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Size Distributions of Particulate Matter Emitted during 3D Printing and Estimates of Inhalation Exposure (3D 프린팅 가동 조건 별 발생 입자크기 분포와 흡입 노출량 추정)

  • Park, Jihoon;Jeon, Haejoon;Park, Kyungho;Yoon, Chungsik
    • Journal of Environmental Health Sciences
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    • v.44 no.6
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    • pp.524-538
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    • 2018
  • Objective: This study aimed to identify the size distributions of particulate matter emitted during 3D printing according to operational conditions and estimate particle inhalation exposure doses at each respiratory region. Methods: Four types of printing filaments were selected: acrylonitrile-butadiene-styrene (ABS), polylactic acid (PLA), Laywood, and nylon. A fused deposition modeling (FDM) 3D printer was used for printing. Airborne particles between 10 nm and $10{\mu}m$ were measured before, during, and after printing using real-time monitors under extruder temperatures from 215 to $290^{\circ}C$. Inhalation exposures, including inhaled and deposited doses at the respiratory regions, were estimated using a mathematical model. Results: Nanoparticles dominated among the particles emitted during printing, and more particles were emitted with higher temperatures for all materials. Under all temperature conditions, the Laywood emitted the highest particle concentration, followed by ABS, PLA, and nylon. The particle concentration peaked for the initial 10 to 20 minutes after starting operations and gradually decreased with elapsed time. Nanoparticles accounted for a large proportion of the total inhaled particles in terms of number, and about a half of the inhaled nanoparticles were estimated to be deposited in the alveolar region. In the case of the mass of inhaled and deposited dose, particles between 0.1 and $1.0{\mu}m$ made up a large proportion. Conclusion: The number of consumers using 3D printers is expected to expand, but hazardous emissions such as thermal byproducts from 3D printing are still unclear. Further studies should be conducted and appropriate control strategies considered in order to minimize human exposure.

Effect of typhoons on the Korean national emergency medical service system

  • Park, Soo Hyun;Cha, Won Chul;Kim, Giwoon;Lee, Tae Rim;Hwang, Sung Yeon;Shin, Tae Gun;Sim, Min Seob;Jo, Ik Joon
    • Clinical and Experimental Emergency Medicine
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    • v.5 no.4
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    • pp.272-277
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    • 2018
  • Objective While the effect of typhoons on emergency medicine has been evaluated, data are scarce on their effects on the emergency medical service (EMS). This study evaluated the effect of typhoons on EMS patients and performance. Methods The study period was January 2010 to December 2012. Meteorological data regarding typhoons were provided by the Korean Meteorological Administration. EMS data were retrieved from the EMS database of the national emergency management agency. The database includes ambulance run sheets, which contain clinical and operational data. In this case-crossover study, the cases and controls were EMS calls on the day of typhoon warnings and calls one week prior to the typhoon warnings, respectively. Results During the study period, 11 typhoons affected Korea. A total of 14,521 cases were selected for analysis. Overall, there were no obvious differences between the case and control groups. However, there were statistically significant differences in age, place, and time requests. There were fewer patients between 0 and 15 years of age (P=0.01) and more unconscious patients (P=0.01) in the case group. The EMS operational performance, as measured by the times elapsed between call to start, call to field, and call to hospital did not differ significantly. There was also no significant difference in the time from hospital arrival between the cases (28.67, standard deviation 16.37) and controls (28.97, standard deviation 28.91) (P=0.39). Conclusion Typhoons did not significantly affect the EMS system in this study. Further study is necessary to understand the reasons for this finding.

Dispersion Model of Initial Consequence Analysis for Instantaneous Chemical Release (순간적인 화학물질 누출에 따른 초기 피해영향 범위 산정을 위한 분산모델 연구)

