• The Journal of Engineering Geology
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• v.21 no.4
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• pp.323-336
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• 2011

The hydro-mechanical behavior of the Earth's crust is strongly dependent on the fractional volume and geometrical structure of effective pore spaces. This study aims to understand the characteristics of pores using electrical impedance. We measured the electric impedance of core samples (diameter, 38-50 mm; length, 70-100 mm) of three types of granite (Hwangdeung, Pocheon, and Yangsan) and two types of sandstone (Boryung and Berea) with different porosities and pore structures, after saturation with saline water of varying salinities. The results show that resistance decreases but capacitance increases with increasing salinity of the pore fluid. For a given salinity, the resistivity and formation factor are reduced with increasing porosity of the rocks, and the capacitance increases. Berea sandstone shows anisotropy in resistance, tortuosity, and cementation factor, with these factors being highest normal to bedding planes. This result indicates that the connectivity of pores is weakest normal to bedding. In conclusion, the electrical characteristics of the tested samples are related not only to their porosity but also to the pore geometry.

• Applied Chemistry for Engineering
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• v.16 no.5
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• pp.689-692
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• 2005

In order to improve the electrochemical performances of Li-ion batteries when spinel $LiMn_2O_4$ is employed as a cathode active material, binary conductive agents were prepared using two different particle-sized carbons like Super P Black and $Vulcan^{(R)}$ XC-72R. The electrochemical performances of the $LiMn_2O_4$ cell system using binary conductive agents were evaluated in terms of specific charge and discharge capacities and cycle life. The cell with binary conductive agent in the 3:7 weight ratios of Super P Black and $Vulcan^{(R)}$ XC-72R showed better electrochemical performances due to the proper combination of ionic diffusion rate and electric contact.

• Analytical Science and Technology
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• v.10 no.4
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• pp.231-239
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• 1997

We developed a procedure that can effectively separate and determine tertiary amines and quaternary ammonium salts in some samples with reverse phase ion-pair high performance chromatography, employing indirect spectrophotometric detection method. Detection and ion-pairing reagents used in this study were benzyl trimethylammonium chloride (BTMACl) and sodium dodecyl sulfate(DDSANa), respectively. Eluting the electrolyte solutions of some commercial electrolytic capacitors with a MeOH(40):water(60) eluent (pH 8.5 adjusted with NH4Cl-NH3 buffer) containing 0.010M DDSANa and 0.004 M BTMACl through Supelco LC-18 or ${\mu}$-Bondapak phenyl column, amines and ammonium salts contained in the sample were successfully separated and determined. Varying the composition, especially the content of quaternary ammonium salts, of electrolyte solutions based on this analysis. we could prepare the low impedance(0.08~0.13) electrolytic capacitors with excellent electrical properties and it was a confirmation that the analysis is favorable.

• Journal of the Korean Society for Nondestructive Testing
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• v.20 no.1
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• pp.33-37
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• 2000

The 1-3 piezoelectric composite transducer with 75 volume percents PZT was fabricated by the dicing-filling method. The resonance modes of the 1-3 transducer have been studied with electric impedance measurement as a function of frequency. The fundamental frequencies of the planar and thickness mode were observed at 0.95MHz and 1.63MHz respectively, but the lateral mode was not observed. In the thickness mode, the electromechanical coupling coefficient of the 1-3 piezoelectric composite transducer, 0.54, was very closed to that of the single phase PZT(0.52). The pulse-echo response by exciting the 1-3 transducer with an electric pulse was observed from the water/reflector interface, and analyzed bandwidth by the spectrum of the impulse response. The quality factor Q for the 1-3 transducer was observed as 1.5 smaller than that of the single phase(80) and then the 1-3 transducer may be used to the broad band type transducer applications.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.4
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• pp.103-109
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• 2010

In this paper, breakdown characteristics of soil in a coaxial cylindrical electrode system stressed by impulse currents were experimentally investigated. The breakdown voltage and current waveforms for 4 types of soils were measured, and the threshold electric field intensity, the time-lag to breakdown and the voltage-current (V-I) curves were analyzed and discussed. As a result, the breakdown voltage and current waveforms are strongly dependent on the grain size of soil, and the voltage and current waveforms for gravel and sand differ from those for silt and loess. The threshold electric field intensity Ec is increased in the order of gravel, sand, loess and silt. The V-I curves for all test samples show a 'cross-closed loop' of ${\infty}$-shape. Also, the time-lag to breakdown for gravel and sand are longer than those for silt and loess. It is expected that the results presented in this paper will provide useful information on the design of improving transient performance of a grounding electrode system subjected to lightning current considering the soil ionization.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.25 no.9
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• pp.938-943
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• 2014

The scattered field by a gap/crack on the PEC surface of a large object having low-observable RCS cannot be negligible, but may not be analyzed by the known high-frequency technique. If the electrical width of the crack is very small, the crack can be modeled by an impedance strip, whose scattering formulation can be analytically obtained based on a low-frequency approximation. The scattering solution is formulated for the 2D strip and TE(Transverse Electric) or TM(Transverse Magnetic) wave incidence, from which a 3D ILDC(Incremental Length Diffraction Coefficients) can be extracted. Using the ILDC formulation, the scattering by any arbitrary shaped crack can be estimated. In this paper, an improved ILDC equations are proposed, which combine the known TE and TM solutions. The improved accuracy of the proposed solution is numerically verified.

