• Title/Summary/Keyword: electrode impedance

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Fuel Cell Performance by the Impedance Method (임피던스법을 이용한 연료전지의 특성 연구)

  • 서장수;김귀열;명기환;이성일;김용주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.927-933
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    • 2000
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO3 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way , Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a results, the performance of Ni-YSZ anode(40vo1%) was better excellent than the others.

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Repassivation Characteristics of Fe-Cr Steels Using the Abrading Electrode Technique in Aqueous 0.1M $Na_2SO_4+ NaCl$ Solutions (0.1M $Na_2SO_4+ NaCl$ 수용액에서 마멸 전극 기법을 이용한 Fe-Cr강의 재부동태 특성)

  • Ham Dong Ho;Lee Jae Bong
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.195-201
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    • 1999
  • The repassivation characteristics of Fe-Cr steels in deaerated 0.1 M $Na_2SO_4$ solution have been investigated with the variation of Cr content, applied potential and Cl- concentration. In the absence of chloride ion, abrading electrode test showed that, slope -n, of log i=k -n log t, a parameter of repassivation rate, approached to -1, regardless of Cr content but as Cr content increased, repassivation current density decreases with increasing Cr content. A.C. Impedance spectroscopy showed that the charge transfer resistance of passive film became higher as Cr content and applied potential increased. However, in the presence of chloride ion, it was observed that chloride ion suppressed the passive film formation, whose effect became greater with increasing applied potential.

Evaluation of Electrical Characteristics on Semiconducting Ceramics Using Complex Impedance Resonance Method (반도성 세라믹스에서 복소임퍼던스 공진법을 이용한 전기적 특성의 평가)

  • 윤상옥;정형진;윤기현
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.869-873
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    • 1994
  • Electrical properties of each interfacial layers on semiconducting ceramics have been analized and evaluated by complex impedance resonance method as functions of ambient temperatures and applied voltages. From the analytical results, it can be observed that the interfacial layers in a semiconducting ceramics vary individually with the ambient temperature and then this influence the total properties. Also, it has been confirmed that the applied voltage on semiconducting ceramics affect mainly the electrode interface, and thus the resistance and capacitance decrease due to the variation of potential barrier layers.

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Fabrication of electrodes on mcirochannel side wall using shadow evaporation effect (샤도우 증착 효과를 이용한 마이크로 채널내 측벽 전극 제작)

  • 강길환;김규만
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1462-1465
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    • 2004
  • A new method to fabricate metal electrodes on side wall of the microchannel is presented. Coulter counter allows to count the number of cell passing through the microchannel by detecting impedance variation between two electrodes. The relative position of two electrodes is important for sensitivity of impedance measurement. 100nm thick Al electrodes are deposited on the channel side wall by means of shadow evaporation.

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Fabrication and Characterization of MEA (MEA의 제작 및 특성 평가)

  • Seong, Nak-Seon;Pak, Jung-Ho
    • Proceedings of the KIEE Conference
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    • 2000.11d
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    • pp.857-859
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    • 2000
  • A planar MEA(Multi-channel Electrode Array) has been developed for monitoring the electrical activity of electrogenic cells in a cell culture by an extracellular recording. The material, fabrication process, characterization of the array, cleaning effect and impedance according to opening size by impedance measurement are described.

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Study to Analyze the Grounding System in the 20 kHz Power Installation (20 kHz 전력설비 접지시스템 분석에 관한 연구)

  • Jung, Jin-Soo;Han, Woon-Ki;Park, Chan-Urm;Song, Young-Sang;Lim, Hyun-Sung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.9
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    • pp.1308-1312
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    • 2013
  • In this paper, carried out for optimal ground system for ensuring safety for electricity used to power equipment in the 20 kHz frequency. Now the grounding system of the mesh electrode, electrode rods are installed for power plant safety and protection against electric shock. However, the electrical equipment grounding system in the 20 kHz were considering the increasing grounding impedance due to the high frequency and the magnetic shielding. But until now, there has been little research on the grounding system. To solve this problem, In this paper was proposed optimal grounding system due to the experiment using a mesh electrode, rod electrode, aluminum plate electrodes. Measurement results, grounding resistance was depending on the material of the electrode grounding resistance. In addition, the leakage current (induced) appeared to be affected depending on the type of electrode.