  • Son, Tai Eun;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.37 no.2
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    • pp.1-9
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    • 2022
  • Most factories deal with toxic or flammable chemicals in their industrial processes. These hazardous substances pose a risk of leakage due to accidents, such as fire and explosion. In the event of chemical release, massive casualties and property damage can result; hence, quantitative risk prediction and assessment are necessary. Several methods are available for evaluating chemical dispersion in the atmosphere, and most analyses are considered neutral in dispersion models and under far-field wind condition. The foregoing assumption renders a model valid only after a considerable time has elapsed from the moment chemicals are released or dispersed from a source. Hence, an initial dispersion model is required to assess risk quantitatively and predict the extent of damage because the most dangerous locations are those near a leak source. In this study, the dispersion model for initial consequence analysis was developed with three-dimensional unsteady advective diffusion equation. In this expression, instantaneous leakage is assumed as a puff, and wind velocity is considered as a coordinate transform in the solution. To minimize the buoyant force, ethane is used as leaked fuel, and two different diffusion coefficients are introduced. The calculated concentration field with a molecular diffusion coefficient shows a moving circular iso-line in the horizontal plane. The maximum concentration decreases as time progresses and distance increases. In the case of using a coefficient for turbulent diffusion, the dispersion along the wind velocity direction is enhanced, and an elliptic iso-contour line is found. The result yielded by a widely used commercial program, ALOHA, was compared with the end point of the lower explosion limit. In the future, we plan to build a more accurate and general initial risk assessment model by considering the turbulence diffusion and buoyancy effect on dispersion.

Permeability Characteristics of Geosynthetics Vertical Barrier Connections for the Prevention of Contaminants Diffusion (오염물질 확산방지를 위한 토목섬유 연직차수벽 연결부의 투수성능 평가)

  • Park, Jeong Jun
    • Journal of the Society of Disaster Information
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    • v.18 no.1
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    • pp.1-9
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    • 2022
  • Purpose: In this study, we used hydrophilic waterstop used in geosynthetics vertical barrier system to evaluate the performance of impermeability under sealing conditions. Method: ASTM D5887 and ASTM D6766 were applied to determine the capability of the connection during the geosynthetics vertical barrier system. Hydrophilic waterstop was saturated in each solution and the weight, thickness, and volume changes were analyzed over elapsed time. Hydrophilic waterstop was installed at the geosynthetics vertical barrier system connection to evaluate the permeability characteristics. Results: As the expansion reaction time of hydrophilic waterstop increased relatively under saline conditions, the decrease in permeability also showed a smaller decrease in fresh water. Furthermore, the method of engagement of the geosynthetics vertical barrier system showed somewhat better performance of the impermeability due to the large pressure resistance caused by the roll joint type than interlock type. Conclusion: In urban pollutants, which can estimate the outflow of pollutants such as oil storage facilities and industrial complexes, proactive response technologies that can prevent the contaminant diffusion can significantly reduce the damage.

A Method to Acquire Bigdata for Predicting Accidents on Power Switchboards (배전반 안전사고 예측을 위한 빅데이터 자료 획득 방안)

  • Lee, Hyeon Sup;Kim, Jin-Deog
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2021.10a
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    • pp.351-353
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    • 2021
  • In recent years, while the demand for electricity is rapidly increasing, fire accidents due to negligence in management of switchboards. In particular, switchboards for industrial and electrical resource control can cause serious problems. Thus, for the safety management of power switchboard, a secondary response is conducted to control firing when a specific condition value is satisfied, but in this case, it is highly likely that a considerable amount of time has elapsed after firing. In this paper, we propose a method to acquire big data for the development of a switchboard temperature and power control system that can actively respond to the current situation by monitoring and learning the temperature of the switchboard's busbar connection in real time. Specifically, a method for periodically acquiring and managing data such as temperature and power from various scattered sensors is proposed.

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Reduction Efficiency Analysis of Furrow Vegetation and PAM (Polyacrylamide) Mulching for Non-Point Source Pollution Load from Sloped Upland During Farming Season (경사밭 고랑 식생 및 PAM (Polyacrylamide) 멀칭에 따른 영농기 비점오염 저감효과 분석)

