• Title/Summary/Keyword: electrochemical

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Machining of Micro Grooves using Hybrid Electrochemical Processes with Voltage Pulses (펄스 전기화학 복합가공기술을 적용한 미세 그루브 가공)

  • 이은상;박정우;문영훈
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.9
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    • pp.32-39
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    • 2003
  • Pulse electrochemical machining process with high or low current density may produce a non-lustrous surface on workpiece surface. The usual polishing process to remove a black layer from the surface has been hand polish the part. But the milli-to-micro meter scale structure formed by the electrochemical machining process may be destroyed while polishing process. The application of ultra short voltage pulses based on the analysis of electrical double layer charging process allows high resolution electrochemical machining and polishing. This technique was based on the specific polarization resistance from the comparison of ideal and experimental potential variation during short voltage pulses.

Micro Electrochemical Machining of Stainless Steel Using Citric Acid (구연산을 이용한 스테인레스 스틸의 미세 전해가공)

  • Ryu, Shi-Hyoung
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.3
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    • pp.134-140
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    • 2008
  • Micro electrochemical machining (ECM) is conducted on stainless steel 304 using non-toxic electrolyte of citric acid. Electrochemical dissolution region is minimized by applying a few hundred second duration pulses between the tungsten SPM tip and the work material. ECM characteristics according to citric acid concentration, feeding velocity and electric conditions such as pulse amplitude, pulse frequency, and offset voltage are investigated through a series of experiments. Micro holes of $60{\mu}m$ in diameter with the depth of $50{\mu}m$ and $90{\mu}m$ in diameter with the depth of $100{\mu}m$ are perforated. Square and circular micro cavities are also manufactured by electrochemical milling. This research can contribute to the development of safe and environmentally friendly micro ECM process.

Electrochemical behaviors of Indium

  • Chung, Yong-Hwa;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • v.3 no.1
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    • pp.1-13
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    • 2012
  • Many researchers focus on indium contained semiconductors and alloy compounds for their various applications. Electrochemists want to obtain indium contained compounds simply via one-step electrodeposition. First of all, electrochemistry of constituent elements must be understood in order to develop the best condition for the electrodeposition of indium contained compounds. We will review the electrochemistry of indium. Equilibria between indium metal and indium ions and the standard electrode potentials of the equilibria will be reviewed. The electrochemical reactions of indium species are affected by surrounding conditions. Thus dependences of electrochemical behaviors of indium metal and indium ions on various parameters will be reviewed.

A study on the Micro Surface Electrochemical Machining for Aluminum Alloy (알루미늄에 대한 미세 표면 전해가공에 관한 연구)

  • 백승엽;이은상;원찬희
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.214-217
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    • 2002
  • Micro Surface Electrochemical Machining has traditionally been used in highly specialized fields such as those of the aerospace and defense industries. It is now increasingly being applied in other industries where parts with difficult-to-cut material, complex geometry and tribology such as compute. hard disk drive(HDD) are required. Pulse Electrochemical Micro-machining provides an economical and effective method for machining high strength, high tension, heat-resistant materials into complex shapes such as turbine blades of titanium and aluminum alloys. Usually aluminum alloys are used bearings to hard disk drive in computer. In order to apply aluminum alloys to bearing used in hard disk drive, this paper presents the characteristics of Micro Surface Electrochemical machining for aluminum alloy.

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Electrochemical Sensor for Detecting Underwater Biofilm Using Cyclicvoltammetry (순환전압전류법을 이용한 수중 생물막 측정 전기화학센서)

  • Hwang, Byeong-Jun;Lee, Sung-Ho
    • Journal of Sensor Science and Technology
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    • v.21 no.5
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    • pp.374-378
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    • 2012
  • Biofouling causes many problem in industrial processes, medical health industries, water utilities and our daily life. So detecting formation of biofilm on the surface of medical appliance, water pipe and industrial utility is highly important to prevent the problem caused by biofouling. In this study, we suggest an electrochemical sensor for detecting biofilm. We fabricated the electrochemical sensor in MEMS process and cultivated two different kinds of Pseudomonas aeruginosa RpoN type and Wild type on the surface of electrochemical sensor. Each group of Pseudomonas aeruginosa was cultivated according to the hours of 2, 4, 6, 8, 12 and 24. Then we investigated changes in degree of biofilm cultivation using cyclic voltammetry. As a result, it was observed that peak of the cyclic voltammetry curve is increased according as the biofilm growth on the surface of electrochemical sensor. Also we can discern between Pseudomonas aeruginosa RpoN type and Wild type.