Optimization of Capacitance Balance for a Hybrid Supercapacitor Consisted of LiMn2O4/AC as a Positive and AC Negative Electrode

  • Cho, Min-Young;Park, Sun-Min;Lee, Jae-Won;Roh, Kwang-Chul
    • Journal of Electrochemical Science and Technology
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    • v.2 no.3
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    • pp.152-156
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    • 2011
  • A hybrid supercapacitor is fabricated using a composite material from $LiMn_2O_4$ (LMO) and activated carbon (AC) as the positive electrode and AC as the negative electrode to form the (LMO + AC)/AC system. Volume ratio (positive : negative) of electrodes is controlled to investigate of the power and energy balance. The (LMO + AC)/AC system shows better performances than the LMO/AC system. Especially, electrochemical impedance spectra, rate charge.discharge and cycle performance testing show that the (LMO + AC)/AC system have an outstanding electrochemical performance at volume ratios of (LMO + AC)/AC = 1 : 1.7 and 1 : 2. Electric double layer capacitor (EDLC) capacitance between AC of the positive electrode and AC of the negative electrode improves power density without loss of capacitance. Stable capacitance is achieved by lowering the positive electrode resistance and balancing the energy and power densities between the positive and negative electrodes by the addition of AC to the positive electrode at high current density.

Impedance Spectroscopy of (Pb0.92La0.08)(Zr0.95Ti0.05)O3 Ceramics above Room Temperatures

  • Jong-Ho Park
    • Korean Journal of Materials Research
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    • v.34 no.5
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    • pp.242-246
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    • 2024
  • La modified lead zirconate titanate ceramics (Pb0.92La0.08)(Zr0.95Ti0.05)O3 = PLZT-8/95/5 were prepared using the conventional solid state reaction method in order to investigate the complex impedance characteristics of the PLZT-8/95/5 ceramic according to temperature. The complex impedance in the PLZT-8/95/5 ceramic was measured over a temperature range of 30~550 ℃ at several frequencies. The complex dielectric constant anomaly of the phase transition was observed near TU1 = 179 ℃ and TU2 = 230 ℃. A remarkable diffuse dielectric constant anomalous behaviour of the complex dielectric constant was found between 100 ℃ and 550 ℃. The complex impedance spectra below and above TU1 and TU2 were fitted by the superposition of two Cole-Cole types of impedance relaxations. The fast component in the higher frequency region may be due to ion migration in the bulk, and the slow component in the lower frequency region is interpreted to be the formation and migration of ions at the grain boundary or electrode/crystal interfacial polarization.

Interface Reaction Between LSMC and YSZ and Impedance Properties (LSMC와 YSZ의 계면반응 및 임피던스 특성)

  • 김재동;김구대;문지웅;김창은;이해원
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.899-904
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    • 1998
  • Interface reaction between LSMC and YSZ is discussed with chemical composition of LSMC. The reac-tivity between LSMC and YSZ increased with increasing Co amount and A-site deficient perovskite is very effective on reducing reactivity. The (La0.8Sr0.2)xMn0.8Co0.2O3 (X=0.9-1) composition is not reactive with YSZ in experimental range. The electrode reaction reaction resistance increases due to reaction product.

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Potential of Perchlorate Ion-Selective Electrode in PVC Membrane and Electrode Characteristics by ac Impedance (과염소산 이온선택성 PVC막 전극전위와 임피던스에 의한 전극특성)

  • 김경민;조경섭;강안수
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.49-52
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    • 1998
  • 1. 서론 : 화약이나 고체 충진제, 고체로\ulcorner 추진제의 산화제, slurry blasting agent 및 동물사료의 식품첨가제로 사용되고 있는 과염소산은 발화나 폭발성이 매우 강한 산화제로 정확한 순도를 측정하는 것은 중요하다. 용량분석법과 중량분석법에 비교하여 조작이 간단하고 편리한 과염소산이온의 농도를 직접 측정할 수 있는 PVC막 전극에 대한 많은 연구가 진행되고 있다. (생략)

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