  • Yeob, So-Jin;Kim, Min-Kyeong;An, Nan-Hee;Choi, Soon-Kun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.65 no.4
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    • pp.1-10
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    • 2023
  • As a result of climate change, non-point source pollution (NPS) from farmland with the steep slope during the rainy season is expected to have a significant impact on the water system. This study aimed to evaluate the effect of furrow mulching using alfalfa and PAM (Polyacrylamide) materials for each rainfall event, while considering the load characteristics of NPS. The study was conducted in Wanju-gun, Jeollabuk-do, in 2022, with a testbed that had a slope of 13%, sandy loam soil, and maize crops. The testbed was composed of four plots: bare soil (Bare), No mulching (Cont.), Vegetation mulching (VM), and PAM mulching (PM). Runoff was collected from each rainfall event using a 1/40 sampler and the NPS load was calculated by measuring the concentrations of SS, T-N, T-P, and TOC. During farming season, the reduction efficiency of NPS load was 37.1~59.5% for VM and 38.2~75.7% for PM. The analysis found that VM had a linear regression correlation (R2=0.28~0.86, P-value=0.01~0.1) with elapsed time of application, while PM had a quadratic regression correlation (R2=0.35~0.80, P-value=0.1). These results suggest that the selection of furrow mulch materials and the appropriate application method play a crucial role in reducing non-point pollution in farmland. Therefore, further studies on the time-series reduction effect based on the application method are recommended to develop more effective preemptive reduction technologies.

Evaluation of Xerostomia Following 3 Dimensional Conformal Radiotherapy for Nasopharyngeal Cancer Patients (3차원 입체조형 방사선치료를 시행받은 코인두암 환자에서의 구강건조증 분석)

  • Park Young-Je;Park Won;Ju Sang-Gyu;Nam Hee-Rim;Oh Dong-Ryul;Park Hee-Chul;Ahn Yong-Chan
    • Radiation Oncology Journal
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    • v.24 no.2
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    • pp.81-87
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    • 2006
  • Purose: This study is to evaluate the xerostomia following 3-dimensional conformal radiation therapy (3D CRT) in nasopharynx cancer patients using the xerostomia questionnaire score (XQS). Materials and Methods: Questionnaire study was done on 51 patients with nasopharynx cancer who received 3D CRT from Dec. 2000 to Aug. 2005. 3D CRT technique is based on 'serial shrinking field' concept by 3 times of computed tomography (CT) simulation. Total target dose to the primary tumor was 72 Gy with 1.8 Gy daily fractions. Xerostomia was assessed with 4-questions XQS, and the associations between XQS and time elapsed after RT, age, sex, stage, concurrent chemotherapy, and parotid dose were analyzed. Results: Concurrent chemotherapy was given to 40 patients and RT alone was given to 11 patients. The median time elapsed after 3D CRT was 20 ($1{\sim}58$) months and the mean XQS of all 51 patients was $8.4{\pm}1.9\;(6{\sim}14)$. XQS continuously and significantly decreased over time after 3D CRT ($X^2$=-0.484, p<0.05). There was no significant difference in XQS according to sex, age, and stag. However, XQS of concurrent chemotherapy patients was significantly higher than RT alone patients (P=0.001). XQS of patients receiving total mean parotid dose ${\ge}35 Gy$ was significantly higher than <35 Gy (p=0.05). Decreasing tendency of XQS over time after 3D CRT was observed. Concurrent chemotherapy and total mean parotid dose ${\ge}35 Gy$ were suggested to adversely affect radiation-induced xerostomia.

A Study on the Characteristics of Chrysotile and Amosite by Acid and Heat Treatment (산 및 열처리 과정에 따른 주요 석면의 특성변화에 관한 연구)

  • Lee, Jin Hyo;Lee, Su Hyun;Kang, Mi Hye;Bae, Il Sang;Kim, Ik Soo;Han, Kyu Mun;Eo, Soo Mi;Jung, Kweon;Koo, Ja Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.6
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    • pp.371-379
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    • 2015
  • This study is purposed to seek the characteristics of both asbestos in accordance with acid and heat treatment for chrysotile and amosite used mainly as building materials. Results of acid treatment, the refractive index, the elongation sign, the extinction of acid-treated chrysotile were mostly similar to those of untreated chrysotile regardless of pH, elapsed time. But the characteristics of acid-treated chrysotile were different from those of untreated chrysotile after 8 weeks, at pH 1.2 acidic solution. When chrysotile treated with acid, weight ratio (%) of O and Mg fluctuated greatly in accordance with acid treatment unlike Si. But the change of constituents ratio (%) was small as time passed after acid treatment. The refractive index, the elongation sign and the extinction of acid-treated amosite were mostly similar to those of untreated amosite regardless of pH, elapsed time. When amosite was treated with acid, weight ratio (%) of Fe slightly increased. But in case of O, a contrary tendency was seen. Results of heat treatment, the higher the temperature, the more increased the refractive index of chrysotile. When chrysotile was heated for 10 minutes at $1,100^{\circ}C$, the elongation sign of chrysotile changed from positive(+) to negative(-). The extinction of chrysotile didn't change apparently in accordance with heat treatment. Also weight ratio (%) of O and Mg fluctuated greatly in accordance with heat treatment unlike Si. The higher the temperature, the more increased the refractive index of amosite. The elongation sign and the extinction of amosite didn't change apparently in accordance with heat treatment. Also weight ratio (%) of O and Fe fluctuated greatly in accordance with heat treatment. But weight ratio (%) of Si and Mg of heated amosite were mostly similar to those of untreated amosite regardless of temperature, heating time.

