• Title/Summary/Keyword: eigenvector

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Determination of Reactivities by MO Theory (ⅩⅥ). Theoretical Studies on Acid Catalyzed Displacement Reactions at Carbonyl Carbon (MO 理論에 依한 反應性의 決定 (第16報). 카르보닐炭素의 酸觸媒置換反應에 關한 理論的 硏究)

  • Ikchoon Lee;Soonki Rhee;Kae Soo Lee
    • Journal of the Korean Chemical Society
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    • v.24 no.3
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    • pp.201-208
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    • 1980
  • The CNDO/2 MO method has been used to study gas phase reactions of protonated acetaldehyde with alcohols and protonated acetic acid with alcohols respectively by optimizing state geometries. Results showed that the former is predicted to proceed by alkyl-O cleavage and the latter by acyl-O cleavage. It has also been found using eigenvector properties of reactants that the former should be a charge controlled while the latter an orbital controlled reaction. According to the calculated activation energies assuming the transition states proposed by Caserio et al., the predicted reactivity order for alcohols agreed with the experiments for the latter but the order predicted was the reverse of the experimental one for the former.

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Stress Fields for the V-notched Crack and Fracture Parameters by Boundary Collocation Method (V-노치균열의 응력장과 경계배치법에 의한 파괴변수)

  • Pae, Jung-Pae;Choi, Sung-Ryul
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.1
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    • pp.66-76
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    • 2003
  • The arbitrary V-notched crack problem is considered. The general expressions for the stress components on this problem are obtained as explicit series forms composed of independent unknown coefficients which are denoted by coefficients of eigenvector. For this results eigenvalue equation is performed first through introducing complex stress functions and applying the traction free boundary conditions. Next solving this equation, eigenvalues and corresponding eigenvectors are obtained respectively, and finally inserting these results into stress components, the general equations are obtained. These results are also shown to be applicable to the symmetric V-notched crack or straight crack. It can be shown that this solutions are composed of the linear combination of Mode I and Mode II solutions which are obtained from different characteristic equations, respectively. Through performing asymptotic analysis for stresses, the stress intensity factor is given as a closed form equipped with the unknown coefficients of eigenvector. In order to calculate the unknown coefficients. based on these general explicit equations, numerical programming using the overdetermined boundary collocation method which is algorithmed originally by Carpenter is also worked out. As this programming requires the input data, the commercial FE analysis for stresses is performed. From this study, for some V-notched problems, unknown coefficients can be calculated numerically and also fracture parameters are determined.

Investigating Journal Citation Network with Centrality Measures in the Public Administration and Policy Field (중심성지수를 이용한 행정학·정책학 관련 학술지의 상호인용 네트워크 분석)

  • Choe, Jong-Mook
    • Journal of Digital Convergence
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    • v.14 no.9
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    • pp.301-308
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    • 2016
  • Writing high-quality papers and publishing them at prestigious academic journals would be something that every scholar strives for. This study made a network with nine academic journals in South Korea in the field of public administration and public policy and analyzed the influence of academic journals through social network analysis. Using centrality measures, such as degree centrality, beta centrality, and eigenvector centrality, this study found that Korean Public Administration Review has the highest influence on the journal network, followed by Korean Public Studies Review. However, different choice of centrality measure led to different ranking of journals in terms of their influence.

Direction-of-Arrival Estimation : Signal Eigenvector Method(SEM) (도래각 추정 : 신호 고유벡터 알고리즘)

  • 김영수
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.12
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    • pp.2303-2312
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    • 1994
  • A high resolution algorithm is presented for resolving multiple narrowband plane waves that are incident on an equispaced linear array. To overcome the deleterious effects due to coherent sources, a number of noise-eigenvector-based approaches have been proposed for narrowband signal processing. For differing reasons, each f these methods provide a less than satisfactory resolution of the coherency problem. The proposed algorithm makes use of fundamental property possessed by those eigenvectors of the spatial covariance matrix that are associated with eigenvalues that are larger than the sensor noise level. This property is then used to solve the incoherent and coherent sources incident on an equispaced linear array. Simulation results are shown to illustrate the high resolution performance achieved with this new approach relative to that obtained with MUSIC and spatial smoothed MUSIC.