Study on Electrochemical Performance of Solid-State-Electrode on Steel bar in Chloride Solution (염화물 수용액 중의 철근에 대한 고체전극의 전기화학적 성능 연구)

  • Park, Dong-Jin;Park, Jang-Hyun;Lee, Han-Seung;Subbiah, Karthick
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.147-148
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    • 2018
  • In order to compare the electrochemical performance with that of Calomel Electrode, MnO2 solid-state-electrode was fabricated and its potential and impedance were measured in chloride aqueous solution. As a result, the SCPS without chloride ions showed a potential of -200 mV or more and an impedance over 2000 Ωcm, but the potential below -600 mV and the impedance below -200 Ωcm showed as the chloride concentration in the solution increased. It is considered electrochemical studies on the corrosion of rebar are necessary for the MOE, which shows the same tendency as SCE and exhibits electrochemical performance, over the Mortar level in the future.

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Electrochemical Rectification at Electrode Chemically Modified with Redox Active Agents at Monolayer (산화환원 화학 종이 단 분자 층으로 화학 흡착된 전극에서의 전기화학적 정류)

  • Lee, Chi-Woo J.;Yoon, Jung-Hyun;Oh, Mi-Kyung
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.43-47
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    • 2007
  • Electrochemical rectification at electrode chemically modified with redox active agents isolated at monolayer level was considered. Formulation of the rising part of linear sweep voltammogram at steady and rotating disc electrode was introduced.

Electrochemical Machining Using a Disk Electrode for Micro Internal Features (미세 내부 형상 가공을 위한 디스크 전극 이용 전해 가공)

  • Jo, Chan-Hee;Kim, Bo-Hyun;Chu, Chong-Nam
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.7
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    • pp.139-144
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    • 2008
  • Micro electrochemical machining was investigated to machine micro internal features. This method uses a micro disk tool electrode and can easily machine micro features inside of a micro hole, which are very difficult to make by the conventional processes. In order to limit the machining area and localize the electrochemical dissolution, ultra short pulses were used as power source and a micro disk electrode with insulating layer on its surface was used as a tool electrode. By electrochemical process, internal features, such as groove array, were fabricated on the stainless steel plate.

Electrochemical Properties of Novel Metal Powder Electrodes for Polymer Electrolyte Membrane Electrolysis

  • Kim, Chang-Hee;Kang, Kyung-Soo;Park, Chu-Sik;Hwang, Gab-Jin;Bae, Ki-Kwang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1227-1228
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    • 2006
  • The electrochemical properties of novel metal powders were investigated for the electrode materias of polymer electrolyte memebrane electrolysis. Two types of Pt black and $IrO_2$ powder electrodes were hot-pressed on the polymer electrolyte membrane to form membrane electrode assembly. The galvanodynamic polarization methode was used to characterize the electrochemical properties of both electrodes. From the experimental results, we concluded that the $IrO_2$ powder electrode exhibits better electrochemical performance than Pt black as cathode material for the electrolysis.

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Electrochemical Properties of Cross-linked Polyurethane Acrylate-Based Gel Polymer Electrolyte

  • Kim, Hyun-Soo;Kim, Sung-Il;Choi, Gwan-Young;Moon, Seong-In;Kim, Sang-Pil
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.197-201
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    • 2002
  • In this study, a gel polymer electrolyte was prepared from urethane acrylate and its electrochemical performances were evaluated. And, $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. Ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.7\times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed electrochemical stability up to potential of 4.5V vs. $Li/Li^+.LiCoO_2/GPE/graphite$ cell showed a good high-rate and a low-temperature performance.