A Study on the Vulcanization Reaction of Modified NR Blends by In-Situ Electrical Property Measurement (전기적 특성의 in-situ 측정에 의한 개질된 NR 블랜드의 가황 반응에 관한 연구)

  • Ha, Ki-Ryong;Suh, Soong-Hyuck;Rho, Seung-Baik;Lee, Seung-Hyun;Ahn, Won-Sool
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.235-242
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    • 2003
  • A vulcanization reaction characteristics of an isoprene rubber (IR)-modified natural rubber/carbon black (NR/CB) composite was studied using in-situ electrical property measuring technique. Since the electrical conductivity of the sample composite would be changed continuously during the vulcanization reaction by rearranging of the carbon black particles within the sample, volume resistivity (${\rho}$) might be obtained as a function or reaction time. A stabilization time ($t_i$), maximum reaction speed time ($t_p$), and volume resistivity at that time(${\rho}_p$) were defined from the data for the Arrhenius analysis. Volume resistivity ${\rho}$ showed a comparatively high value of ${\sim}10^8$ order before the reaction started, and dramatically decreased to be stabilized within $1{\sim}2$ minutes as soon as the reaction started. As the more time elapsed, thereafter, ${\rho}$ decreased monotonously to a certain constant value through a peak, ${\rho}_p$ at time $t_p$, which was considered as the maximum reaction rate. As a result, while $t_i$ values were comparatively constant as $1{\sim}2$ minutes, $t_p$ values showed to become shorter and shorter as the reaction temperature.

A Study on Foreign Arbitral Awards related to Seller's Notice Fixing Additional Final Period for Performance and Right to Avoid the Contract under the CISG (CISG상 매도인의 부가기간지정권과 계약해제권에 관한 외국중재판정사례 연구)

  • Yi, Ki-Sub;Ahn, Keon-Hyung
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
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    • v.42
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    • pp.163-186
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    • 2009
  • On April 11, 1980, the "United Nations on Contracts for the International Sale of Goods" ("CISG") was prepared by the United Nations Commission on International Trade Law (UNCITRAL) and approved by a diplomatic conference in Vienna providing uniform law for international sales of goods. It took effect as of March 1, 2005, in Korea. It is set forth on the seller's remedies for breach by the buyer Section III (Art. 61 - 65) under the CISG. In this study, the focus is only on the seller's notice fixing additional final period for performance (Art. 63) and the right to avoid the contract (Art. 64), with examination on some relevant foreign arbitral awards rendered by the ICC and the CIETAC together. Article 63 provides that the seller may fix an additional period of time for reasonable length for performance by the buyer of his obligation. It was found from the above arbitral awards that the concept of 'reasonable length' should be decided on a case-by-case basis, given the specific circumstances in the case [Art. 63(1)]. It is provided that unless the seller has received a notice that he will not perform within the period so fixed, the seller may not, during that period, resort to any remedy for breach of contract in accordance with Article 63(2). Article 64(1) provides the means and grounds for avoidance of the contract, which can be avoided 1) when the breach of the buyer amounts to a fundamental breach of contract, or 2) when the additional period of time is fixed by the seller, unless the buyer declares that he will not perform so within the period of fixed time. As we examined in the above arbitral awards, it was held that the contract is avoided when the seller sends the final notice stating that he will avoid the contract, after the expiration of the additional period of time fixed by the seller in the ICC award. On the contrary, it was held that the contract should be deemed to be avoided exactly when the expiration of additional period noted in the avoidance notice is elapsed in the CIETAC award. Article 64(2) sets time limits for avoidance.

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