addressed over the past decade by the increasing use of zinc and zinc alloy coated steels in automotive application. This paper describes the evaluation of formability, weldability and painted corrosion performance of galvalume steel sheet. This paper presents an overview of the program and some initial test results on the weldability, lifetime of the electrode tip shape of the spot welding and corrosion protection. Galvalume steel sheet improved corrosion performance and spot weldability of galvalume steel sheet was not changed under the influence of the variation of welding current. And tip shape has influenced on the lifetime of tip for galvalume steel sheet.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
• /
• pp.46-48
• /
• 2004

A micro-scale discharge device has been fabricated using MEMS technology and failure mechanisms during DC discharge are investigated for the microstructure. The failure of sustaining the plasma is mainly caused by either open or short of the micro-electrodes, both resulting from the sputtered metal atoms during the DC discharge. The glow discharge lifetime of the microstructures is found to depend on bias circuit scheme as well as the electrode structure. Based on the understanding of the failure mechanism, a novel microstructure is suggested to improve discharge lifetime and the longer lifetime is experimentally demonstrated. In addition to the failure mechanism, an electric breakdown between two electrodes with microns gap are studied using micromachined metal structures. The electrode gap is able to be accurately controlled by thickness of a sacrificial layer and the electric breakdown was measured while varying the gap from $2{\mu}m$ to $20{\mu}m$. The electric breakdown behavior was found to highly depend on the electrode material, which was not considered in Paschen's law.

• 분석과학
• /
• 제8권4호
• /
• pp.623-630
• /
• 1995

Silicone rubber-based sodium-selective membranes are developed for solid-state ion sensors. It was shown that the potetiometric performance of SR-based membranes are greatly dependent on the type of neutral carriers employed; among the three ionophores, N,N,N',N'-tetracyclohexyl-1,2-phenylenedioxydiacetamide (ETH 2120), bis[(12-crown-4)methyl]dodecylmethylmalonate (D12C4DMM) and monensin methyl ester (MME), examined, only ETH 2120 was compatible with the SR-based matrix. Addition of about 20 wt% plasticizer to the SR-based matrix provided the resulting membranes with potentiometric properties essentially equivalent to those of the corresponding PVC-based membranes. Owing to the strong adhesive strength of SR-based membranes, the CWEs coated \vith those membranes exhibited long lifetime with conventional electrode-like performance. Blending of PU into the SR matrix increased the lifetime of CWEs from two weeks to one month.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2007년도 Techno-Fair 및 추계학술대회 논문집 전기물성,응용부문
• /
• pp.188-189
• /
• 2007

Axial magnetic field was applied into the hollow anode of plasma torch for the purpose of extension of electrode lifetime. The average arc voltage increased because the arc column became longer, the arc voltage ripple frequency became low. The steady state of arc voltage was removed by applied magnetic filed. The lifetime of electrode was over 1000 hours which is 100 times longer than operation without magnetic field.

• Bulletin of the Korean Chemical Society
• /
• 제33권2호
• /
• pp.469-472
• /
• 2012

Intensity modulated photocurrent spectroscopy and intensity modulated photovoltage spectroscopy were investigated to measure the dynamic response of charge transfer and recombination in the standard, $TiCl_4$-treated and the combined scattering layer electrode dye-sensitized solar cells (DSSCs). IMPS and IMVS provided transit time ($\tau_n$), lifetime ($\tau_r$), diffusion coefficient ($D_n$) and effective diffusion length ($L_n$). These expressions are derived that generation, collection, and recombination of electrons in a thin layer nanocrystalline DSSC under conditions of steady illumination and with a superimposed small amplitude modulation. In this experimental, IMPS/IMVS showed that the main effect of $TiCl_4$ treatment is to suppress the recombination of photogenerated electrons, thereby extending their lifetime. And the Diffusion coefficient of combined scattering layer electrode is $6.10{\times}10^{-6}$ higher than that of the others, resulting in longer diffusion length.