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Design of the Well-Conditioned Observer - A Linear Matrix Inequality Approach - (Well-Conditioned 관측기 설계 - A Linear Matrix Inequality Approach -)

  • Jung, Jong-Chul;Huh, Kun-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.5
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    • pp.503-510
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    • 2004
  • In this paper, the well-conditioned observer for a stochastic system is designed so that the observer is less sensitive to the ill-conditioning factors in transient and steady-state observer performance. These factors include not only deterministic uncertainties such as unknown initial estimation error, round-off error, modeling error and sensing bias, but also stochastic uncertainties such as disturbance and sensor noise. In deterministic perspectives, a small value in the L$_{2}$ norm condition number of the observer eigenvector matrix guarantees robust estimation performance to the deterministic uncertainties. In stochastic viewpoints, the estimation variance represents the robustness to the stochastic uncertainties and its upper bound can be minimized by reducing the observer gain and increasing the decay rate. Both deterministic and stochastic issues are considered as a weighted sum with a LMI (Linear Matrix Inequality) formulation. The gain in the well-conditioned observer is optimally chosen by the optimization technique. Simulation examples are given to evaluate the estimation performance of the proposed observer.

An Integrated Approach to Measuring Supply Chain Performance

  • Theeranuphattana, Adisak;Tang, John C.S.;Khang, Do Ba
    • Industrial Engineering and Management Systems
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    • v.11 no.1
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    • pp.54-69
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    • 2012
  • Chan and Qi (SCM 8/3 (2003) 209) developed an innovative measurement method that aggregates performance measures in a supply chain into an overall performance index. The method is useful and makes a significant contribution to supply chain management. Nevertheless, it can be cumbersome in computation due to its highly complex algorithmic fuzzy model. In aggregating the performance information, weights used by Chan and Qi-which aim to address the imprecision of human judgments-are incompatible with weights in additive models. Furthermore, the default assumption of linearity of its scoring procedure could lead to an inaccurate assessment of the overall performance. This paper addresses these limitations by developing an alternative measurement that takes care of the above. This research integrates three different approaches to multiple criteria decision analysis (MCDA)-the multiattribute value theory (MAVT), the swing weighting method and the eigenvector procedure-to develop a comprehensive assessment of supply chain performance. One case study is presented to demonstrate the measurement of the proposed method. The performance model used in the case study relies on the Supply Chain Operations Reference (SCOR) model level 1. With this measurement method, supply chain managers can easily benchmark the performance of the whole system, and then analyze the effectiveness and efficiency of the supply chain.

Effect Analysis of an Additional Edge on Centrality and Ranking of Graph Using Computational Experiments (실험계산을 통한 에지 한 개 추가에 따른 그래프의 중심성 및 순위 변화 분석)

  • Han, Chi-Geun;Lee, Sang-Hoon
    • Journal of Internet Computing and Services
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    • v.16 no.5
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    • pp.39-47
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    • 2015
  • The centrality is calculated to describe the importance of a node in a graph and ranking is given according to the centrality for each node. There are many centrality measures and we use degree centrality, closeness centrality, eigenvector centrality, and betweenness centrality. In this paper, we analyze the effect of an additional edge of a graph on centrality and ranking through experimental computations. It is found that the effect of an additional edge on centrality and ranking of the nodes in the graph is different according to the graph structure using PCA. The results can be used for define the graph characteristics.