• Proceedings of the Korean Society of Medical Physics Conference
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• 2002.09a
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• pp.396-399
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• 2002

Intense quasi-monochromatic x-ray irradiation from the linear plasma target is described. The plasma x-ray generator employs a high-voltage power supply, a low-impedance coaxial transmission line, a high-voltage condenser with a capacity of about 200 nF, a turbo-molecular pump, a thyristor pulse generator as a trigger device, and a flash x-ray tube. The high-voltage main condenser is charged up to 55 kV by the power supply, and the electric charges in the condenser are discharged to the tube after triggering the cathode electrode. The x-ray tube is of a demountable triode that is connected to the turbo molecular pump with a pressure of approximately 1 mPa. As electron flows from the cathode electrode are roughly converged to the molybdenum target by the electric field in the tube, the weakly ionized plasma, which consists of metal ions and electrons, forms by the target evaporating. In the present work, the peak tube voltage was almost equal to the initial charging voltage of the main condenser, and the peak current was about 20 kA with a charging voltage of 55 kV. When the charging voltage was increased, the linear plasma x-ray source grew, and the characteristic x-ray intensities of K-series lines increased. The quite sharp lines such as hard x-ray lasers were clearly observed. The quasi-monochromatic radiography was performed by a new film-less computed radiography system.

• Proceedings of the KSR Conference
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• 2000.11a
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• pp.535-542
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• 2000

Pure copper, Cu-1.1wt%Cd and ACSR(Aluminum Conductor Steel Reinforced) have been used as Catenary Materials in Electric Railway System. Since these materials may have chance to be exposed to the corrosive environments like polluted air, acid rain and sea water, it is important not only to investigate the corrosion characteristics but also to measure corrosion rates in various corrosive environments. In order to examine corrosion characteristics according to the dissolved oxygen content, pH, chloride ion concentration ion, and the addition of Cd to Cu, a series of tests such as potentiodynamic polarization. a.c impedance spectroscopy and galvanic corrosion tests were carried out in these materials. Results showed that the addition of Cd to Cu and chloride ion in the solution have an adverse effect on the resistance to corrosion. Additionally, Galvanic currents between Al and steel wires of ACSR were confirmed by using ZRA(zero resistance ammeter) method.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.49-49
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• 2008

ZnO-based varistors have been widely used for voltage stabilization or transient surge suppression in electric power systems and electronic circuits. Recently, It has reported that the varistor behavior with nonlinear coefficient of 6~17 in Mn-doped ZnO. In this study we have chosen the composition of ZnO-$TeO_2-Mn_3O_4$ (ZTM) system to the purpose of whether varistor behavior appeared in doped ZnO by the solid state sintering or not. We investigated the sintering and electric properties of 0.5~3.0 at% Mn doped ZnO-1.0 at% $TeO_2$ system. Electrical properties, such as current-voltage (I-V), capacitance-voltage (C-V), and impedance spectroscopy were conducted. $TeO_2$ itself melts at $732^{\circ}C$ in air but forms the $ZnTeO_3$ phase with ZnO as increasing temperature and therefore retards the densification of ZnO to $1000^{\circ}C$. The average grain size of sintered samples was at about $3{\mu}m$ and decreased with increasing Mn contents. It was found that a good varistor characteristics were developed in ZTM system sintered at $1100^{\circ}C$ (nonlinear coefficient $\alpha$ ~ 60). The results of C-V characteristics such as barrier height ($\Theta$), donor density ($N_d$), depletion layer (W), and interface state density ($N_t$) in ZTM ceramics were $4\times10^{17}cm^{-3}$, 0.7 V, 40 nm, and $1.6\times10^{12}cm^{-2}$, respectively. It will be discussed about the stability and homogeneity of grain boundaries using distribution parameter ($\alpha$) simulated with the Z(T)"-logf plots in ZTM system.

• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.99-105
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• 2005

In this study, the $PPy/CLO_4$ and PPy/PVS composite electrodes were prepared at various polymerization potential by incorporating electrolyte anions of different anion size during constant potential polymerization. The reulting Polypyrrole surfaces were inspected by SEM, and their electrochemical Properties were investigated with CV and ac impedance method. The results of electrochemical analysis were suggested that anion for $PPy/CLO_4$ electrode and cation fir PPy/PVS electrode were transferred during redox reaction. As constant potential of polymerization was increased, the charge transfer resistance of $PPy/CLO_4$ and PPy/PVS was decreased and the electric double layer capacitances of $PPy/CLO_4$ was higher than that of PPy/PVS. The change of PPy/PVS surface was relatively smaller than that of $PPy/CLO_4$ according to electropolymerization potential.