• Journal of Electrochemical Science and Technology
• /
• 제10권3호
• /
• pp.321-328
• /
• 2019

A new miniaturized all solid-state contact Fe (III)-selective PVC membrane electrode based on Fe (II) phthalocyanine as a neutral carrier was described. The effects of the membrane composition and foreign ions on the electrode performance was investigated. The best performance was obtained with a membrane containing 32% poly (vinyl chloride), 64% dioctylsebacate, 3% Fe (II) phthalocyanine, and 1% potassium tetrakis (p-chlorophenyl) borate. The electrode showed near Nernstian response of $26.04{\pm}0.95mV/decade$ over the wide linear concentration range $1.0{\times}10^{-6}$ to $1.0{\times}10^{-1}M$, and a very low limit of detection $1.8{\pm}0.5{\times}10^{-7}M$. The potentiometric response of the developed electrode was independent at pH 3.5-5.7. The lifetime of the electrode was approximately 3 months and the response time was very short (< 7 s). It exhibited excellent selectivity towards Fe (III) over various cations. The miniaturized all solid-state contact Fe (III)-selective membrane electrode was successfully applied as an indicator electrode for the potentiometric titration of $1.0{\times}10^{-3}M$ Fe (III) ions with a $1.0{\times}10^{-2}M$ EDTA and the direct determination of Fe (III) ions in real water samples.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
• /
• pp.112-114
• /
• 2009

Charge injection at electrode-organic interfaces is key to the performance, lifetime and stability of organic electronic devices. The link between fundamental material properties and the energy-level alignment at electrode-organic interfaces will be discussed. In addition the impact of the injection barrier height-a parameterization of the energylevel alignment-on device characteristics will also be discussed.

• Bulletin of the Korean Chemical Society
• /
• 제26권6호
• /
• pp.882-886
• /
• 2005

Copper(II) ion-selective PVC membrane electrode based on 2-mercaptobenzoxazole as a new ionophore and o-nitrophenyl octyl ether (o-NPOE) as plasticizer is proposed. This electrode revealed good selectivity for $Cu^{2+}$ over a wide variety of other metal ions. Effects of experimental parameters such as membrane composition, nature and amount of plasticizer, and concentration of internal solution on the potential response of $Cu^{2+}$ sensor were investigated. The electrode exhibits good response for $Cu^{2+}$ in a wide linear range of 5.0 ${\times}$ 10−.6-1.6 ${\times}$ $10^{-2}$ mol/L with a slope of 29.2 ${\pm}$ 2.0 mV/decade. The response time of the sensor is less than 10 s, and the detection limit is 2.0 ${\times}$ $10^{-6}$ mol/L. The electrode response was stable in pH range of 4-6. The lifetime of the electrode was about 2 months. The electrode revealed comparatively good selectivities with respect to many alkali, alkaline earth, and transition metal ions.

• 한국표면공학회지
• /
• 제49권1호
• /
• pp.87-91
• /
• 2016

The development of high performance transparent electrode with flexibility have been required for flexible electronics. Here, we demonstrate the silver nanowire and reduced graphene oxide hybrid transparent electrode for replacing brittle indium-tin-oxide electrode by spray coating technique and plasma reduction. The spray coating system is applied to deposit silver nanowire and over coated graphene oxide films and it has a great potential to scale-up. The resistance of silver nanowire transparent electrode is reduced by 10% and the surface roughness is decreased after graphene oxide coating. The over-coated graphene oxide is successfully reduced by $H_2$ plasma treatment and it is effective in increasing the environmental stability of electrode. The lifetime of silver nanowire and reduced graphene oxide hybrid electrode at $85^{\circ}C$ of Celsius degree of temperature and 85% of relative humidity has much increased.

• 분석과학
• /
• 제7권2호
• /
• pp.149-153
• /
• 1994

Squash-조직을 graphite rod disk 전극에 고정하여 메탄올 용매 속에서 L-ascorbic acid(AA)를 정량할 수 있는 전류법 바이오센서를 만들었다. 전극의 검출한계는 $2{\times}10^{-6}M$이었다. 순수한 ascorbate oxidase(AO)를 고정시켜 만든 전극에 비해 식물 조직에 들어 있는 효소로 만든 이 전극은 생촉매의 활성도가 높고 안정성이 좋았으며(1주간) 대단히 값싸게 만들 수 있었다.