Semantic Network Analysis about Comments on Internet Articles about Nurse Workplace Bullying (간호사 괴롭힘 관련 인터넷 포털 기사에 대한 댓글의 의미연결망 분석)

  • Kim, Chang Hee;Moon, Seong Mi
    • Journal of Korean Clinical Nursing Research
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    • v.25 no.3
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    • pp.209-220
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    • 2019
  • Purpose: A significant amount of public opinion about nurse bullying is expressed on the internet. The purpose of this study was to analyze the linkage structures among words extracted from comments on internet articles related to nurse workplace bullying using semantic network analysis. Methods: From February 2018 to April 2019, comments made on news articles posted to the Daum and Naver web portal containing keywords such as "nurse", "Taeum", and "bullying" were collected using a web crawler written in Python. A morphological analysis performed with Open Korean Text in KoNLPy generated 54 major nodes. The frequencies, eigenvector centralities, and betweenness centralities of the 54 nodes were calculated and semantic networks were visualized using the UCINET and NetDraw programs. Convergence of iterated correlations (CONCOR) analysis was performed to identify structural equivalence. Results: This paper presents results about March 2018 and January 2019 because these months had highest number of articles. Of the 54 major nodes, "nurse", "hospital", "patient", and "physician" were the most frequent and had the highest eigenvector and betweenness centralities. The CONCOR analysis identified work environment, nurse, gender, and military clusters. Conclusion: This study structurally explored public opinion about nurse bullying through semantic network analysis. It is suggested that various studies on nursing phenomena will be conducted using social network analysis.

Factory Layout and Aisle Structure Design Considering Dimension Constraints and Door Locations (형태 제약과 출입구를 고려한 설비 배치 및 복도 구조 디자인)

  • Chae-Bogk Kim
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.26 no.3
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    • pp.58-66
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    • 2003
  • The cut tree approach of Montreuil and Ratliff [16] and eigenvector approach [10] are used to automatically draw a feasible facility layout with aisle structure. The department arrangement can minimize an aisle distance criterion considering door locations and dimension constraints. The aisle distance is measured by the door to door distance between departments. An eigenvector and cut tree approaches [1] are implemented based on the branch and bound technique in Kim et al. [2] in order to obtain feasible layouts. Then, the algorithm to fix the door location of each department is developed. After the door locations are determined, the factory layout is evaluated in terms of aisle distance. The aisle structure is obtained by expanding the original layout. The solution is kept until we will find better factory layout. The proposed approach based on the branch and bound technique, in theory, will provide the optimal solution. If the runs are time and/or node limited, the proposed method is a strong heuristic. The technique is made further practical by the fact that the solution is constrained such that the rectangular shape dimensions length(l) and width(w) are fixed and a perfect fit is generated if a fit is possible.

Variations in Kiwifruit Microbiota across Cultivars and Tissues during Developmental Stages

  • Su-Hyeon Kim;Da-Ran Kim;Youn-Sig Kwak
    • The Plant Pathology Journal
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    • v.39 no.3
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    • pp.245-254
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    • 2023
  • The plant microbiota plays a crucial role in promoting plant health by facilitating the nutrient acquisition, abiotic stress tolerance, biotic stress resilience, and host immune regulation. Despite decades of research efforts, the precise relationship and function between plants and microorganisms remain unclear. Kiwifruit (Actinidia spp.) is a widely cultivated horticultural crop known for its high vitamin C, potassium, and phytochemical content. In this study, we investigated the microbial communities of kiwifruit across different cultivars (cvs. Deliwoong and Sweetgold) and tissues at various developmental stages. Our results showed that the microbiota community similarity was confirmed between the cultivars using principal coordinates analysis. Network analysis using both degree and eigenvector centrality indicated similar network forms between the cultivars. Furthermore, Streptomycetaceae was identified in the endosphere of cv. Deliwoong by analyzing amplicon sequence variants corresponding to tissues with an eigenvector centrality value of 0.6 or higher. Our findings provide a foundation for maintaining kiwifruit health through the analysis of its microbial community.